9,9'-(5-methyl-1,3-phenylene)bis(9H-carbazole)

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9,9'-(5-methyl-1,3-phenylene)bis(9H-carbazole)
• 英文别名: 9-(3-Carbazol-9-yl-5-methylphenyl)carbazole
• 化学式: C₃₁H₂₂N₂
• 分子量: 422.529
• InChiKey: JYUDEEWCLRYKIX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  33
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  9,9'-(5-methyl-1,3-phenylene)bis(9H-carbazole) 在 吡啶 、 四氯化钛 、 锌 、 三氯氧磷 作用下， 以 四氢呋喃 、 1,2-二氯乙烷 为溶剂， 反应 24.0h， 生成
  参考文献：
  名称：

  Synthesis and Optoelectrochemical Properties of Stilbenophanes Having Carbazole Moieties

  摘要：

  A series of stilbenophanes having N-arylated carbazole moieties possessing small and large cavities have been synthesized via McMurry coupling of the corresponding dialdehyde derived from N-arylation of carbazole with various dibromide followed by formylation. The electrochemical, photophysical, and complexation properties of all the stilbenophanes with electron-deficient guest molecules like TCNQ, TCNE, and PQT were also carried out at different concentrations.

  DOI：

  10.1055/s-0032-1317324
• 作为产物：
  描述：

  3,5-二溴甲苯 、 咔唑 在 tris-(dibenzylideneacetone)dipalladium(0) 、 sodium t-butanolate 、 2-二环己基磷-2,4,6-三异丙基联苯 作用下， 以 甲苯 为溶剂， 以76%的产率得到9,9'-(5-methyl-1,3-phenylene)bis(9H-carbazole)
  参考文献：
  名称：

  基于硝基氧自由基的共轭微孔聚合物作为选择性好氧醇氧化的非均相催化剂†

  摘要：

  通过具有成本效益的FeCl 3催化的二咔唑官能化的TEMPO的氧化聚合，可将2,2,6,6-四甲基哌啶-1-氧基（TEMPO）共价锚定在共轭微孔聚合物（CMP）的支架上。这些TEMPO-CMP在无金属条件下对多种醇的好氧氧化表现出出色的催化性能。此外，TEMPO-CMP可以重复使用至少20次，并具有良好的高催化活性。

  DOI：

  10.1039/c8ta02664e

文献信息

• Organic metal compounds in which compounds for host and compounds for dopant are connected, organic electroluminesence display devices using the compounds and method for preparation of the devices
  申请人：Park Jin Soo

  公开号：US20060237715A1

  公开（公告）日：2006-10-26

  The present embodiments relate to organic metal compounds in which compounds for host and compounds for dopant are connected, organic electroluminescence display devices using the compounds and a method for preparation of the devices. More precisely, the present embodiments relate to organic metal compounds in which the compounds for host and the compounds for dopant are connected to make energy transmission between host and dopant possible in a molecular level, organic electroluminescence display devices using the same and a preparation method thereof. The organic metal compound of the present embodiments can be effectively used as a coloring material of photoluminescence device since it has low molecular level emitting property. Moreover, the photoluminescence device prepared by using the organic metal compound of the present embodiments has enhanced emitting efficiency, brightness, color purity and lifetime.

  本实施例涉及有机金属化合物，其中主体化合物和掺杂剂化合物相连，使用这些化合物的有机电致发光显示器件以及制备这些器件的方法。更确切地说，本实施例涉及有机金属化合物，其中主体化合物和掺杂剂化合物相连，以便在分子水平上实现主体和掺杂剂之间的能量传输，使用相同的有机电致发光显示器件以及其制备方法。本实施例的有机金属化合物可有效用作光致发光器件的着色材料，因为其具有低分子级发射特性。此外，使用本实施例的有机金属化合物制备的光致发光器件具有增强的发射效率、亮度、色彩纯度和寿命。
• [EN] DYES, METHOD OF MAKING THEM, AND THEIR USE IN DYE-SENSITIZED SOLAR CELLS<br/>[FR] COLORANTS, PROCÉDÉS DE FABRICATION DE CEUX-CI, ET LEUR UTILISATION DANS DES CELLULES SOLAIRES SENSIBILISÉES PAR COLORANT
  申请人：SOLVAY

  公开号：WO2012175536A1

  公开（公告）日：2012-12-27

  Dyes, method of making them, and their use in photoelectric conversion devices, especially in dye-sensitized solar cells. The dye compounds are organic compounds of formula (D-π1-B-π2+)n-A comprising at least one sequence D-π1-B-π2 connected to a group A, wherein D is a π-electron donor group electronically conjugated to a π-electron acceptor group (A) through a π-electron bridge group(B), n is an integer from 1 to 10, π1 and π2 being optional bridges electronically conjugating respectively D to B and B to A, and wherein the π-electron acceptor group (A) comprises at least two anchoring groups.

