6-methyl-trideca-6,7-diene-1,12-diyne

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 6-methyl-trideca-6,7-diene-1,12-diyne
• 化学式: C₁₄H₁₈
• 分子量: 186.297
• InChiKey: UHIWMSVWWLVSBV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-(4-戊炔氧基)四氢-2H-吡喃 在 六甲基磷酰三胺 、 正丁基锂 、 copper(I) bromide dimethylsulfide complex 、 sodium hydride 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 为溶剂， 反应 1.67h， 生成 6-methyl-trideca-6,7-diene-1,12-diyne
  参考文献：
  名称：

  Synthesis of variously substituted allenediynes and their cobalt (I)-mediated [2+2+2] cycloaddition reactions

  摘要：

  Syntheses of variously substituted allenediynes where the allene moiety is at the terminal or internal position are described. Their cobalt(I)-mediated [2+2+2] cycloaddition reactions led to the corresponding eta(4)-complexed tricyclic compounds; the regioselectivity of these cyclizations depending on the substitution and the position of the allene is discussed. (C) 1998 Elsevier Science Ltd. Ali rights reserved.

  DOI：

  10.1016/s0040-4020(98)00567-5

文献信息

• Synthesis of variously substituted allenediynes and their cobalt (I)-mediated [2+2+2] cycloaddition reactions
  作者：Dominique Llerena、Olivier Buisine、Corinne Aubert、Max Malacria

  DOI：10.1016/s0040-4020(98)00567-5

  日期：1998.8

  Syntheses of variously substituted allenediynes where the allene moiety is at the terminal or internal position are described. Their cobalt(I)-mediated [2+2+2] cycloaddition reactions led to the corresponding eta(4)-complexed tricyclic compounds; the regioselectivity of these cyclizations depending on the substitution and the position of the allene is discussed. (C) 1998 Elsevier Science Ltd. Ali rights reserved.