(Z)-唑螨酯 | 149054-53-5

• 物质功能分类: 化学农药原药 - 杀虫剂 - 杀螨剂
• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: (Z)-唑螨酯
• 英文名称: Fenpyroximate, (Z)-
• 英文别名: tert-butyl 4-[[(Z)-(1,3-dimethyl-5-phenoxypyrazol-4-yl)methylideneamino]oxymethyl]benzoate
• CAS: 149054-53-5
• 化学式: C₂₄H₂₇N₃O₄
• 分子量: 421.5
• InChiKey: YYJNOYZRYGDPNH-MYYYXRDXSA-N

物化性质

• 熔点：
  48～53℃
• 颜色/状态：
  White crystalline powder
• 闪点：
  85.0 °C (185 °F) (closed cup). /FujiMite 5EC Miticide/Insecticide/
• 溶解度：
  In methanol 15.3, acetone 150, chloroform 1197, tetrahydrofuran 737, toluene 268, ethyl acetate 201, ethanol 16.5, n-hexane 3.5 (all in g/L, 25 °C)
• 密度：
  1.25 g/cu cm at 20 °C
• 蒸汽压力：
  7.4X10-3 mPa /5.58X10-8 mm Hg/ at 25 °C
• 稳定性/保质期：

  This product is stable for at least 12 months under normal storage conditions 25 deg +/- 2 °C. /FujiMite 5EC Miticide/Insecticide/

• 碰撞截面：
  215.89 Ų [M+H]+ [CCS Type: TW]

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  31
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  74.9
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  喹螨醚 、 (Z)-唑螨酯 、 嘧螨醚 、 吡螨胺 、 唑虫酰胺 生成 amitraz
  参考文献：
  名称：

  6-ACYL-1,2,4-TRIAZINE-3,5-DIONE DERIVATIVE AND HERBICIDES

  摘要：

  本发明涉及三嗪衍生物化合物，当它们应用于土壤和叶面时，表现出足够的除草活性，且施用剂量较低，以及使用相同的农药组合物，特别是除草剂。

  公开号：

  US20150203457A1

文献信息

• Pyrazolyl Carboxamides
  申请人：Dunkel Ralf

  公开号：US20090069398A1

  公开（公告）日：2009-03-12

  Novel pyrazolylcarboxamides of the formula (I) The present application is further directed to a plurality of processes for preparing these compounds and their use for controlling unwanted microorganisms, and also novel intermediates and their preparation.

  本申请还涉及制备式(I)的新型吡唑基羧酰胺化合物的多种方法及其用于控制不需要的微生物的应用，还包括新型中间体及其制备方法。
• Alkoxyimino derivative and pest control agent
  申请人：Fukumoto Shunichirou

  公开号：US08895035B2

  公开（公告）日：2014-11-25

  The present invention provides a novel alkoxyimino derivative or a salt thereof, as well as to a pest control agent containing the derivative or salt thereof as an active ingredient, which shows an excellent pest control effect on a wide range of pests in the agricultural and horticultural field and is also capable of controlling resistant pests. The novel alkoxyimino derivative is characterized by being represented by general formula [I] (in the formula, X, R1, R2 and Q are as defined in the specification) and the post control agent is characterized by containing as an active ingredient the alkoxyimino derivative or a salt thereof.

  本发明提供了一种新型的烷氧基亚胺衍生物或其盐，以及包含该衍生物或其盐作为活性成分的杀虫剂，在农业和园艺领域对广泛的害虫表现出优异的杀虫效果，并且还能够控制抗性害虫。该新型烷氧基亚胺衍生物的特征在于由通式[I]表示（式中，X、R1、R2和Q如规范中所定义），而该杀虫剂的特征在于包含烷氧基亚胺衍生物或其盐作为活性成分。
• 6-acyl-1,2,4-triazine-3,5-dione derivative and herbicides
  申请人：Shibayama Atsushi

  公开号：US08969554B2

  公开（公告）日：2015-03-03

  Disclosed are compounds exhibiting sufficient herbicidal activity at low application dosage when they are applied to soils and foliage, and an agrochemical composition using the same, in particular herbicides. The compounds are triazine derivatives represented by following Formula 1 or salts thereof, and the herbicides containing them: [Chem. 28] wherein in the formula, R1 represents a hydrogen atom; a C1-C12 alkyl group; a C2-C6 alkenyl group, etc., R2 represents a C1-C12 alkyl group, etc., Y and Z represent an oxygen atom or a sulfur atom, and A represents a 5- or 6-membered cyclic group which may contain a nitrogen atom, an oxygen atom, or a sulfur atom.

  本发明涉及在土壤和叶面上施用时表现出足够的除草活性，并且在低施用剂量下使用的化合物，以及使用它们的农药组合物，特别是除草剂。该化合物是由以下式子1表示的三嗪衍生物或其盐，以及含有它们的除草剂：[Chem. 28] 其中，在该式中，R1表示氢原子；C1-C12烷基；C2-C6烯基等，R2表示C1-C12烷基等，Y和Z表示氧原子或硫原子，A表示可能含有氮原子，氧原子或硫原子的5-或6-成员环状基团。
• ALKOXYIMINO DERIVATIVE AND PEST CONTROL AGENT
  申请人：Fukumoto Shunichirou

  公开号：US20130102568A1

  公开（公告）日：2013-04-25

  [PROBLEMS] The present invention provides a novel alkoxyimino derivative or a salt thereof, as well as to a pest control agent containing the derivative or salt thereof as an active ingredient, which shows an excellent pest control effect on a wide range of pests in the agricultural and horticultural field and is also capable of controlling resistant pests. [MEANS FOR SOLVING PROBLEMS] The novel alkoxyimino derivative is characterized by being represented by general formula [I] (in the formula, X, R 1 , R 2 and Q are as defined in the specification) and the post control agent is characterized by containing as an active ingredient the alkoxyimino derivative or a salt thereof.

  [问题] 本发明提供了一种新型的烷氧基亚胺衍生物或其盐，以及一种含有该衍生物或其盐作为活性成分的杀虫剂，该杀虫剂在农业和园艺领域对广泛的害虫具有出色的杀虫效果，并且还能够控制抗性害虫。 [解决问题的方法] 新型的烷氧基亚胺衍生物的特点是由通式[I]表示（在公式中，X，R1，R2和Q如规范中所定义），而该杀虫剂的特点是含有烷氧基亚胺衍生物或其盐作为活性成分。
• Triazole compound having pesticidal activities
  申请人：Toriyabe Keiji

  公开号：US08729116B2

  公开（公告）日：2014-05-20

  To provide a triazole compound which has remarkably excellent pesticidal activities. Optically active (+)-1-[2-fluoro-4-methyl-5-(2,2,2-trifluoroethylsulfinyl)phenyl]-5-amino-3-(trifluoromethyl)-1H-1,2,4-triazole represented by the following formula (I), which is obtainable by subjecting a racemic modification of 1-[2-fluoro-4-methyl-5-(2,2,2-trifluoroethylsulfinyl)phenyl]-5-amino-3-(trifluoromethyl)-1H-1,2,4-triazole to optical resolution:

  提供一种具有显著杀虫活性的三唑类化合物。该化合物是光学活性的(+)-1-[2-氟-4-甲基-5-(2,2,2-三氟乙基磺酰基)苯基]-5-氨基-3-(三氟甲基)-1H-1,2,4-三唑，由将1-[2-氟-4-甲基-5-(2,2,2-三氟乙基磺酰基)苯基]-5-氨基-3-(三氟甲基)-1H-1,2,4-三唑的外消旋体经过光学分离得到，其化学式如下（I）：