Ru (4,4'-diphenyl-1,10-phenantrolene)2 4,4'-dicarboxy-2,2'-bipyridine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Ru (4,4'-diphenyl-1,10-phenantrolene)2 4,4'-dicarboxy-2,2'-bipyridine
• 英文别名: 2-(4-carboxypyridin-2-yl)pyridine-4-carboxylic acid;4,7-diphenyl-1,10-phenanthroline;ruthenium
• 化学式: C₆₀H₄₀N₆O₄Ru
• 分子量: 1010.09
• InChiKey: HDTXFOYLOYFMHA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.77
• 重原子数：
  71
• 可旋转键数：
  6
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  152
• 氢给体数：
  2
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  Ru(4,7-diphenyl-1,10-phenanthroline)₂Cl₂ 、 2,2'-联吡啶-4,4'-二甲酸 、 4,7-二苯基-1,10-菲罗啉 在 triethylamine 作用下， 以 乙醇 、 水 为溶剂， 生成 Ru (4,4'-diphenyl-1,10-phenantrolene)2 4,4'-dicarboxy-2,2'-bipyridine
  参考文献：
  名称：

  Chemical potential shifts at organic device electrodes induced by grafted monolayers

  摘要：

  Charge injection from an electrode into an organic semiconductor is strongly dependent on the height of the energy barrier between the electrode workfunction and the energy level of the HOMO or LUMO molecular orbitals. In the case of the well-known emitter tris-(8-hydroxyquinoline) aluminium (Alq) on clean indium tin oxide (ITO), an energy barrier of about 1 eV hinders both negative and positive charge carriers to be injected from the oxide electrode. By grafting molecules with appropriate dipole moments on ITO we have constructed light-emitting diodes based on Alq to demonstrate that the ITO workfunction can be modified in such a way that holes and even electrons can be efficiently injected. (C) 1998 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0009-2614(98)00350-9