四(乙腈)四氟硼酸钯(II) | 21797-13-7

• 物质功能分类: 有机原料 - 有机金属类化合物 - 有机钯
• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 四(乙腈)四氟硼酸钯(II)
• 中文别名: 四乙腈四氟硼酸钯
• 英文名称: acetonitrile;palladium(2+);ditetrafluoroborate
• CAS: 21797-13-7
• 化学式: C8H12B2F8N4Pd
• 分子量: 444.2
• InChiKey: YWMRPVUMBTVUEX-UHFFFAOYSA-N

物化性质

• 熔点：
  230 °C (dec.) (lit.)
• 稳定性/保质期：
  如果按照规格正确使用和储存，则不会分解。避免接触氧化物和空气。

计算性质

• 辛醇/水分配系数(LogP)：
  4.72
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  95.2
• 氢给体数：
  0
• 氢受体数：
  14

安全信息

• 危险等级：
  6.1
• 危险品标志：
  Xn
• 安全说明：
  S22,S36/37/39,S38
• 危险类别码：
  R20
• WGK Germany：
  3
• 海关编码：
  29310099
• 危险品运输编号：
  UN 2811
• 危险标志：
  GHS07
• 危险性描述：
  H332
• 危险性防范说明：
  P261,P304+P340

SDS

Name:	Tetrakis(acetonitrile)palladium(II) tetrafluoroborate Material Safety Data Sheet
Synonym:
CAS:	21797-13-7

Section 1 - Chemical Product MSDS Name:Tetrakis(acetonitrile)palladium(II) tetrafluoroborate Material Safety Data Sheet
Synonym:

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
21797-13-7	Tetrakis(acetonitrile)palladium(II) te		unlisted

Hazard Symbols: XN
Risk Phrases: 20/21/22

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.Air sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
Not available.

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Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

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Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store under nitrogen.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 21797-13-7: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 230 deg C (dec.)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C8H12B2F8N4Pd
Molecular Weight: 444.22

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to air.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride gas, boron oxides.
Hazardous Polymerization: Has not been reported

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 21797-13-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tetrakis(acetonitrile)palladium(II) tetrafluoroborate - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
No information available.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 21797-13-7: 2
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 21797-13-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 21797-13-7 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  四(乙腈)四氟硼酸钯(II) 、 苯甲腈 生成 benzonitrile;palladium(2+);ditetrafluoroborate
  参考文献：
  名称：

  SEN, AYUSMAN;LAI, TA-WANG;THOMAS, RICHARD R., J. ORGANOMET. CHEM., 358,(1988) N-3, C. 567-588

  摘要：

  DOI：

文献信息

• SEN, AYUSMAN;LAI, TA-WANG;THOMAS, RICHARD R., J. ORGANOMET. CHEM., 358,(1988) N-3, C. 567-588
  作者：SEN, AYUSMAN、LAI, TA-WANG、THOMAS, RICHARD R.

  DOI：——

  日期：——
• JIANG, ZHAOZHONG;SEN, AYUSMAN, J. AMER. CHEM. SOC., 112,(1990) N6, C. 9655-9657
  作者：JIANG, ZHAOZHONG、SEN, AYUSMAN

  DOI：——

  日期：——