1-氯-1,3,3,3-四氟丙烯 | 460-71-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-氯-1,3,3,3-四氟丙烯
• 英文名称: 1-chloro-1,3,3,3-tetrafluoropropene
• 英文别名: 1-chloro-1,3,3,3-tetrafluoro-propene；1ξ-Chlor-1ξ,3,3,3-tetrafluor-propen；1-Chlor-1,3,3,3-tetrafluor-propen；1,3,3,3-Tetrafluor-1-chlor-propen；1-chloro-1,3,3,3-tetrafluoroprop-1-ene
• CAS: 460-71-9
• 化学式: C₃HClF₄
• 分子量: 148.488
• InChiKey: PNWJILFKWURCIR-UHFFFAOYSA-N

物化性质

• 沸点：
  19-20°C

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 危险等级：
  IRRITANT
• 危险品标志：
  Xi
• 安全说明：
  S23,S38
• 海关编码：
  2903799090
• 危险品运输编号：
  UN 3163

反应信息

• 作为反应物：
  描述：

  1-氯-1,3,3,3-四氟丙烯 在 水 、 氯 作用下， 生成 1,1,2,2-四氯-1,3,3,3-四氟丙烷
  参考文献：
  名称：

  Substitution and Addition Reactions of the Fluoroölefins. III.¹ SN2' Substitution Reactions of Chlorofluoroallyl Chlorides with Halide Ions²

  摘要：

  DOI：

  10.1021/ja01518a013
• 作为产物：
  描述：

  3,3-二氯-1,1,3-三氟-丙烯 在 四乙基氟化铵水合物 作用下， 以 氯仿 为溶剂， 生成 1-氯-1,3,3,3-四氟丙烯
  参考文献：
  名称：

  Substitution and Addition Reactions of the Fluoroölefins. IV.¹ Reactions of Fluoride Ion with Fluoroölefins^2,3

  摘要：

  DOI：

  10.1021/ja01497a028

文献信息

• Process for the manufacture of halogenated propanes containing
  申请人：E. I. du Pont de Nemours and Company

  公开号：US06066769A1

  公开（公告）日：2000-05-23

  A process is disclosed for producing a compound of the formula: CF.sub.3 CHXCF.sub.3-z Y.sub.2 where X and Y are independently selected from the group consisting of H and Cl, and z is 0 or 1. The process involves (1) contacting CCl.sub.3 CHXCC.sub.3-z Y.sub.z,CCl.sub.2-z .dbd.CXCC.sub.3, and/or CCl.sub.2 CX.dbd.CC.sub.3-z Y.sub.z starting material, with hydrogen fluoride at a temperature of less than 200.degree. C. to produce a fluorination product of said starting material which includes at least 90 mole percent total of C.sub.3 HXY.sub.z Cl.sub.6-z-x F.sub.x saturated compounds and C.sub.3 XY.sub.z Cl.sub.5-z-y F.sub.y olefinic compounds, wherein x is an integer from 1 to 6-z and y is an integer from 1 to 5-z, (the fluorination product including no more than about 40 mole percent of the desired product, CF.sub.3 CHXCF.sub.3-z Y.sub.z); (2) contacting saturated compounds and olefinic compounds produced in (1) with hydrogen fluoride in the vapor phase at a temperature of from 200.degree. C. to about 400.degree. C. in the presence of a fluorination catalyst; and (3) reacting a sufficient amount of said compounds, wherein x is an integer from 1 to 5-z and olefinic compounds produced in (1) with hydrogen fluoride in the vapor phase at a temperature of from 200.degree. C. to about 400.degree. C. in the presence of a vapor phase fluorination catalyst to provide an overall selectivity to CF.sub.3 CHXCF.sub.3-z Y.sub.z of at least about 90 percent based upon the amount of starting material reacted with HF in (1) and (2).

  本发明公开了一种生产化合物的方法，该化合物的化学式为：CF.sub.3 CHXCF.sub.3-z Y.sub.2，其中X和Y是独立选择自H和Cl的一组，z为0或1。该方法包括：（1）将CCl.sub.3 CHXCC.sub.3-z Y.sub.z、CCl.sub.2-z .dbd.CXCC.sub.3和/或CCl.sub.2 CX.dbd.CC.sub.3-z Y.sub.z起始物料与氢氟酸接触，温度低于200°C，以产生起始物料的氟化产物，其中至少包括90摩尔％的C.sub.3 HXY.sub.z Cl.sub.6-z-x F.sub.x饱和化合物和C.sub.3 XY.sub.z Cl.sub.5-z-y F.sub.y烯烃化合物，其中x为1至6-z的整数，y为1至5-z的整数，（所述氟化产物中所含期望产物CF.sub.3 CHXCF.sub.3-z Y.sub.z的摩尔百分含量不超过40％）；（2）在存在氟化催化剂的条件下，将(1)中产生的饱和化合物和烯烃化合物与氢氟酸在200°C至约400°C的蒸汽相中接触；以及（3）在存在蒸汽相氟化催化剂的条件下，将(1)中产生的x为1至5-z的整数和烯烃化合物与氢氟酸在200°C至约400°C的蒸汽相中接触，以提供对于起始物料在(1)和(2)中与HF反应的总选择性至少为90％的CF.sub.3 CHXCF.sub.3-z Y.sub.z。
• Copolymers of perfluorodioxoles
  申请人：Ausimont S.p.A.

  公开号：US06335408B1

  公开（公告）日：2002-01-01

  Copolymers of perfluoro-4-alkyl-1,3-dioxoles having the general formula wherein Rf is a perfluoroalkylic radical having from 1 to 5 carbon atoms, allow to prepare copolymers with Tg higher than those of the copolymers containing the same molar percentage of fluorinated dioxoles of the art.

  具有以下一般式的全氟-4-烷基-1,3-二噁烷共聚物，其中Rf是具有1到5个碳原子的全氟烷基基团，可以制备出具有Tg高于艺术中含有相同摩尔百分比的氟代二噁烷共聚物的共聚物。
• Perfluoro-4-methyl-1,3-dioxole: a new monomer for high-Tg amorphous fluoropolymers
  作者：Antonio Russo、Walter Navarrini

  DOI：10.1016/j.jfluchem.2003.10.009

  日期：2004.1

  A 4-Chloro-5-trifluoromethyl-2,2,4-trifluoro-1,3-dioxolane (1) was synthesised by reaction of CF2(OF)(2) with CF3-CH=CFCl; the elimination of HCl from (1) in basic conditions led to the formation of dioxole perfluoro-4-methyl-1,3-dioxole (2). Both these synthetic steps gave the corresponding product in high yield.A new synthetic route for the preparation of CF3-CH=CFCl, starting from CF2ClBr and CH2=CF2, together with some examples of polymerisation products obtained by reaction of dioxole (2) with fluoroolefins are also reported. (C) 2003 Elsevier B.V. All rights reserved.
• Substitution and Addition Reactions of the Fluoroölefins. III.¹ SN2' Substitution Reactions of Chlorofluoroallyl Chlorides with Halide Ions²
  作者：John H. Fried、William T. Miller

  DOI：10.1021/ja01518a013

  日期：1959.5
• Substitution and Addition Reactions of the Fluoroölefins. IV.¹ Reactions of Fluoride Ion with Fluoroölefins^2,3
  作者：William T. Miller、John H. Fried、Harold Goldwhite

  DOI：10.1021/ja01497a028

  日期：1960.6