2,9-dimethylphenanthridine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2,9-dimethylphenanthridine
• 化学式: C₁₅H₁₃N
• 分子量: 207.275
• InChiKey: UPFDNLOMRQSRKC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (4-methyl-phenyl)-(4-methylbenzylidene)-amine 在 叔丁醇 作用下， 反应 2.0h， 以80%的产率得到2,9-dimethylphenanthridine
  参考文献：
  名称：

  直接脱氢条件下菲啶及其衍生物的光环合成

  摘要：

  建立了一种通过光环化合成菲啶的新方法。该方法不需要惰性气体保护，不需要过渡金属催化剂，并且是环境友好，有效和方便的。提出以（E）-N，1-二苯基甲亚胺为底物通过紫外光合成菲啶及其衍生物，为进一步研究光环化合成菲啶提供了一条新的合成途径。合成了八种新的菲啶化合物。其结构的确认为进一步研究其性能和挖掘其应用潜力提供了物质基础。该方法的建立进一步拓宽了菲啶化合物的合成途径。

  DOI：

  10.1016/j.tetlet.2020.152734

文献信息

• One‐pot Cascade Reaction for the Synthesis of Phenanthridines via Suzuki Coupling/C−H Oxidation/Aromatization
  作者：Yi Zhang、Yuxin Ding、Rener Chen、Yongmin Ma

  DOI：10.1002/adsc.202000949

  日期：2020.12.22

  A one‐pot cascade coupling/annulation reaction for the synthesis of phenanthridines has been developed from arylboronic acids and o‐bromo arylamides with DMSO as a carbon source. The desired phenanthridines were obtained in moderate to good yields by using simple procedure.

  由芳基硼酸和邻溴代芳基酰胺以DMSO为碳源开发了一种单锅级联偶联/环化反应，用于合成菲啶。通过使用简单的方法，以中等至良好的产率获得了所需的菲啶。
• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20180138419A1

  公开（公告）日：2018-05-17

  The present invention discloses organic azacyclophane compounds with two substituted triazine, pyridine, pyrimidine or pyrazine rings. These materials may serve as hosts, charge transporting and blocking materials and may improve OLED performance.

  本发明公开了具有两个取代三嗪、吡啶、嘧啶或吡嗪环的有机氮杂环烷化合物。这些材料可以用作宿主、电荷传输和阻挡材料，并且可以提高有机发光二极管（OLED）的性能。
• POLYMER COMPOUND CONTAINING NITROGEN-CONTAINING HETEROCYCLIC STRUCTURE, AND COMPOSITION, SOLUTION, THIN FILM AND POLYMER LIGHT-EMITTING ELEMENT EACH CONTAINING SAME
  申请人：Ishii Yusuke

  公开号：US20110210322A1

  公开（公告）日：2011-09-01

  A polymer compound having a repeating unit represented by formula (1-0): wherein in formula (1-0), ring A 01 and ring A 02 are the same or different and each represents an aromatic hydrocarbon ring that is optionally substituted; and X 10 and X 20 are the same or different and each represents a hydrogen atom or a substituent, provided that at least one of X 10 and X 20 is a group represented by formula (2-0): wherein in formula (2-0), Z 10 , Z 20 and Z 30 are the same or different and each represents —N═ or —CH═, provided that at least two of Z 10 , Z 20 and Z 30 are —N═; L 0 represents an arylene group or a single bond; and Ar 10 and Ar 20 are the same or different and each represents an aryl group, provided that the total carbon number of the groups represented by Ar 10 , Ar 20 and L 0 is 24 or more.

  具有由公式（1-0）表示的重复单元的聚合物化合物：其中，在公式（1-0）中，环A01和环A02相同或不同，每个环都表示可以选择取代的芳香族碳氢环；X10和X20相同或不同，每个都表示氢原子或取代基，但至少其中一个是由公式（2-0）表示的基团：其中，在公式（2-0）中，Z10、Z20和Z30相同或不同，每个都表示—N═或—CH═，但至少有两个是—N═；L0表示芳撑基团或单键；Ar10和Ar20相同或不同，每个都表示芳基团，但由Ar10、Ar20和L0表示的基团的总碳数为24或更多。
• COMPOUND CONTAINING 1,3-DIENE STRUCTURE AND METHOD FOR PRODUCING SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2311893A1

  公开（公告）日：2011-04-20

  Disclosed is a compound containing a divalent group represented by formula (I). (In formula (I), Ar1 represents an arylene group, a divalent heterocyclic group or a divalent aromatic amine group; J1 represents a phenylene group; J2 represents an alkylene group; X represents an oxygen atom or a sulfur atom; j represents 0 or 1, k represents an integer of 0-3, and 1 represents 0 or 1, while satisfying 1 ≤ j + k + l ≤ 5; m represents 1 or 2; R1 represents a hydrogen atom, an alkyl group, an alkoxy group, an alkylthio group, an aryl group, an aryloxy group, an arylthio group, an arylalkyl group, an arylalkoxy group, an arylalkylthio group, an arylalkenyl group, an arylalkynyl group, an amino group, a substituted amino group, a silyl group, a substituted silyl group, a halogen atom, an acyl group, an acyloxy group, an imine residue, a carbamoyl group, an acid imide group, a monovalent heterocyclic group, a carboxyl group, a substituted carboxyl group, a cyano group or a nitro group; the plurality of R1's may be the same as or different from each other; and when there are a plurality of J1's, J2's, X's, j's, k's or l's, the J1's, J2's, X's, j's, k's or l's may be the same as or different from each other, respectively.)

  本发明公开了一种含有由式（I）表示的二价基团的化合物。(在式(I)中，Ar1代表芳烯基、二价杂环基或二价芳胺基；J1代表亚苯基；J2代表亚烷基；X代表氧原子或硫原子；j代表0或1，k代表0-3的整数，1代表0或1，同时满足1≤j+k+l≤5；m代表1或2；R1 代表氢原子、烷基、烷氧基、烷硫基、芳基、芳氧基、芳硫基、芳烷基、芳烷氧基、 芳烷氧基、芳烷硫基、芳烯基、芳炔基、氨基、取代氨基硅烷基、取代硅烷基、卤素原子、酰基、酰氧基、亚胺残基、氨基甲酰基、酸亚胺基、一价杂环基、羧基、取代羧基、氰基或硝基；多个 R1 可以彼此相同或彼此不同；当存在多个 J1、J2、X、j、k 或 l 时，J1、J2、X、j、k 或 l 可以分别彼此相同或彼此不同。)
• COMPOSITION AND LIGHT EMITTING ELEMENT USING THE COMPOSITION
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2518110A1

  公开（公告）日：2012-10-31

  A composition comprising (i) a crosslinkable polymer compound having a crosslinkable group and being capable of showing at least one of a light emitting property and charge transportability, and (ii) a crosslinkable low molecular weight compound having a crosslinkable group and being capable of showing at least one of a light emitting property and charge transportability.

  一种组合物，包含(i)具有可交联基团并能显示发光特性和电荷传输性中至少一种特性的可交联聚合物化合物，以及(ii)具有可交联基团并能显示发光特性和电荷传输性中至少一种特性的可交联低分子量化合物。