1,3,5-三硝基-2-苯基苯 | 29128-23-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,3,5-三硝基-2-苯基苯
• 英文名称: 2,4,6-Trinitro-biphenyl
• 英文别名: 2,4,6-Trinitrobiphenyl；1,3,5-trinitro-2-phenylbenzene
• CAS: 29128-23-2
• 化学式: C₁₂H₇N₃O₆
• 分子量: 289.204
• InChiKey: KXXIUGHYTQVIRG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  138
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,3,5-三硝基-2-苯基苯 、 potassium phenolate 以 二甲基亚砜 为溶剂， 反应 24.0h， 以25%的产率得到
  参考文献：
  名称：

  Buncel, Erwin; Murarka, Suresh Kumar; Norris, Albert Richard, Canadian Journal of Chemistry, 1984, vol. 62, p. 534 - 539

  摘要：

  DOI：
• 作为产物：
  描述：

  2,4,6-三硝基氯苯 、 三甲基(苯基)锡 在 iodophenylbis(triphenylphosphine)palladium 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 1.5h， 以96%的产率得到1,3,5-三硝基-2-苯基苯
  参考文献：
  名称：

  Kashin, N. A.; Bumagina, I. G.; Bumagin, N. A., Journal of Organic Chemistry USSR (English Translation), 1981, vol. 17, # 1, p. 18 - 24

  摘要：

  DOI：

文献信息

• Ferricyanide Oxidation of 4-Arylazo-2,6-di-<i>t</i>-butylphenols
  作者：Eiichiro Manda

  DOI：10.1246/bcsj.46.2160

  日期：1973.7

  Alkaline ferricyanide oxidation of 4-arylazo-2,6-di-t-butylphenols (I) gave molecular nitrogen, diphenyl derivatives (VI), 2,6-di-t-butyl-p-benzoquinone-N-(3′,5′-di-t-butyl-4′-hydroxyphenyl)arylhydrazone (V) and red tarry compounds. Picryl derivative of phenol (I) gave 2,6-di-t-butyl-p-benzoquinone-picrylanil (X) instead of hydrazone (V). The reaction path was studied on the basis of isolated compounds

  4-芳基偶氮-2,6-二叔丁基苯酚 (I) 的碱性铁氰化物氧化得到分子氮、二苯基衍生物 (VI)、2,6-二叔丁基-对苯醌-N-(3', 5'-二叔丁基-4'-羟基苯基）芳基腙（V）和红色焦油化合物。苯酚 (I) 的苦味基衍生物得到 2,6-二叔丁基-对苯醌-苦味基苯胺 (X)，而不是腙 (V)。在分离化合物的基础上研究了反应路径。
• Aromatic Arylation with Aryl Radicals. I. A Novel Method for Generating Aryl Free Radical
  作者：Michio Kobayashi、Hiroshi Minato、Nobumasa Kobori、Eiichi Yamada

  DOI：10.1246/bcsj.43.1131

  日期：1970.4

  evolution of nitrogen upon addition of a DMSO solution of sodium nitrite. Orientations and partial rate factors for phenylation of substituted benzenes indicated that not phenyl cation but phenyl radical was produced as an intermediate. Hammett’s plots of partial rate factors of meta and para positions yielded good straight lines with ρm=0.46 and ρp=1.67. Plausible mechanisms were discussed. From m-dinitrobenzene

  加入亚硝酸钠的 DMSO 溶液后，DMSO 中的苯重氮四氟硼酸盐立即分解，释放出氮气。取代苯苯基化的取向和部分速率因子表明，不是苯基阳离子而是苯基自由基作为中间体产生。哈米特的元和对位的部分速率因子图产生了很好的直线，ρm=0.46 和 ρp=1.67。讨论了合理的机制。从间二硝基苯中分别以 47% 和 23% 的产率生产了 2,6- 和 2,4- 二硝基联苯，并指出了该方法的合成价值。
• Apparatus and method for spatially detecting or quantifying chemical species
  申请人：General Electric Company

