1,2:13,14-二环氧十四烷 | 65520-48-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 中文名称: 1,2:13,14-二环氧十四烷
• 英文名称: 1,2:13,14-diepoxytetradecane
• 英文别名: 2-[10-(oxiran-2-yl)decyl]oxirane
• CAS: 65520-48-1
• 化学式: C₁₄H₂₆O₂
• 分子量: 226.359
• InChiKey: GMOUFZQRQCICEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2:13,14-二环氧十四烷 在 (1R,2R)-(-)-N,N'-bis(3,5-di-tert-butylsalicydene)-1,2-cyclohexanediaminocobalt(II) 、 水 、 二正丁基氧化锡 、 溶剂黄146 、 三乙胺 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 16.0h， 生成 (S)-2-hydroxy-12-((R)-oxiran-2-yl)dodecyl-4-methylbenzenesulfonate
  参考文献：
  名称：

  Hydrolytic and Aminolytic Kinetic Resolution of Terminal Bis-Epoxides

  摘要：

  Hydrolytic and aminolytic kinetic resolution of terminal bis-epoxides catalyzed by (salen)Co-III complexes affords epoxy-diols and N-protected epoxy-amino alcohols with excellent enantio- and diastereoselectivity and good yields. An operationally simple procedure gives instant access to valuable building blocks containing two remote stereocenters in highly enantioenriched form.

  DOI：

  10.1021/jo3024335
• 作为产物：
  描述：

  (1,13-十四烷二)烯 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 2.5h， 以92%的产率得到1,2:13,14-二环氧十四烷
  参考文献：
  名称：

  产乙酸原蛋白的线性氮杂和硫代类似物的合成及其细胞毒性的评价

  摘要：

  根据一般的合成路线，合成了四无氮产乙酸甘油酯的四个氮杂和两个硫代类似物。通过末端双环氧化物的水解动力学拆分，一步一步将类似物中的两个远程立体中心设置为具有高对映体和非对映体选择性。

  DOI：

  10.1002/ejoc.201300767

文献信息

• Sulfonium salt, curable composition, ink composition, inkjet recording method, printed material, process for producing lithographic printing plate, and lithographic printing plate
  申请人：Tsuchimura Tomotaka

  公开号：US20070197677A1

  公开（公告）日：2007-08-23

  A sulfonium salt is provided that has a cation represented by Formula (II) (R 1′ to R 13′ in Formula (II) independently denote a hydrogen atom or a substituent, and may be bonded to each other to form a ring, provided that at least one of R 1′ to R 8′ denotes a halogen atom or a haloalkyl group). There are also provided a curable composition that includes the sulfonium salt, and an ink composition that includes the curabie composition. Furthermore, there are also provided an inkjet recording method employing the ink composition, and a process for producing a lithographic printing plate, the process including discharging the ink composition onto a hydrophilic support. A printed material and a lithographic printing plate thus obtained are also included in the present invention.

  提供一种具有由化学式（II）表示的阳离子的硫铵盐（其中，化学式（II）中的R1'到R13'独立地表示氢原子或取代基，并且它们可以结合在一起形成环，前提是R1'到R8'中至少有一个表示卤素原子或卤代烷基）。还提供了包括该硫铵盐的可固化组合物，以及包括该可固化组合物的油墨组合物。此外，还提供了一种采用该油墨组合物的喷墨记录方法，以及生产平版印刷版的工艺，其中该工艺包括将油墨组合物排放到亲水性支撑体上。本发明还包括由此获得的印刷材料和平版印刷版。
• Composition and method for corrosion inhibition
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0176990A1

  公开（公告）日：1986-04-09

  A composition is provided which, when applied to a metal surface, forms a corrosion-inhibiting film thereon. The composition comprises the reaction product of a first component selected from an epoxy resin, an epoxidized alkene and a substrate having at least one displaceable halogen, and a second component comprising a monomercaptan in a hydrocarbon diluent. The composition is applied by contacting the metal surface with the composition. The composition is particularly useful in the treatment of down- well metal surfaces in oil and gas wells to inhibit the corrosion of the metal under highly corrosive conditions, and is effective even in the presence of polymeric permeability control agents such as aqueous polyacrylamides.

