1-乙烯基-4-[3-(4-乙烯基苯氧基)丙氧基]苯 | 112309-97-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 1-乙烯基-4-[3-(4-乙烯基苯氧基)丙氧基]苯
• 英文名称: 1,3-bis(4-vinylphenoxy)propane
• 英文别名: 1,1'-[Propane-1,3-diylbis(oxy)]bis(4-ethenylbenzene)；1-ethenyl-4-[3-(4-ethenylphenoxy)propoxy]benzene
• CAS: 112309-97-4
• 化学式: C₁₉H₂₀O₂
• 分子量: 280.367
• InChiKey: AKYUVHNMXAPIOI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-乙烯基-4-[3-(4-乙烯基苯氧基)丙氧基]苯 、 亚硝基苯 在 ytterbium(III) triflate 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 36.0h， 以30%的产率得到2,4-bis(4-(3-(4-vinylphenoxy)propoxy)phenyl)quinoline
  参考文献：
  名称：

  Lewis acid catalyzed reactivity switch: pseudo three-component annulation of nitrosoarenes and (epoxy)styrenes

  摘要：

  Lewis酸催化的环化模式改变允许通过硝基芳烃的C-H官能化和（环氧）苯乙烯的C-C断裂形成芳基喹啉。

  DOI：

  10.1039/d0cc02650f
• 作为产物：
  描述：

  对羟基苯甲醛 在 sodium hydride 、 potassium carbonate 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 、 mineral oil 为溶剂， 反应 24.0h， 生成 1-乙烯基-4-[3-(4-乙烯基苯氧基)丙氧基]苯
  参考文献：
  名称：

  Lewis acid catalyzed reactivity switch: pseudo three-component annulation of nitrosoarenes and (epoxy)styrenes

  摘要：

  Lewis酸催化的环化模式改变允许通过硝基芳烃的C-H官能化和（环氧）苯乙烯的C-C断裂形成芳基喹啉。

  DOI：

  10.1039/d0cc02650f

文献信息

• VINYL ETHER-BASED STAR POLYMER AND PROCESS FOR PRODUCTION THEREOF
  申请人：Maruzen Petrochemical Co., Ltd.

  公开号：EP2465885A1

  公开（公告）日：2012-06-20

  Provided is a vinyl ether-based star polymer that has arms containing a copolymer of a vinyl ether-based polymer and a oxystyrene-based polymer, and a process for production of the star polymer that is capable of being carried out continuously in a series of steps. The process includes a vinyl ether-based star polymer having arms containing a copolymer of a vinyl ether-based polymer and an oxystyrene-based polymer, and a process for production of the vinyl ether-based star polymer, containing: subjecting a vinyl ether-based monomer to living cationic polymerization in the presence of an initiating species, a Lewis acid that is suitable for cationic polymerization of the vinyl ether-based monomer, and a solvent; then subjecting an oxystyrene-based monomer to living cationic polymerization with a Lewis acid that is suitable for cationic polymerization of the oxystyrene-based monomer added thereto; adding a divinyl compound to introduce a vinyl group to a side chain; and forming a core through intermolecular crosslinking with the vinyl group.

  本发明提供了一种乙烯基醚基星形聚合物，该聚合物具有含有乙烯基醚基聚合物和氧苯乙烯基聚合物共聚物的臂，还提供了一种能够通过一系列步骤连续进行的生产该星形聚合物的工艺。该工艺包括一种乙烯基醚基星型聚合物，其臂含有乙烯基醚基聚合物和氧苯乙烯基聚合物的共聚物，以及一种生产乙烯基醚基星型聚合物的工艺，该工艺包括：使乙烯基醚基单体在引发剂、适用于乙烯基醚基单体阳离子聚合的路易斯酸和溶剂的存在下进行活阳离子聚合；然后使氧苯乙烯基单体与加入其中的适用于氧苯乙烯基单体阳离子聚合的路易斯酸进行活阳离子聚合；加入二乙烯基化合物以向侧链引入乙烯基；以及通过与乙烯基的分子间交联形成芯。
• METALLIC NANOPARTICLE COMPOSITE AND METHOD FOR PRODUCING THE SAME
  申请人：Maruzen Petrochemical Co., Ltd.

  公开号：EP2669029A1

  公开（公告）日：2013-12-04

  Provided are a metal nanoparticle composite which exhibits excellent stability over time and retention stability and is useful as a raw material for a metal nanoparticle-dispersed film, a method for producing the composite, a metal nanoparticle dispersion liquid, a composition for forming a metal nanoparticle-dispersed film, and a metal nanoparticle-dispersed film. Disclosed is a metal nanoparticle composite comprising (A) a star-shaped polymer having a central core and arms bonded to the central core, the arms comprising a repeating unit represented by the following formula (1) and a repeating unit represented by the following formula (2); and (B) metal nanoparticles supported thereon: wherein in the formula (1), R1 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; and in the formula (2), R2 represents a methyl group or an ethyl group; and k represents an integer from 1 to 10.

  本发明提供了一种金属纳米粒子复合材料，该复合材料具有优异的长期稳定性和保留稳定性，可用作金属纳米粒子分散膜的原料；还提供了一种生产该复合材料的方法、一种金属纳米粒子分散液、一种用于形成金属纳米粒子分散膜的组合物以及一种金属纳米粒子分散膜。公开了一种金属纳米粒子复合材料，包括(A)星形聚合物，该聚合物具有中心芯和与中心芯结合的臂，臂包括下式(1)代表的重复单元和下式(2)代表的重复单元；以及(B)支撑在其上的金属纳米粒子：其中，在式(1)中，R1代表氢原子或具有 1 至 4 个碳原子的烷基；在式(2)中，R2 代表甲基或乙基；以及 k 代表 1 至 10 的整数。
• METAL NANOPARTICLE COMPOSITE AND METHOD FOR PRODUCING THE SAME
  申请人：Yoshida Norihiro

  公开号：US20140058028A1

  公开（公告）日：2014-02-27

  Provided are a metal nanoparticle composite which exhibits excellent stability over time and retention stability and is useful as a raw material for a metal nanoparticle-dispersed film, a method for producing the composite, a metal nanoparticle dispersion liquid, a composition for forming a metal nanoparticle-dispersed film, and a metal nanoparticle-dispersed film. Disclosed is a metal nanoparticle composite comprising (A) a star-shaped polymer having a central core and arms bonded to the central core, the arms comprising a repeating unit represented by the following formula (1) and a repeating unit represented by the following formula (2); and (B) metal nanoparticles supported thereon: wherein in the formula (1), R 1 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; and in the formula (2), R 2 represents a methyl group or an ethyl group; and k represents an integer from 1 to 10.
• US9598553B2
  申请人：——

  公开号：US9598553B2

  公开（公告）日：2017-03-21
• Lewis acid catalyzed reactivity switch: pseudo three-component annulation of nitrosoarenes and (epoxy)styrenes
  作者：Anisha Purkait、Subhajit Saha、Santanu Ghosh、Chandan K. Jana

  DOI：10.1039/d0cc02650f

  日期：——

  Lewis acid catalyzed alteration of annulation pattern allowed formation of arylquinolines via C–H functionalization of nitrosoarenes and C–C cleavage of (epoxy)styrene.

  Lewis酸催化的环化模式改变允许通过硝基芳烃的C-H官能化和（环氧）苯乙烯的C-C断裂形成芳基喹啉。