2'-ethylhexyl 4-nitrocinnamate

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: 2'-ethylhexyl 4-nitrocinnamate
• 英文别名: 2-ethylhexyl-p-nitrocinnamate；2-ethylhexyl (E)-3-(4-nitrophenyl)prop-2-enoate
• 化学式: C₁₇H₂₃NO₄
• 分子量: 305.374
• InChiKey: TYFVBNSLMWINAW-FMIVXFBMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  22
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  72.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  丙烯酸2-乙基己酯 、 4-nitrobenzenediazonium tetrafluoroborate 在 (IMes)Pd(NQ) 作用下， 以 乙醇 为溶剂， 反应 1.0h， 以96%的产率得到2'-ethylhexyl 4-nitrocinnamate
  参考文献：
  名称：

  Novel nickel-carbene, palladium-carbene and platinum-carbene complexes, their produciton and use in catalytic reactions

  摘要：

  该发明涉及镍、钯或铂的新型单卡宾配合物与电子不足的烯烃配体，以及它们的制备和在有机反应的均相催化中的应用。

  公开号：

  US20060122398A1

文献信息

• Novel nickel-carbene, palladium-carbene and platinum-carbene complexes, their produciton and use in catalytic reactions
  申请人：Karch Ralf

  公开号：US20060122398A1

  公开（公告）日：2006-06-08

  The invention relates to novel monocarbene complexes of nickel, palladium or platinum with electron-deficient olefin ligands, to their preparation and to their use in the homogeneous catalysis of organic reactions.

  该发明涉及镍、钯或铂的新型单卡宾配合物与电子不足的烯烃配体，以及它们的制备和在有机反应的均相催化中的应用。
• RESIN COMPOSITION AND OPTICAL COMPENSATION FILM USING SAME
  申请人：Tosoh Corporation

  公开号：EP3208301A1

  公开（公告）日：2017-08-23

  To provide a resin composition suitable for an optical compensation film, an optical compensation film using the same, which is excellent in the retardation characteristics and wavelength dispersion characteristics, and a production method of an optical compensation film. A resin composition containing, as resin components, from 30 to 99 wt% of a cellulose-based resin represented by the following formula (1) and from 1 to 70 wt% of a cinnamic acid ester copolymer. (wherein each of R1, R2 and R3 independently represents hydrogen or a substituent having a carbon number of 1 to 12).

  提供一种适用于光学补偿膜的树脂组合物、一种使用了该树脂组合物的光学补偿膜，该光学补偿膜在延缓特性和波长色散特性方面都非常出色，还提供了一种光学补偿膜的生产方法。 一种树脂组合物，作为树脂成分，含有 30 至 99 wt%由下式（1）表示的纤维素基树脂和 1 至 70 wt%的肉桂酸酯共聚物。 (其中 R1、R2 和 R3 各自独立地代表氢或碳原子数为 1 至 12 的取代基）。
• Resin composition and optical compensation film using same
  申请人：TOSOH CORPORATION

  公开号：US10126478B2

  公开（公告）日：2018-11-13

  A resin composition suitable for an optical compensation film, an optical compensation film using the same, which is excellent in the retardation characteristics and wavelength dispersion characteristics, and a production method of an optical compensation film. A resin composition containing, as resin components, from 30 to 99 wt % of a cellulose-based resin represented by the following formula (1) and from 1 to 70 wt % of a cinnamic acid ester copolymer: where each of R1, R2 and R3 independently represents hydrogen or a substituent having a carbon number of 1 to 12.

  一种适用于光学补偿膜的树脂组合物、一种使用了该树脂组合物且延缓特性和波长色散特性优异的光学补偿膜，以及一种光学补偿膜的生产方法。一种树脂组合物，作为树脂成分，含有 30 至 99 wt % 下式（1）表示的纤维素基树脂和 1 至 70 wt % 肉桂酸酯共聚物： 其中 R1、R2 和 R3 各自独立地代表氢或碳原子数为 1 至 12 的取代基。
• New Palladium Carbene Catalysts for the Heck Reaction of Aryl Chlorides in Ionic Liquids
  作者：Kumaravel Selvakumar、Alexander Zapf、Matthias Beller

  DOI：10.1021/ol020103h

  日期：2002.9.1

  [GRAPHICS]The Heck reaction of aryl chlorides was investigated in the presence of defined monocarbenepalladium(0) complexes. Activated and nonactivated aryl chlorides provide the corresponding cinnamic esters and stilbenes in (Bu4NBr)-Bu-n as a ionic liquid in good to excellent yields.
• Synthesis of Monocarbenepalladium(0) Complexes and Their Catalytic Behavior in Cross-Coupling Reactions of Aryldiazonium Salts
  作者：Kumaravel Selvakumar、Alexander Zapf、Anke Spannenberg、Matthias Beller

  DOI：10.1002/1521-3765(20020902)8:17<3901::aid-chem3901>3.0.co;2-e

  日期：2002.9.2

  The first monocarbenepalladium(0) complexes with benzoquinone and naphthoquinone as additional ligands have been prepared. As demonstrated by NMR spectroscopy and X-ray analysis, the complexes show a unique coordination mode giving quinone-bridged dimers. The monocarbenepalladium(0) complexes allow efficient cross-coupling reactions of aryldiazonium salts with olefins (Heck reaction) and arylboronic acids (Suzuki reaction).