  公开号：US20030040118A1

  公开（公告）日：2003-02-27

  An apparatus provides for the detection, the determination of the location or the spatial distribution, and/or the quantification of an amount of a chemical species by allowing the chemical species to come into contact with a fluid medium contained in a permeable capillary, transferring the content of the capillary after the contact to a detector, and detecting the chemical species as the content of the capillary is transferred to a detector. The fluid medium can contain a selected reagent that selectively interacts with the chemical species to produce an optically detectable interaction product. The location and amount of the chemical species are determined from a characteristic of the chemical species or its interaction product measured on the content of the capillary and the time at which the characteristic is detected. The apparatus may be used in a method for detecting, determining the location or the spatial distribution of, and quantifying a wide range of chemical compounds, such as for monitoring chemicals in environment and industrial facilities and determining products in a combinatorial experiment.

  有一种仪器可以检测、确定化学物质的位置或空间分布，和/或量化化学物质的数量，其方法是让化学物质与可渗透毛细管中的流体介质接触，接触后将毛细管中的物质转移到检测器中，当毛细管中的物质转移到检测器中时检测化学物质。流体介质可以含有选择性试剂，该试剂可选择性地与化学物质相互作用，产生可光学检测的相互作用产物。根据在毛细管内容物上测量到的化学物质或其相互作用产物的特征以及检测到该特征的时间来确定化学物质的位置和数量。该装置可用于检测、确定各种化合物的位置或空间分布以及量化各种化合物的方法，例如用于监测环境和工业设施中的化学品以及确定组合实验中的产物。
• Opto-acoustic wave chemical sensor
  申请人：General Electric Company

  公开号：US20030053936A1

  公开（公告）日：2003-03-20

  An opto-acoustic wave sensor provides for the detection, the determination of the location, and/or the quantification of an amount of a chemical species using a selective chemical interaction of the chemical species and a selective reagent disposed on a surface of the opto-acoustic wave sensing element. The amount of the chemical species is detected by a change in the mass of the opto-acoustic wave-sensing element, which results in a detectable change in a resonance frequency of the sensing element. The identity of the chemical species is ascertained by an optical property of the product of the selective chemical interaction such as an absorbance or an intensity or other properties of the electromagnetic radiation emitted by the product. The sensor may be used in a method for detecting, determining the location or the spatial distribution of, and quantifying a wide range of chemical compounds, such as for monitoring chemicals in environment and industrial facilities and determining products in a combinatorial experiment.

  一种光声波传感器可利用化学物质与设置在光声波传感元件表面的选择性试剂之间的选择性化学作用来检测、确定化学物质的位置和/或量化化学物质的数量。光声波传感元件的质量变化会导致传感元件的共振频率发生可检测的变化，从而检测出化学物质的数量。化学物质的特性可通过选择性化学作用产物的光学特性（如吸光度或强度）或产物发射的电磁辐射的其他特性来确定。该传感器可用于检测、确定各种化合物的位置或空间分布以及量化各种化合物的方法，例如用于监测环境和工业设施中的化学品以及确定组合实验中的产物。
• Opto-acoustic sensor system and associated method
  申请人：Potyrailo Alexandrovich Radislav

  公开号：US20060210440A1

  公开（公告）日：2006-09-21

  A system that includes a device is provided in which the device includes a piezoelectric substrate; a sensor layer disposed on the substrate and operable to interact with, or react with, a target species; a first and a second electrode that are spaced from each other and in communication with the substrate; a first detector operable to detect the interaction or the reaction of the sensor layer with the target species based on a change in an optical characteristic of electromagnetic radiation propagated through the substrate; and a second detector operable to acoustically detect the interaction or the reaction of the sensor layer with the target species. Associated methods are provided.

  提供了一种包括装置的系统，其中装置包括压电基板；设置在基板上并可与目标物质相互作用或反应的传感器层；彼此间隔并与基板通信的第一和第二电极；可根据传播通过基板的电磁辐射的光学特性变化检测传感器层与目标物质的相互作用或反应的第一检测器；以及可声学检测传感器层与目标物质的相互作用或反应的第二检测器。还提供了相关的方法。