双(过氧化叔丁基)邻苯二甲酸酯 | 2155-71-7

• 物质功能分类: 化学试剂 - 有机试剂 - 酯类
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 双(过氧化叔丁基)邻苯二甲酸酯
• 中文别名: 過氧鄰苯二甲酸二(三級丁酯)；過氧酞酸二(三級丁酯)；?氧?苯二甲酸二(三?丁酯)
• 英文名称: diperoxyphthalic acid di-tert-butyl ester
• 英文别名: Diperoxyphthalsaeure-di-tert-butylester；di-tert-butyl diperoxyphthalate；di-tert.-butyl diperphthalate；di-t-butyl diperoxyphthalate；di-tert-butyl diperphthalate；Di-perphthalsaeure-di-tert.-butylester；Perbutyl MA；ditert-butyl benzene-1,2-dicarboperoxoate
• CAS: 2155-71-7
• 化学式: C₁₆H₂₂O₆
• 分子量: 310.347
• InChiKey: QZYRMODBFHTNHF-UHFFFAOYSA-N

物化性质

• 沸点：
  370.51°C (rough estimate)
• 密度：
  1.1625 (rough estimate)
• 物理描述：
  Di-(tert-butylperoxy)phthalate, [<= 55% as a paste] is a crystalline solid mixed with water. Water lessens the explosion hazard.

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  22
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 海关编码：
  2918300090

反应信息

• 作为产物：
  描述：

  邻苯二甲酰氯 在 叔丁基过氧化氢 、 氢氧化钾 作用下， 生成 双(过氧化叔丁基)邻苯二甲酸酯
  参考文献：
  名称：

  有机过氧化物的研究；叔丁基过酸酯。

  摘要：

  DOI：

  10.1021/ja01208a033
• 作为试剂：
  描述：

  2,3-二甲基-1-丁烯 在 双(过氧化叔丁基)邻苯二甲酸酯 、 氢溴酸 作用下， 生成 1-bromo-2,3-dimethyl-butane
  参考文献：
  名称：

  Polymerization. XII. The Metalation of Olefins and Dienes and their Use in Alfin Polymerization of Butadiene¹

  摘要：

  DOI：

  10.1021/ja01164a125

文献信息

• Fluorinated crosslinker and composition
  申请人：——

  公开号：US20020111518A1

  公开（公告）日：2002-08-15

  Fluorinated multifunctional alcohols containing at least 3 primary hydroxyl groups are disclosed. Such alcohols allow for easy synthesis of multifunctional crosslinkers such as acrylates, epoxies and vinyl ethers. The multifunctional crosslinkers are used in fluorinated optical coating and waveguide compositions to increase curing speed and crosslinking density.

  揭示了含有至少3个主要羟基的氟化多功能醇。这些醇可用于易于合成多功能交联剂，如丙烯酸酯、环氧树脂和乙烯醚。多功能交联剂用于氟化光学涂层和波导组合物中，以增加固化速度和交联密度。
• Temperature-controlled solvent-free selective synthesis of tert-butyl peresters or acids from benzyl cyanides in the presence of the TBHP/Cu(OAc)₂ system
  作者：H. Hashemi、D. Saberi、S. Poorsadeghi、Kh. Niknam

  DOI：10.1039/c6ra27921j

  日期：——

  tert-butyl peresters was achieved via copper-catalyzed oxidative-coupling of benzyl cyanides with tert-butyl hydroperoxide in short reaction times. Various derivatives of tert-butyl peresters were synthesized by this pathway in good to excellent yields. Further investigation revealed that the above-mentioned protocol is effective for the synthesis of benzoic acid derivatives when the reaction is conducted

  叔丁基过酸酯的无溶剂室温合成是通过铜催化的氰基苄基化物与叔丁基氢过氧化物在较短的反应时间内进行氧化偶联。通过该途径合成了叔丁基过酸酯的各种衍生物，收率良好至优异。进一步的研究表明，在相同的反应条件下于80°C进行反应时，上述方案对于合成苯甲酸衍生物是有效的。
• COPOLYMERS INCLUDING A TRIAZINE GROUP AND COMPOSITIONS INCLUDING THEM
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20170198119A1

  公开（公告）日：2017-07-13

  An ultraviolet light-absorbing oligomer that includes a first divalent unit represented by formula (I): and a second divalent unit represented by formula (II): Each R 1 is independently hydrogen or methyl; V is O or NH; X is bond or X is alkylene or alkyleneoxy group having from 1 to 10 carbon atoms and optionally interrupted by one or more —O— groups and optionally substituted by a hydroxyl group; and R2 is alkyl having from 1 to 22 carbon atoms. Compositions that include fluoropolymers and the oligomers are disclosed. The composition can be an extruded film. Compositions that include pressure sensitive adhesives and these oligomers are disclosed.

