1-叔丁基过氧己烷 | 827341-41-3

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 1-叔丁基过氧己烷
• 英文名称: t-butyl t-hexyl peroxide
• 英文别名: Peroxide, 1,1-dimethylethyl hexyl；1-tert-butylperoxyhexane
• CAS: 827341-41-3
• 化学式: C₁₀H₂₂O₂
• 分子量: 174.283
• InChiKey: NOSXUFXBUISMPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  叔丁基过氧化氢 、 1-氯己烷 在 六甲基磷酰三胺 、 sodium hydroxide 作用下， 反应 2.0h， 以45%的产率得到1-叔丁基过氧己烷
  参考文献：
  名称：

  Specific Features of Alkylation of Organic Hydroperoxides with Chlorinated Hydrocarbons in Superbasic Media

  摘要：

  Alkylation of organic hydroperoxides with chlorinated hydrocarbons in superbasic media (dipolar nonhydroxyl solvent-strong ionic base) was performed.

  DOI：

  10.1023/b:rugc.0000045866.17932.f7

文献信息

• Emulsion composition of modified polypropylene
  申请人：Ozaki Hiroyuki

  公开号：US20070004847A1

  公开（公告）日：2007-01-04

  An emulsion composition of a modified polypropylene. It can have exceedingly improved emulsion stability because the modified polypropylene used has extremely high solubility in solvents and is easily emulsifiable. The modified-polypropylene emulsion composition comprises water and a modified polypropylene dispersed and emulsified therein, and is characterized in that the modified polypropylene has a racemic diad content [r] of 0.12 to 0.88 and has hydrophilic functional groups in a number of 0.5 or larger on the average per molecular chain of the polypropylene.

  一种改性聚丙烯的乳液组合物。它可以具有极大改善的乳液稳定性，因为所使用的改性聚丙烯在溶剂中具有极高的溶解度，并且易于乳化。改性聚丙烯乳液组合物包括水和分散和乳化其中的改性聚丙烯，其特征在于改性聚丙烯的嘧啶二聚物含量[r]为0.12至0.88，并且在聚丙烯的每条分子链上平均有0.5个或更多的亲水性功能基团。
• Surface treating agent comprising modified propylene-ethylene copolymer, processes for preparing said surface treating agent, and use of said surface treating agent in the treatment of articles of an olefin resin
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0009971A2

  公开（公告）日：1980-04-16

  A surface treating agent for fabricated articles of olefin polymers which is composed of an organic solvent solution of a modified polymer resulting from the graft copolymerization of a propylene-ethylene copolymer with maleic acid or maleic anhydride. The propylene-ethylene copolymer has a propylene content of 50 to 75 mole% and a crystallinity determined by an X-ray diffraction method of 2 to 20%. The amount of maleic acid or maleic anhydride grafted is 0.5 to 15% by weight. The modified polymer has an intrinsic viscosity of at least 0.3 dl/g, and is dissolved in the organic solvent in a concentration of 10 to 100 kg/m) of solvent. The treating agent can be prepared by dissolving the propylene-ethylene copolymer in the organic solvent before carrying out the grafting reaction or by carrying out the grafting reaction in a melt before adding the organic solvent. The treating agent is suitable for use as an undercoat for olefin polymer articles and improves the adhesion of a paint thereto.

  一种用于烯烃聚合物制成品的表面处理剂，由丙烯-乙烯共聚物与马来酸或马来酸酐接枝共聚产生的改性聚合物的有机溶剂溶液组成。丙烯-乙烯共聚物的丙烯含量为 50 至 75 摩尔%，用 X 射线衍射法测定的结晶度为 2 至 20%。接枝的马来酸或马来酸酐的量为 0.5 至 15%（按重量计）。改性聚合物的固有粘度至少为 0.3 dl/g，并以 10 至 100 kg/m) 的溶剂浓度溶解在有机溶剂中。处理剂的制备方法可以是在进行接枝反应前将丙烯-乙烯共聚物溶解在有机溶剂中，也可以是在加入有机溶剂前在熔体中进行接枝反应。处理剂适合用作烯烃聚合物制品的底层涂料，可提高涂料的附着力。
• End-capped polyarylene polyethers, articles made therefrom and process for preparing such polyarylene polyethers
  申请人：AMOCO CORPORATION

