1,3-丁二烯与2-甲基-1,3-丁二烯的聚合物 | 25102-52-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 中文名称: 1,3-丁二烯与2-甲基-1,3-丁二烯的聚合物
• 英文名称: Isoprene butadiene
• 英文别名: buta-1,3-diene;2-methylbuta-1,3-diene
• CAS: 25102-52-7
• 化学式: C9H14
• 分子量: 122.21
• InChiKey: VLLYOYVKQDKAHN-UHFFFAOYSA-N

物化性质

• 熔点：
  41 °C
• 密度：
  0.92 g/mL at 25 °C(lit.)
• 稳定性/保质期：

  遵照规定使用和储存，则不会分解。

计算性质

• 辛醇/水分配系数(LogP)：
  3.11
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,3-丁二烯与2-甲基-1,3-丁二烯的聚合物 、 苯甲酸苯酯 以 异丙醇 为溶剂， 反应 1.5h， 生成 Isoprene Butadiene Isoprene
  参考文献：
  名称：

  Solid block elastomeric copolymers

  摘要：

  本发明揭示了一种线性嵌段共聚物，包括至少一个三嵌段I-B-I，其中I是至少5个碳原子的聚合共轭二烯块，例如异戊二烯，B是至少4个碳原子的聚合共轭二烯块，不同于式（1）的共轭二烯块，例如1,3-丁二烯。B块被选择性氢化，而每个I块保留足够的原始不饱和度以使共聚物硫化。还揭示了一种替代的线性嵌段共聚物，其中至少包含一个由芳基取代的烯烃制成的第一聚合物块的三嵌段，例如苯乙烯，以及用于聚合块I的共轭二烯，用于聚合块B的第二个中间聚合物块和与第一聚合物块相同的第三聚合物块。在这种替代共聚物中，中间块也被选择性氢化，从而使末端聚合物块具有足够的双键以使共聚物硫化。可以通过含有乙烯不饱和度的末端块交联或功能化聚合物。还揭示了由与线性嵌段共聚物相同的单体制成的随机和星形嵌段共聚物和随机共聚物。还揭示了生产和选择性氢化聚合物的方法。

  公开号：

  US05306780A1
• 作为产物：
  描述：

  对叔丁基邻苯二酚 、 四甲基乙二胺 在 silica 、 铝 、 天然橡胶 、 1,3-丁二烯 、 hexanes 、 one-gallon 、 solution 、 正丁基锂 、 四氯化锡 作用下， 以 one-gallon 为溶剂， 反应 3.5h， 生成 1,3-丁二烯与2-甲基-1,3-丁二烯的聚合物
  参考文献：
  名称：

  Process for making tin-coupled rubbery polymers

  摘要：

  本发明公开了一种制备不对称锡偶联橡胶聚合物的过程，包括：(1)在第一反应器中连续聚合至少一种二烯单体，利用阴离子引发剂使得转化率至少达到90％，产生含有活性聚二烯橡胶链的聚合物水泥；(2)将在第一反应器中产生的聚合物水泥连续进料至第二反应器；(3)在第二反应器中加入锡卤化物，并在搅拌条件下使其均匀分散在聚合物水泥中，其中在第二反应器中的停留时间在约15分钟至约4小时的范围内；(4)将具有均匀分散锡卤化物的聚合物水泥连续进料至塞流反应器中，其停留时间在约15分钟至约1小时的范围内，以产生不对称锡偶联橡胶聚合物的聚合物水泥；(5)从塞流反应器中连续取出不对称锡偶联橡胶聚合物的聚合物水泥。通过该过程制备的不对称锡偶联橡胶聚合物在老化时表现出改善的稳定性。

  公开号：

  US06075095A1

文献信息

• Multilayer film for packaging
  申请人：——

  公开号：US20010014384A1

  公开（公告）日：2001-08-16

  A multilayer film for packaging which is superior in, such as extensible elasticity, ability for adhering onto various surfaces, transparency, clear cutting performance, heat-sealability, resistance to fogging, resistance to break-through and ability for restoring from finger pressing and which comprises outer layers made of the outer layer resin composition (I) or (II) given below and an inner layer made of an inner layer resin composition composed of a higher melting component (III) and a softening component (IV) interposed between the outer layers, wherein the resin composition (I) comprises 59.5-99.5% by weight of (A) an ethylene/&agr;-olefin copolymer component, which is composed of at least one copolymer of ethylene and an &agr;-olefin having 3-20 carbon atoms and which has a melt flow rate (MFR) of 0.1-10 g/10 min. and a density of 0.850 g/cm 3 -0.910 g/cm 3 ; 0-40% by weight of (B) a high-pressure process low density polyethylene having a density of 0.915-0.930 g/cm 3 , and 0.5-10% by weight of (C) an anti-fogging agent, and wherein the resin composition (II) comprises 99.5-90% by weight of (D) an ethylene/vinyl acetate copolymer, which is a copolymer of ethylene and vinyl acetate and has a vinyl acetate content of 10-30% by weight and an MFR of 0.5-30 g/10 min., and 0.5-10% by weight of (C) anti-fogging agent.