  染料，制备方法以及它们在光电转换器件中的应用，特别是在染料敏化太阳能电池中的应用。这些染料化合物是具有式(D-π1-B-π2+)n-A的有机化合物，其中至少包含一个连接到基团A的序列D-π1-B-π2，其中D是通过π-电子桥基团(B)与π-电子受体基团(A)电子共轭的π-电子给体基团，n是1到10之间的整数，π1和π2分别是可选的桥基，分别将D与B和B与A电子共轭，其中π-电子受体基团(A)包括至少两个锚定基团。
• ORGANIC LIGHT-EMITTING DIODES COMPRISING AT LEAST ONE DISILYL COMPOUND SELECTED FROM DISILYLCARBAZOLES, DISILYLDIBENZOFURANS, DISILYLDIBENZOTHIOPHENES, DISILYLDIBENZOPHOLES, DISILYLDIBENZOTHIOPHENE S-OXIDES AND DISILYLDIBENZOTHIOPHENE S,S-DIOXIDES
  申请人：Langer Nicolle

  公开号：US20110031477A1

  公开（公告）日：2011-02-10

  The present invention relates to an organic light-emitting diode comprising an anode An and a cathode Ka and a light-emitting layer E and if appropriate at least one further layer, where the light-emitting layer E and/or the at least one further layer comprises at least one compound selected from disilylcarbazoles, disilyldibenzofurans, disilyldibenzothiophenes, disilyldibenzophospholes, disilyldibenzothiophene S-oxides and disilyldibenzothiophene S,S-dioxides, to a light-emitting layer comprising at least one of the aforementioned compounds, to the use of the aforementioned compounds as matrix material, hole/exciton blocker material, electron/exciton blocker material, hole injection material, electron injection material, hole conductor material and/or electron conductor material, and to a device selected from the group consisting of stationary visual display units, mobile visual display units and illumination units comprising at least one inventive organic light-emitting diode.

  本发明涉及一种有机发光二极管，包括阳极An和阴极Ka以及发光层E，如适当的至少一层，其中发光层E和/或至少一层包括至少一种选择自二硅基咔唑、二硅基二苯并呋喃、二硅基二苯并噻吩、二硅基二苯并磷杂环戊二烯、二硅基二苯并噻吩S-氧化物和二硅基二苯并噻吩S,S-二氧化物的化合物，至少包括上述化合物之一的发光层，使用上述化合物作为基质材料、空穴/激子阻挡材料、电子/激子阻挡材料、空穴注入材料、电子注入材料、空穴传导材料和/或电子传导材料，并选择自固定的视觉显示单元、移动的视觉显示单元和包括至少一个创新有机发光二极管的照明单元的设备。
• BIPIRIDINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE ELEMENT CONTAINING THE SAME
  申请人：Kimura Masato

  公开号：US20100327265A1

  公开（公告）日：2010-12-30

  The present invention provides a new bipyridine derivative which is suitable for an electron transport material of an organic electronics element and which has bipyridyl central rings as a core, and further provides an organic electroluminescence element containing the derivative. The bipyridine derivative is expressed by the following general formula. (where A 1 , A 2 : represent an aromatic heterocyclic group (except for a carbazolyl group) and an aromatic hydrocarbon group and the aromatic heterocyclic group may be combined; a, b=1 or 2; Ar 1 , Ar 2 : represent a divalent or trivalent aromatic hydrocarbon group which may be substituted by hydrogen atom, an alkyl group, a cycloalkyl group, or an alkoxy group; B 1 , B 2 : represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, an aromatic hydrocarbon group, or an aromatic heterocyclic group; and ring E 1 , ring E 2 : represent a pyridine ring, and may have hydrogen atom, an alkyl group, a cycloalkyl group, or an alkoxy group.), which is used as an electron transport material.

  本发明提供了一种新的联吡啶衍生物，适用于有机电子元件的电子传输材料，并且以联吡啶中心环为核心，并进一步提供了含有该衍生物的有机电致发光元件。该联吡啶衍生物由以下通用公式表示（其中A1、A2：表示芳香杂环基团（除了羰基苯胺基团）和芳香烃基团，芳香杂环基团可以结合；a、b=1或2；Ar1、Ar2：表示可以被氢原子、烷基基团、环烷基基团或烷氧基取代的二价或三价芳香烃基团；B1、B2：表示氢原子、烷基基团、环烷基基团、烷氧基、芳香烃基团或芳香杂环基团；环E1、环E2：表示吡啶环，并且可能带有氢原子、烷基基团、环烷基基团或烷氧基），该衍生物用作电子传输材料。
• Phosphorescent Thymidine Triphosphate Sensor Based on a Donor-Acceptor Ensemble System using Intermolecular Energy Transfer
  作者：Tae-Hyuk Kwon、Hee Jin Kim、Jong-In Hong

  DOI：10.1002/chem.200801260

  日期：2008.10.29

  An ensemble sensor system that exhibited selective luminescence enhancement upon binding to thymidine 5'-triphosphate (TTP) in HEPES buffer over other nucleotides was developed. The ensemble system consisted of an energy acceptor (FIrpic-bis(Zn2+-dipicolylamine conjugate, FIrpic=bis[(4,6-difluorophenyl)-pyridinato-N,C2+]picolinate) derivative) and an energy donor (mCP-Zn2+-cyclen, mCP=N,N'-dicarbazolyl-3

  开发了一种集合传感器系统，该系统在与HEPES缓冲液中的胸苷5'-三磷酸（TTP）结合后比其他核苷酸具有选择性的发光增强。该集合系统由能量受体（FIrpic-双（Zn2 +-二甲基吡啶胺共轭物，FIrpic =双[（4,6-二氟苯基）-吡啶基-N，C2 +]吡啶甲酸）衍生物）和能量供体（mCP-Zn2 +-环，mCP ＝ N，N′-二咔唑基-3，5-苯）。在这些核苷酸中，TTP的选择性识别和发光增强是通过胸腺嘧啶单元与Zn2 +-环素（周期数= 1,4,7,10-四氮杂环十二烷）的牢固结合以及mCP和FIrpic部分之间的分子间能量转移而实现的。