(E,Z,Z)-2,4,7-十三碳三烯醛 | 13552-96-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: (E,Z,Z)-2,4,7-十三碳三烯醛
• 英文名称: (E,Z,Z)-2,4,7-tridecatrienal
• 英文别名: trideca-2t,4c,7c-trienal；(E,Z,Z)-trideca-2,4,7-trienal；(2E,4Z,7Z)-trideca-2,4,7-trienal
• CAS: 13552-96-0
• 化学式: C₁₃H₂₀O
• 分子量: 192.301
• InChiKey: BIXIZZVISIZZDM-JSHIYTDESA-N

物化性质

• 沸点：
  309.5±21.0 °C(Predicted)
• 密度：
  0.869±0.06 g/cm3(Predicted)
• LogP：
  4.259 (est)
• 物理描述：
  colourless to pale yellow liquid; fatty aroma with light fruity undertones
• 溶解度：
  Soluble in fat; Insoluble in water
• 折光率：
  1.472-1.478
• 保留指数：
  1589;1584

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2912190090

反应信息

• 作为反应物：
  描述：

  (E,Z,Z)-2,4,7-十三碳三烯醛 在 咪唑 、 4-二甲氨基吡啶 、 Rh₂(Oct)4 、 双(三甲基硅烷基)氨基钾 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 22.17h， 生成
  参考文献：
  名称：

  Synthesis of the Eight Enantiomerically Pure Diastereomers of the 12-F₂-Isoprostanes

  摘要：

  Syntheses of the eight enantiomerically pure diastereomers of the 12-F-2-isoprostanes (4-11) are described. The key steps included rhodium-mediated intramolecular cyclopropanation and enzymatic resolution of the racemic diol 12.

  DOI：

  10.1021/ja020816v
• 作为产物：
  描述：

  2-辛炔-1-醇 在 Lindlar's catalyst 吡啶 、 manganese(IV) oxide 、 乙基溴化镁 、 氢气 、 三溴化磷 、 copper(l) chloride 作用下， 以 甲醇 、 乙醚 、 正己烷 为溶剂， 反应 28.5h， 生成 (E,Z,Z)-2,4,7-十三碳三烯醛
  参考文献：
  名称：

  Blank; Lin; Vera, Journal of Agricultural and Food Chemistry, 2001, vol. 49, # 6, p. 2959 - 2965

  摘要：

  DOI：

文献信息

• FLAVOR MODULATOR HAVING PYRIDINE DERIVATIVE OR SALT THEREOF AS ACTIVE INGREDIENT
  申请人：T. HASEGAWA CO., LTD.

  公开号：US20180072670A1

  公开（公告）日：2018-03-15

  2-(phenylalkyloxyalkyl)pyridine derivative or a 2-(phenylalkylthioalkyl)pyridine derivative imparts, when added to food and drink or cosmetics as an active ingredient, a flavor of natural impression thereto; and in particular, when added to food and drink, the compound imparts an umami imparting or enhancing, a saltiness enhancing a sweetness enhancing, and in particular, when added to a milk or dairy product, a food or drink product containing a milk or dairy product, or a dairy replacement product, the compound provides a milk richness enhancing.

  2-(苯基烷氧基烷基)吡啶衍生物或2-(苯基烷硫基烷基)吡啶衍生物，当作为食品、饮料或化妆品的活性成分添加时，赋予其一种天然印象的风味；特别是当添加到食品和饮料中时，该化合物赋予了一种鲜味、增强了咸味和甜味，特别是当添加到牛奶或乳制品中时，该化合物提供了增强奶香的效果。
• BITTER TASTE MODIFIERS INCLUDING SUBSTITUTED 1-BENZYL-3-(1-(ISOXAZOL-4-YLMETHYL)-1H-PYRAZOL-4-YL)IMIDAZOLIDINE-2,4-DIONES AND COMPOSITIONS THEREOF
  申请人：SENOMYX, INC.

  公开号：US20160376263A1

  公开（公告）日：2016-12-29

  The present invention includes compounds and compositions known to modify the perception of bitter taste, and combinations of said compositions and compounds with additional compositions, compounds, and products. Exemplary compositions comprise one or more of the following: cooling agents; inactive drug ingredients; active pharmaceutical ingredients; food additives or foodstuffs; flavorants, or flavor enhancers; food or beverage products; bitter compounds; sweeteners; bitterants; sour flavorants; salty flavorants; umami flavorants; plant or animal products; compounds known to be used in pet care products; compounds known to be used in personal care products; compounds known to be used in home products; pharmaceutical preparations; topical preparations; cannabis-derived or cannabis-related products; compounds known to be used in oral care products; beverages; scents, perfumes, or odorants; compounds known to be used in consumer products; silicone compounds; abrasives; surfactants; warming agents; smoking articles; fats, oils, or emulsions; and/or probiotic bacteria or supplements.

  本发明涵盖已知用于改变苦味感知的化合物和组合物，以及所述组合物和化合物与额外的组合物、化合物和产品的组合。示例组合物包括以下一种或多种：冷却剂；无活性药物成分；活性药用成分；食品添加剂或食品；调味剂或调味增强剂；食品或饮料产品；苦味化合物；甜味剂；苦味剂；酸味调味剂；咸味调味剂；鲜味调味剂；植物或动物产品；已知用于宠物护理产品中的化合物；已知用于个人护理产品中的化合物；已知用于家用产品中的化合物；制药制剂；局部制剂；大麻衍生或与大麻相关的产品；已知用于口腔护理产品中的化合物；饮料；香味、香水或除臭剂；已知用于消费品中的化合物；硅化合物；磨料；表面活性剂；发热剂；吸烟物品；脂肪、油脂或乳化剂；和/或益生菌或补充剂。
• COMPOUNDS USEFUL AS MODULATORS OF TRPM8
  申请人：Senomyx, Inc.

  公开号：US20170096418A1

  公开（公告）日：2017-04-06

  The present disclosure relates to compounds which are useful as cooling sensation compounds.

  本公开涉及作为冷感化合物有用的化合物。
• ACID TASTE/ACID SMELL-REDUCING AGENT
  申请人：Haraguchi Kenji

  公开号：US20140120232A1

  公开（公告）日：2014-05-01

  Provided is an acid taste and/or acid smell-reducing agent that can effectively reduce acid taste/acid smell without adding off-taste and off-smell. The acid taste and/or acid smell-reducing agent is composed of 4,7-tridecadienal and/or 2,4,7-tridecatrienal and is added to a food or drink having acid taste and/or acid smell.

  提供了一种酸味和/或酸味减少剂，可以有效地减少酸味/酸味，而不会添加异味和异味。该酸味和/或酸味减少剂由4,7-十三烯醛和/或2,4,7-十三烯三醛组成，并添加到具有酸味和/或酸味的食品或饮料中。
• Absorbent articles including odour control system
  申请人：The Procter and Gamble Company

  公开号：EP1842564A1

  公开（公告）日：2007-10-10

  Absorbent articles which are provided with an odour control system. The odour control system includes at least two classes of odour control materials, wherein one class acts on malodours or a malodorous substance in the absorbent article, whereas a second class acts on nose receptors. The classes of odour control materials may be selected to provide a synergistic effect in terms of malodour reduction.

  具有气味控制系统的吸附用品。气味控制系统包括至少两类气味控制材料，其中一类对吸收物品中的恶臭或恶臭物质起作用，而第二类则对鼻子感受器起作用。可以选择这两类气味控制材料，以便在减少恶臭方面产生协同效应。