1-丁基-3-甲基环戊-3-烯-1-醇 | 143398-15-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-丁基-3-甲基环戊-3-烯-1-醇
• 英文名称: 3-Cyclopenten-1-ol, 1-butyl-3-methyl-
• 英文别名: 1-butyl-3-methylcyclopent-3-en-1-ol
• CAS: 143398-15-6
• 化学式: C₁₀H₁₈O
• 分子量: 154.252
• InChiKey: JJWMJZGVPWKFIV-UHFFFAOYSA-N

物化性质

• 沸点：
  221.6±9.0 °C(Predicted)
• 密度：
  0.929±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  戊酸甲酯 、 天然橡胶 以 四氢呋喃 为溶剂， 以76%的产率得到1-丁基-3-甲基环戊-3-烯-1-醇
  参考文献：
  名称：

  Electroorganic chemistry. 138. Electrochemically promoted cyclocoupling of 1,3-dienes or styrenes with aliphatic carboxylic esters

  摘要：

  The cathodic cyclocoupling of 1,3-dienes 1 with aliphatic esters 2 is promoted by a magnesium electrode and yields homologs of 3-cyclopentenol. Under similar reaction conditions, the coupling of styrenes with 2 affords 2-phenylcyclopropanol derivatives, and this coupling reaction has been successfully applied to the synthesis of ar-dihydroturmerone and curcumone.

  DOI：

  10.1021/jo00047a003

文献信息

• Electroorganic chemistry. 138. Electrochemically promoted cyclocoupling of 1,3-dienes or styrenes with aliphatic carboxylic esters
  作者：Tatsuya Shono、Manabu Ishifune、Hiroshi Kinugasa、Shigenori Kashimura

  DOI：10.1021/jo00047a003

  日期：1992.10

  The cathodic cyclocoupling of 1,3-dienes 1 with aliphatic esters 2 is promoted by a magnesium electrode and yields homologs of 3-cyclopentenol. Under similar reaction conditions, the coupling of styrenes with 2 affords 2-phenylcyclopropanol derivatives, and this coupling reaction has been successfully applied to the synthesis of ar-dihydroturmerone and curcumone.