  公开号：EP0106023A2

  公开（公告）日：1984-04-25

  Class of high performance thermosetting materials composed of polyarylene polyether resins having each of their ends capped with a monovalent unsaturated organo radical. The end-capped polyarylene polyether resins have the formula: wherein Z and Z' are each a monovalent unsaturated organo radical. Usually Z and Z' are alkylene, aralkylene or cycloalkylene moieties. The end-capped polyarylene polyethers can be cured as is or in the presence of one or more unsaturated comonomers to afford homopolymers or copolymers, respectively. Such cured systems exhibit high glass transition temperatures, good tensile properties, excellent electric and alkali resistance and improved stress cracking resistance. End- terminated polysulfone resins having molecular weight of 5,00 to 15.000 are especially advantageous. The properties exhibited by the vinyl/allyl terminated oligomers are useful in fields which require high temperature performance, excellent solvent resistance and good fabrication characteristics. Specific areas of application include high performance molded products for appliances and electronics, high temperature laminates and adhesives and protective and insulative coatings.

  一类高性能热固性材料，由聚芳醚树脂组成，每种树脂的末端都有一个一价不饱和有机基。末端封端的聚芳基聚醚树脂的结构式如下 其中 Z 和 Z'各为一价不饱和有机基。通常 Z 和 Z' 为亚烷基、芳烷基或环烷基。末端封端的聚芳基醚可以原样固化，也可以在一种或多种不饱和共聚单体的存在下固化，分别生成均聚物或共聚物。这种固化体系具有较高的玻璃化转变温度、良好的拉伸性能、优异的耐电和耐碱性能以及更强的抗应力开裂性能。分子量在 5,00 至 15,000 之间的端末端聚砜树脂尤其具有优势。乙烯基/烯丙基端接低聚物所表现出的特性适用于需要高温性能、优异的耐溶剂性和良好的制造特性的领域。 具体应用领域包括用于电器和电子产品的高性能模塑产品、高温层压板和粘合剂以及保护性和绝缘性涂层。
• Compositions thermoplastiques contenant un polymère greffé par des silanes permettant d'améliorer les propriétés physiques d'une polyoléfine thermoplastique, procédé permettant cette amélioration
  申请人：ALPHACAN

  公开号：EP0130855A1

  公开（公告）日：1985-01-09

  Procédé permettant d'améliorer les propriétés physiques d'une polyoléfine thermoplastique consistant à mettre en forme un mélange de 20 à 99,5 parties en poids de polyoléfine thermoplastique compatible avec 0,5 à 80 parties en poids d'un polymère greffé par des silanes puis à l'hydrolyser.

  一种改善热塑性聚烯烃物理性能的工艺，包括将 20 至 99.5 重量份的相容热塑性聚烯烃与 0.5 至 80 重量份的硅烷接枝聚合物的混合物成型，然后水解。
• One-extrusion method for making a shaped crosslinked polymeric product
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0163865A1

  公开（公告）日：1985-12-11

  Method of and apparatus for making a shaped cross- linked extruded polymeric product by extruding compacted, melted polymer, e.g., polyethylene, into a mixer (18) formed on or fitted to the discharge end of an extruder, injecting proportionate amounts of a mixture of compounding ingredients including olefinically unsaturated hydrolyzable silane, free-radical generator and, preferably, a silanol condensation catalyst into the compacted, melted polymer. The polymer and compounding ingredients are blended in the mixer (18) until the silane is grafted to said polymer, and the resulting grafted polymer mixed with the silanol condensation catalyst is extruded through a die to form the product of the required final shape. The resulting product is subjected to the action of H20 until the grafted polymer is cross- linked.

  用于制造异型交联挤出聚合物产品的方法和设备，其方法是将压实熔化的聚合物（如聚乙烯）挤入在挤出机出料端上形成或安装的混合器（18）中，按比例向压实熔化的聚合物中注入一定量的混合配料，包括烯烃不饱和可水解硅烷、自由基发生器和最好是硅烷醇缩合催化剂。聚合物和配料在混合器（18）中混合，直到硅烷接枝到所述聚合物上，然后通过模头挤出与硅烷醇缩合催化剂混合的接枝聚合物，形成所需最终形状的产品。将得到的产品置于 H20 的作用下，直到接枝聚合物发生交联。