  一种用于包装的多层薄膜，具有伸缩弹性、能够附着在各种表面上、透明、易于切割、热封性能、防雾性能、防穿透性和能够从手指按压中恢复等优点，包括由下列外层树脂组分(I)或(II)制成的外层和由高熔点组分(III)和软化组分(IV)组成的内层树脂组分组成的内层，其中树脂组分(I)包括：59.5-99.5重量％的(A)乙烯/α-烯烃共聚物组分，由乙烯和一种具有3-20个碳原子的α-烯烃的至少一种共聚物组成，具有熔融流速(MFR)为0.1-10 g/10 min.和密度为0.850 g/cm3-0.910 g/cm3；0-40重量％的(B)高压过程低密度聚乙烯，密度为0.915-0.930 g/cm3；0.5-10重量％的(C)防雾剂；树脂组分(II)包括：99.5-90重量％的(D)乙烯/醋酸乙烯共聚物，是乙烯和醋酸乙烯的共聚物，醋酸乙烯含量为10-30重量％，MFR为0.5-30 g/10 min.；0.5-10重量％的(C)防雾剂。
• Solid block and random elastomeric copolymers
  申请人：Mobil Oil Corporation

  公开号：US05187236A1

  公开（公告）日：1993-02-16

  There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of a polymerized conjugated diene of at least 5 carbon atoms, such as isoprene, and B is a block of a polymer of a conjugated diene, different from that of formula (1), of at least 4 carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from an aryl-substituted olefin, such as sytrene, and the conjugated diene used to polymerize the block I, the second middle polymer block of the diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block. In this alternative copolymer, the middle block is also selectively hydrogenated, thereby leaving the terminal polymer blocks with a sufficient amount of double bonds to vulcanize the copolymer. The polymers can be crosslinked or functionalized through the terminal blocks containing the vinyl unsaturation. There are also disclosed random and star-branched block and random copolymers made from the same monomers as the linear block copolymers. Also disclosed are methods of producing and selectively hydrogenating the polymers.

  本文公开了一种线性嵌段共聚物，其中至少包含一个三嵌段I-B-I，其中I是至少含有5个碳原子的共轭二烯聚合物块，如异戊二烯，B是至少含有4个碳原子的不同于公式（1）的共轭二烯聚合物块，如1,3-丁二烯。B块被选择性氢化，而每个I块保留足够数量的不饱和度以使共聚物硫化。还公开了一种替代性线性嵌段共聚物，其中至少包含一个三嵌段，第一个聚合物块由芳基取代的烯烃制成，如苯乙烯，第二个中间聚合物块由用于聚合块B的二烯制成，第三个聚合物块与第一个聚合物块相同。在这种替代共聚物中，中间块也被选择性氢化，因此留下具有足够双键数量以使共聚物硫化的末端聚合物块。这些聚合物可以通过含有乙烯不饱和度的末端块交联或官能化。还公开了由与线性嵌段共聚物相同的单体制成的随机和星形支化嵌段共聚物和随机共聚物。还公开了制备和选择性氢化聚合物的方法。
• Process for preparing a catalyst system useful in the synthesis of
  申请人：The Goodyear Tire & Rubber Company

  公开号：US05405815A1

  公开（公告）日：1995-04-11

  The subject invention relates to a technique for synthesizing rubbery non-tapered, random, copolymers of 1,3-butadiene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire sidewall rubber compounds for truck tires. By utilizing these isoprene-butadiene rubbers in tire sidewalls, tires having improved cut growth resistance can be built without sacrificing rolling resistance. Such rubbers can also be employed in tire tread compounds to improve tread wear characteristics and decrease rolling resistance without sacrificing traction characteristics. This invention more specifically discloses a process for the synthesis of isoprene-butadiene rubbers which comprises copolymerizing isoprene monomer and 1,3-butadiene monomer in an organic solvent in the presence of a catalyst system which is made by the sequential steps of (1) mixing (a) an organoaluminum hydride, (b) a member selected from the group consisting of aliphatic alcohols, cycloaliphatic alcohols, aliphatic thiols, cycloaliphatic thiols, trialkyl silanols, and triaryl silanols, and (c) optionally, 1,3-butadiene in an organic solvent to produce a modified organoaluminum catalyst component; (2) adding an organometallic compound which contains a metal from Group III-B of the Periodic System to the modified organoaluminum catalyst component to produce a Group III-B metal containing catalyst component; and (3) adding a compound which contains at least one labile halogen atom to the Group III-B metal containing catalyst component.

