2-trifluoroacetyl-2-methylcyclopentene

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-trifluoroacetyl-2-methylcyclopentene
• 英文别名: 1-trif;uoroacetyl-2-methylcyclopent-1-ene；Ethanone, 2,2,2-trifluoro-1-(2-methyl-1-cyclopenten-1-yl)-(9CI)；2,2,2-trifluoro-1-(2-methylcyclopenten-1-yl)ethanone
• 化学式: C₈H₉F₃O
• 分子量: 178.154
• InChiKey: RCXQKCIQVRRYMQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1-甲基环戊烯 、 三氟乙酸酐 在 二甲基硫 、 三氟化硼 作用下， 以 二氯甲烷 为溶剂， 以30%的产率得到2-trifluoroacetyl-2-methylcyclopentene
  参考文献：
  名称：

  Nenaidenko, V. G.; Balenkova, E. S., Russian Journal of Organic Chemistry, 1995, vol. 31, # 8, p. 1030 - 1036

  摘要：

  DOI：

文献信息

• Perfluoroacylation of alkenes
  作者：Valentine G Nenajdenko、Ilya D Gridnev、Elizabeth S Balenkova

  DOI：10.1016/s0040-4020(01)85712-4

  日期：1994.1

  Reaction of direct electrophilic perfluoroacylation of diffferent structure alkenes with trifluoroacetic anhydride activated by BF3.SMe(2) complex leads to trifluoromethylalkenylketones with different structure of alkenyl group. Possible composition of the reactive species is considered on the basis of IR and NMR data. Dependence of the reaction course on the substrate structure is discussed.
• Honeybee Repellents and Uses Thereof
  申请人：Inscent, Inc.

  公开号：US20160251312A1

  公开（公告）日：2016-09-01

  The present specification discloses honeybee repellents exhibiting repellent properties similar to 2-heptanone, compositions comprising such repellents, uses to repel a honeybee from a mammal, location, plant, structure treated of such repellents, and methods of treating a mammal, location, plant, structure by applying such repellents.
• US9796676B2
  申请人：——

  公开号：US9796676B2

  公开（公告）日：2017-10-24
• [EN] IMPROVED HONEYBEE REPELLENTS AND USES THEREOF<br/>[FR] RÉPULSIFS AMÉLIORÉS CONTRE LES ABEILLES DOMESTIQUES ET LEURS UTILISATIONS
  申请人：INSCENT INC

  公开号：WO2014179785A1

  公开（公告）日：2014-11-06

  The present specification discloses honeybee repellents exhibiting repellent properties similar to 2- heptanone, compositions comprising such repellents, uses to repel a honeybee from a mammal, location, plant, structure treated of such repellents, and methods of treating a mammal, location, plant, structure by applying such repellents.
• Nenaidenko, V. G.; Balenkova, E. S., Russian Journal of Organic Chemistry, 1995, vol. 31, # 8, p. 1030 - 1036
  作者：Nenaidenko, V. G.、Balenkova, E. S.

  DOI：——

  日期：——