  一种包括由式(I)表示的第一二价单元和由式(II)表示的第二二价单元的紫外光吸收寡聚物：每个R1独立地是氢或甲基；V为O或NH；X为键或X为含有1至10个碳原子的烷基或烷氧基团，并且可以被一个或多个—O—基团中断，并且可以被一个羟基取代；R2是具有1到22个碳原子的烷基。公开了包括氟聚合物和这些寡聚物的组合物。该组合物可以是挤压薄膜。公开了包括压敏胶粘剂和这些寡聚物的组合物。
• [EN] BENZOTHIAZOL-2-YLAZO-PHENYL COMPOUND AS DYE, COMPOSITIONS INCLUDING THE DYE, AND METHOD OF DETERMINING DEGREE OF CURE OF SUCH COMPOSITIONS<br/>[FR] COMPOSÉ DE BENZOTHIAZOL-2-YLAZO-PHÉNYLE EN TANT QUE COLORANT, COMPOSITIONS INCLUANT LE COLORANT, ET PROCÉDÉ DE DÉTERMINATION DU DEGRÉ DE DURCISSEMENT DE CES COMPOSITIONS
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2014151708A1

  公开（公告）日：2014-09-25

  A compound represented by formula: is disclosed. R is hydrogen or alkyl; X is alkylene; Y is a bond, ether, thioether, amine, amide, ester, thioester, carbonate, thiocarbonate, carbamate, thiocarbamate, urea, thiourea, alkylene, arylalkylene, alkylarylene, or arylene, wherein alkylene, arylalkylene, alkylarylene, and arylene are optionally at least one of interrupted or terminated by at least one of an ether, thioether, amine, amide, ester, thioester, carbonate, thiocarbonate, carbamate, thiocarbamate, urea, or thiourea; and Z is an acrylate, a methacrylate, an acrylamide, a methacrylamide, a styrenyl, or a terminal alkenylene having at least three carbon atoms. A composition including the compound, and a method of determining the degree of cure of a curable polymeric resin are also disclosed.

  揭示了一种由以下公式表示的化合物。R是氢或烷基；X是烷基；Y是键合，醚，硫醚，胺，酰胺，酯，硫酯，碳酸酯，硫代碳酸酯，氨基甲酸酯，硫代氨基甲酸酯，脲，硫代脲，烷基，芳基烷基，烷基芳基，或芳基，其中烷基，芳基烷基，烷基芳基和芳基可以选择至少一个被醚，硫醚，胺，酰胺，酯，硫酯，碳酸酯，硫代碳酸酯，氨基甲酸酯，硫代氨基甲酸酯，脲或硫代脲中的至少一个中断或终止；Z是丙烯酸酯，甲基丙烯酸酯，丙烯酰胺，甲基丙烯酰胺，苯乙烯基，或至少有三个碳原子的末端烯烃基。还公开了包含该化合物的组合物和确定可固化聚合物树脂固化程度的方法。
• COMPOSITIONS INCLUDING A POLYTHIOL, AN UNSATURATED COMPOUND, AND A DYE AND METHODS RELATING TO SUCH COMPOSITIONS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20160319106A1

  公开（公告）日：2016-11-03

  A curable composition having a polythiol; at least one unsaturated compound comprising two or more carbon-carbon double bonds, carbon-carbon triple bonds, or a combination thereof; and a dye compound represented by formula: A crosslinked composition prepared from the curable composition, a method for indicating curing in a curable composition, and a method of stabilizing a curable composition comprising a polythiol and at least one unsaturated compound comprising two or more carbon-carbon double bonds, carbon-carbon triple bonds, or a combination thereof are also disclosed.

  本发明涉及一种可治愈组合物，其中包括聚硫醇；至少一种包含两个或多个碳-碳双键、碳-碳三键或其组合的不饱和化合物；以及由公式表示的染料化合物：制备自可治愈组合物的交联组合物，一种指示可治愈组合物中固化的方法，以及一种稳定聚硫醇和至少一种包含两个或多个碳-碳双键、碳-碳三键或其组合的不饱和化合物的可治愈组合物的方法也被揭示。