  本发明涉及一种合成1,3-丁二烯和异戊二烯的橡胶非锥形随机共聚物的技术。这些橡胶共聚物在卡车轮胎侧壁橡胶复合材料中展现出优异的性能组合。通过在轮胎侧壁中使用这些异戊二烯-丁二烯橡胶，可以制造出具有更好的抗切割性能的轮胎，而不会牺牲滚动阻力。这些橡胶还可以用于轮胎胎面复合材料，以改善胎面磨损特性并降低滚动阻力，而不会牺牲牵引特性。本发明更具体地揭示了一种合成异戊二烯-丁二烯橡胶的过程，其中包括在有机溶剂中存在催化剂体系的情况下，共聚合异戊二烯单体和1,3-丁二烯单体。该催化剂体系由以下步骤制成：(1)将(甲)有机铝氢化物、(乙)选自脂肪族醇、环状脂肪族醇、脂肪族硫醇、环状脂肪族硫醇、三烷基硅醇和三芳基硅醇的成员以及(丙)可选的1,3-丁二烯在有机溶剂中混合，以产生改性有机铝催化剂组分；(2)向改性有机铝催化剂组分中添加含有周期表III-B族金属的有机金属化合物，以产生含有III-B族金属的催化剂组分；(3)向含有III-B族金属的催化剂组分中添加至少含有一个活性卤素原子的化合物。
• Polymer/clay nanocomposite materials and process for the preparation thereof
  申请人：Li Yang

  公开号：US20050282948A1

  公开（公告）日：2005-12-22

  The present invention relates to nanocomposite materials based on a copolymer of at least two monomers selected from the group consisting of butadiene, isoprene and styrene and a clay mineral dispersed therein, and a process for preparing them. By using an organolithium as the initiator, an organic hydrocarbon solvent as the solvent and a polar additive as the microstructure modifier by means of a classical anionic solution polymerization process, at least two monomers selected from the group consisting of butadiene, isoprene and styrene are in-situ intercalation polymerized in the presence of an organoclay, thereby obtaining a delaminated nanocomposite material which is excellent in mechanical properties, heat resistance, barrier property, chemical resistance and is well balanced in its comprehensive properties.

  本发明涉及一种基于至少两种单体的共聚物的纳米复合材料，所述单体选自丁二烯、异戊二烯和苯乙烯组成的群体，并且其中分散有一种粘土矿物，以及一种制备它们的方法。通过使用有机锂作为引发剂，有机烃溶剂作为溶剂，极性添加剂作为微结构调节剂，通过经典的阴离子溶液聚合过程，在有机粘土的存在下原位插层聚合至少选自丁二烯、异戊二烯和苯乙烯的两种单体，从而获得一种剥离的纳米复合材料，其在机械性能、耐热性、屏障性能、化学耐受性方面表现出色，并且在其综合性能方面平衡良好。
• Thermoplastic elastomer composition
  申请人：Kuraray Company, Ltd.

  公开号：US05436295A1

  公开（公告）日：1995-07-25

  A thermoplastic elastomer composition comprises the following two components: (a) a thermoplastic polyurethane having soft segments from a poly (3-methyl-1,5-pentane adipate) diol having a molecular weight of at least 2,000 and having a JIS A hardness at 25.degree. C. of not more than 80, and (b) a block copolymer comprising at least 2 polymer blocks A principally comprising an aromatic vinyl compound and at least 1 block B comprising an olefinic elastomer, said aromatic vinyl compound being contained in an amount of 5 to 50% by weight based on the weight of the block copolymer and the olefinic elastomer block having a glass transition point of not higher than -20.degree. C. and a heat of fusion of crystal of not more than 8 cal/g; the ratio by weight between the component (a) and the component (b) being (a)/(b)=95/5 to 5/95.

  一种热塑性弹性体组合物包括以下两个组分：(a)热塑性聚氨酯，其软段来自具有分子量至少为2,000的聚（3-甲基-1,5-戊二酸酯）二元醇，并且其在25℃下的JIS A硬度不超过80；(b)嵌段共聚物，包括至少2个聚合物块A，主要包含芳香族乙烯化合物，以及至少1个块B，包含烯烃弹性体，所述芳香族乙烯化合物在嵌段共聚物重量的5%至50%之间，并且烯烃弹性体块的玻璃化转变温度不高于-20℃，结晶热不超过8 cal/g；组分(a)和组分(b)的重量比为(a)/(b)=95/5至5/95。