1-(呋喃-3-基)戊烷-1,4-二酮 | 496-06-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-(呋喃-3-基)戊烷-1,4-二酮
• 中文别名: 甘薯黑疤霉二酮
• 英文名称: 1-(furan-3-yl)pentane-1,4-dione
• 英文别名: ipomeanine；1-furan-3-yl-pentane-1,4-dione；1-[3]furyl-pentane-1,4-dione；1-[3]Furyl-pentan-1,4-dion；3-<1,4-Dioxo-pentyl>-furan；3-(γ-Oxovaleroyl)-furan
• CAS: 496-06-0
• 化学式: C₉H₁₀O₃
• mdl: MFCD01709274
• 分子量: 166.177
• InChiKey: VUENWDJSJYJARL-UHFFFAOYSA-N

物化性质

• 熔点：
  42.5°C
• 沸点：
  234.38°C (rough estimate)
• 密度：
  1.1097 (rough estimate)
• LogP：
  0.670 (est)
• 物理描述：
  Solid

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.333
• 拓扑面积：
  47.3
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2932190090

反应信息

• 作为反应物：
  描述：

  1-(呋喃-3-基)戊烷-1,4-二酮 、 乙醇 、 盐酸氨基脲 、 potassium acetate 生成 (2-[3]furyl-5-methyl-pyrrol-1-yl)-urea
  参考文献：
  名称：

  Chemical Studies on the Black Rot Disease of Sweet Potatoes. XVII. Abnormal Semicarbazone of Ipomeanine and of Related Compounds

  摘要：

  DOI：

  10.1246/bcsj.38.1191
• 作为产物：
  描述：

  (4R)-1-(furan-3-yl)-4,8-dimethylnonane-1,4,6-triol 在 Celite 、 silver carbonate 作用下， 以 苯 为溶剂， 反应 3.0h， 生成 1-(呋喃-3-基)戊烷-1,4-二酮
  参考文献：
  名称：

  The configuration of the sesquiterpenoid 4-hydroxy-myoporone (athanagrandione)

  摘要：

  DOI：

  10.1016/s0031-9422(00)80452-5

文献信息

• Volatile constituents of black-rotted sweet potato and related substances
  作者：Takashi Kubota

  DOI：10.1016/0040-4020(58)88007-2

  日期：1958.1

  From the volatile component of sweet potatoes infected by Ceratostomella fimbriata (“black rotted” disease), four β-substituted furans, viz. ipomeamarone (1), batatic acid (45), ipomeanine (47) and β-furan carboxylic acid were isolated. The chemical constitutions of the former three compounds were determined by degradations and by synthesis. The chemical constitution of β-substituted furans, viz. ngaione

  从感染了Ceratostomella fimbriata（“黑腐烂”病）的甘薯的挥发性成分中，得到四种β-取代的呋喃。分离得到ipomeamarone（1），batatic酸（45），ipomeanine（47）和β-呋喃羧酸。前三种化合物的化学组成通过降解和合成来确定。β-取代的呋喃的化学组成，即。测定了从Myoporum植物精油中分离得到的ngaione（52）和myoporon（53），并建立了ipomeamarone，ngaione和myoporone的关系。
• Synthesis of 3-Acylfurans Using 3-(Phenylthio)propanal Dimethyl Acetal as a New Synthon. Syntheses of Ipomeanine and Isoegomaketone
  作者：Eiji Watanabe、Naohiro Imai、Katsuhiko Inomata、Hideki Kinoshita、Hiroshi Kotake

  DOI：10.1246/bcsj.55.3225

  日期：1982.10

  It was found that 3-(phenylthio)propanal dimethyl acetal is a very useful starting material for the preparation of 3-acylfuranoterpenes. Syntheses of two naturally-occurring furans, isoegomaketone and ipomeanine were described.

  发现3-(苯硫基)丙醛二甲基缩醛是用于制备3-酰基呋喃萜的非常有用的起始原料。描述了两种天然呋喃、异己酮和伊波米宁的合成。
• ACIDOPHILIC FUSARIUM OXYSPORUM STRAIN, METHODS OF ITS GROWTH AND METHODS OF ITS USE
  申请人：The Fynder Group, Inc.

  公开号：EP3712248A1

  公开（公告）日：2020-09-23

  The present invention provides isolated acidophilic Fusarium oxysporum strain MK7, or a progeny thereof, compositions comprising this strain or a progeny thereof, methods of growing the strain or a progeny thereof, and methods of using the strain or a progeny thereof.

  本发明提供了分离的嗜酸镰孢菌株 MK7 或其后代、包含该菌株或其后代的组合物、培养该菌株或其后代的方法以及使用该菌株或其后代的方法。
• Acidophilic fusarium oxysporum strains, methods of their production and methods of their use
  申请人：Sustainable Bioproducts, Inc.

  公开号：US10344306B2

  公开（公告）日：2019-07-09

  The present invention provides isolated acidophilic Fusarium oxysporum strains, such as MK7, and their progeny, compositions comprising such strains and their progeny, methods of producing such strains and their progeny, and methods of using such strains and their progeny.

  本发明提供了分离的嗜酸镰孢菌株（如 MK7）及其后代、包含这些菌株及其后代的组合物、生产这些菌株及其后代的方法以及使用这些菌株及其后代的方法。
• Synthesis of 1,4-diketones by palladium-catalyzed reductive coupling of acid chlorides with (E)-1,2-bis(tri-n-butylstannyl)ethene or .beta.-stannyl enones
  作者：Marta Perez、Ana M. Castano、Antonio M. Echavarren

  DOI：10.1021/jo00045a002

  日期：1992.9

  The palladium-catalyzed coupling of acid chlorides with (E)-1,2-bis(tri-n-butylstannyl)ethene or beta-stannyl enones gives butane-1,4-diones directly by reduction of the intermediate enedicarbonyl derivative by a palladium hydride derived from n-Bu3SnCl.