  本发明提供了一种组合物，当应用于金属表面时，可在其上形成一层腐蚀抑制膜。 该组合物包括选自环氧树脂、环氧化烯和具有至少一种可置换卤素的基质的第一组分与包括烃类稀释剂中的单硫醇的第二组分的反应产物。 通过将金属表面与该组合物接触来应用该组合物。 该组合物特别适用于处理油气井中的井下金属表面，以抑制金属在高腐蚀性条件下的腐蚀，即使在存在聚合物渗透性控制剂（如水性聚丙烯酰胺）的情况下也有效。
• Advanced epoxy compositions, curable compositions and cured products
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0486918A2

  公开（公告）日：1992-05-27

  Compositions are prepared by the reaction of (A) an advanced composition resulting from reacting (1) at least one of (a) at least one epoxidized triglyceride of a fatty acid, or (b) at least one epoxidized fatty acid having an average of more than one unsaturated group per molecule or (c) at least one diepoxyalkane, or (d) any combination of any two or more of (a), (b) or (c), or (e) a combination of any one or more of (a), (b) or (c) and (f) a diglycidyl ether of a dihydric phenol; with (2) a dihydric phenol; (B) optionally a monohydric phenol; (C) a phosphorus-containing compound; and (D) optionally a base. These compositions can be cured with curing agents which react with aliphatic hydroxyl groups.

  (A) 由以下物质中的至少一种反应生成的高级组合物：(1) (a) 至少一种环氧化脂肪酸甘油三酯、(c) 至少一种二环氧烷，或 (d) (a)、(b)或(c)中任何两种或两种以上的组合，或 (e)(a)、(b)或(c)中任何一种或两种以上的组合和 (f) 二氢酚的二缩水甘油醚；(2) 二水苯酚；(B) 可选的一水苯酚；(C) 含磷化合物；和 (D) 可选的碱。这些组合物可用与脂肪族羟基反应的固化剂固化。
• Polydiglycidylphenyl ethers of alkylene or alkylenoxy chains for use in microelectronics adhesives
  申请人：National Starch and Chemical Investment Holding Corporation

  公开号：EP0747370A1

  公开（公告）日：1996-12-11

  This invention relates to flexible epoxy resins characterized by a low ionic contamination, total chlorine content less than 0.1%. The epoxy resins are liquids at room temperatur, have Tg values when cured of less than or equal to 150°C, have neat resin viscosities of 25,000 cps or less at 25°C, and have a structural composition comprising an oligomeric backbone of alkylene or alkyleneoxy repeat units, terminated with an aromatic moiety bearing one or more epoxy functionalities: in which:    the flexible chain is CH2CH2CH2CH2O when r is an integer 1-10; or    the flexible chain is CH2CH20 when r is an integer 3-10; or    the flexible chain is CH2 when r is an integer 10-20; or ; or in which:    the flexible chain is CH2CH2CH2CH2O when q is an integer 1-6; or    the flexible chain is CH2CH20 when q is an integer 3-10.

  本发明涉及柔性环氧树脂，其特点是离子污染少，总氯含量小于 0.1%。环氧树脂在室温下为液体，固化时的 Tg 值小于或等于 150°C，25°C 时的纯树脂粘度小于或等于 25,000cps，其结构组成包括由亚烷基或亚烷氧基重复单元组成的低聚物骨架，以带有一个或多个环氧官能团的芳香族基团为端基： 其中 当 r 为 1-10 整数时，柔性链为 O；或 当 r 为 3-10 个整数时，柔性链为 0；或 当 r 为 10-20 个整数时，柔性链为 CH2；或 或 其中 当 q 为 1-6 个整数时，柔性链为 O；或 当 q 为 3-10 个整数时，柔性链为 0。
• Snap-cure epoxy adhesives
  申请人：National Starch and Chemical Investment Holding Corporation

  公开号：EP0748831A2

  公开（公告）日：1996-12-18

  This invention relates to adhesive formulations, which can be snap-cured without loss of adhesive strength (as measured by die shear strength) and flexibility (as measured by radius of curvature), comprising 20-80 parts by weight of a flexible epoxy resin and 80-20 parts by weight of an aromatic O-glycidyl ether (to a total 100 parts), a curing catalyst, and optionally one or more fillers.

  本发明涉及可快速固化而不损失粘合强度（以模头剪切强度衡量）和柔韧性（以曲率半径衡量）的粘合剂配方，该配方包括 20-80 份（按重量计）柔性环氧树脂和 80-20 份（按重量计）芳香族 O-缩水甘油醚（总计 100 份）、固化催化剂以及可选的一种或多种填料。