1-叔丁基过氧丁烷 | 33324-93-5

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 1-叔丁基过氧丁烷
• 英文名称: n-Butyl-tert-butyl-peroxid
• 英文别名: 1-(tert-Butylperoxy)butane；1-tert-butylperoxybutane
• CAS: 33324-93-5
• 化学式: C₈H₁₈O₂
• 分子量: 146.23
• InChiKey: GOAHRBQLKIZLKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-叔丁基过氧丁烷 、 环己烯 生成 聚合甲醛 、 丙酮 、 叔丁醇 、 正丁醇
  参考文献：
  名称：

  Decompositions of Di-t-alkyl Peroxides. V. Relative Stabilities of Alkoxy Radicals Derived from Unsymmetrical Dialkyl Peroxides

  摘要：

  DOI：

  10.1021/ja01157a089
• 作为产物：
  描述：

  正溴丁烷 、 叔丁基过氧化氢 在 氢氧化钾 、 苄基三乙基氯化铵 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 以38%的产率得到1-叔丁基过氧丁烷
  参考文献：
  名称：

  Moulines, Jean; Bougeois, Marie-Josephe; Campagnole, Monique, Synthetic Communications, 1990, vol. 20, # 3, p. 349 - 353

  摘要：

  DOI：

文献信息

• METALLIC CROSSLINKING COAGENT, PREPARATION METHODS THEREOF, AND RESIN COMPOSITION COMPRISING THE SAME
  申请人：KUO CHING CHEMICAL CO., LTD.

  公开号：US20160326196A1

  公开（公告）日：2016-11-10

  Provided are a metallic crosslinking coagent, preparation methods thereof, and a resin composition comprising the metallic crosslinking coagent. With the active-hydrogen containing organic phosphorus compound group and metallophilic acrylate group, the metallic crosslinking coagent provides both stabilizer and flame-retardant effects, enhances the crosslinking efficiency of the resin composition, and improves the compatibility between flame retardant and the polymer. Accordingly, the metallic crosslinking coagent is effective to improve the mechanical properties of the application material and to develop a safe and environmentally friendly flame retardant material.

  提供了一种金属交联交联剂，其制备方法，以及包含该金属交联交联剂的树脂组合物。金属交联交联剂具有活性氢含有机磷化合物基团和金属亲和丙烯酸酯基团，提供了稳定剂和阻燃效果，增强了树脂组合物的交联效率，并改善了阻燃剂与聚合物之间的相容性。因此，金属交联交联剂有效地提高了应用材料的机械性能，并开发了一种安全和环保的阻燃材料。
• A convenient and general preparation of alkyl hydroperoxides and dialkyl peroxides
  作者：Peter G. Cookson、Alwyn G. Davies、Brian P. Roberts

  DOI：10.1039/c39760001022

  日期：——

  Primary, secondary, and tertiary alkyl hydroperoxides and dialkyl peroxides can be prepared from the appropriate alkyl bromide or iodide and hydrogen peroxide or alkyl hydroperoxide in the presence of silver trifluoroacetate.

  伯，仲和叔烷基氢过氧化物和二烷基过氧化物可以在三氟乙酸银存在下由合适的烷基溴或碘化物和过氧化氢或烷基氢过氧化物制备。
• 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
  申请人：——

  公开号：US20030065184A1

  公开（公告）日：2003-04-03

  The present invention relates to selected 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 trimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom; a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,6 dimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.

  本发明涉及选择的1-烷氧基-2,2-二乙基-6,6-二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-三甲基哌啶衍生物，这些衍生物在4位被氧或氮原子取代；包括a）至少一种乙烯基不饱和单体和b）所述哌啶衍生物的可聚合组合物。本发明的其他方面包括聚合乙烯基不饱和单体的过程，以及使用在4位被氧或氮原子取代的1-烷氧基-2,2-二乙基-6,6-二甲基哌啶和1-烷氧基-2,6-二乙基-2,6-二甲基哌啶衍生物进行受控聚合。中间体N-氧基衍生物，N-氧基衍生物与乙烯基不饱和单体和自由基引发剂的组合物，以及聚合的过程也是本发明的主题。
• [EN] RADICALLY POLYMERIZABLE SULFUR-CONTAINING COMPOUND AND RADICALLY POLYMERIZABLE SULFUR-CONTAINING POLYMER<br/>[FR] COMPOSE POLYMERISABLE PAR VOIE RADICALAIRE, CONTENANT DU SOUFRE, ET POLYMERE POLYMERISABLE PAR VOIE RADICALAIRE, CONTENANT DU SOUFRE
  申请人：SHOWA DENKO KK

  公开号：WO2006033438A1

  公开（公告）日：2006-03-30

  The invention relates to a radically polymerizable sulfur-containing compound having a group represented by formula (1) and at least one selected from among groups represented by formulae (2) to (4) , a radically polymerizable sulfur-containing polymer obtained by subjecting the compound to cationic ring-opening (co)polymerization, production process thereof, a composition containing the sulfur-containing compound and/or the sulfur-containing polymer, and a cured product obtained from the composition……………. (1)(2) (3) (4)………….( R1 to R6 each independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.) The cured product obtained from the radically polymerizable sulfur-containing compound and the radically polymerizable sulfur-containing polymer having a high refractive index is useful as an optical material, especially for lens material.

  该发明涉及一种具有由式（1）表示的基团和至少从式（2）到（4）中选择的基团中的一种的可进行根本聚合的含硫化合物，通过对该化合物进行阳离子环开（共）聚合获得的可进行根本聚合的含硫聚合物，其生产工艺，含有该含硫化合物和/或该含硫聚合物的组合物，以及从该组合物获得的固化产品…………（1）（2）（3）（4）…………（R1至R6分别表示氢原子或具有1至4个碳原子的烷基基团）。从具有高折射率的可进行根本聚合的含硫化合物和可进行根本聚合的含硫聚合物获得的固化产品可用作光学材料，特别是用于镜片材料。
• Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization
  申请人：Hintermann Tobias

  公开号：US20050124814A1

  公开（公告）日：2005-06-09

  The present invention relates to open chain alkoxyamine compounds, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) at least one open chain alkoxyamine compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of open chain alkoxyamine compounds for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator X, as well as a process and their use for polymerization are also subjects of the present invention.

  本发明涉及开链烷氧胺化合物，一种可聚合组合物，包括a)至少一种乙烯基不饱和单体和b)至少一种开链烷氧胺化合物。本发明的进一步方面包括聚合乙烯基不饱和单体的过程，以及使用开链烷氧胺化合物进行控制聚合。中间体N-氧化物衍生物，N-氧化物衍生物与乙烯基不饱和单体和自由基引发剂X的组合物，以及用于聚合的过程和它们的使用也是本发明的主题。