1-甲氧基-3-亚甲基环己烯 | 2773-58-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-甲氧基-3-亚甲基环己烯
• 英文名称: 1-methoxy-3-methylenecyclohexene
• 英文别名: methyl-(3-methylene-cyclohex-1-enyl)-ether；Methyl-(3-methylen-cyclohex-1-enyl)-aether；3-Methoxy-1-methylen-cyclohexen-(2)；1-Methoxy-3-methylen-cyclohexen-(1)；3-Methylen-1-methoxy-cyclohex-1-en；1-Methoxy-3-methylcyclohexen；1-methoxy-3-methylidenecyclohexene
• CAS: 2773-58-2
• 化学式: C₈H₁₂O
• 分子量: 124.183
• InChiKey: LCJLBMWGZXUTRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2909209000

反应信息

• 作为反应物：
  描述：

  1-甲氧基-3-亚甲基环己烯 在 potassium tert-butylate 作用下， 以 环己烷 为溶剂， 生成 1-methoxy-3-methyl-1,3-cyclohexadiene
  参考文献：
  名称：

  Thermodynamics of vinyl ethers. 31. Isomer equilibria in some six- and seven-membered cyclic dienes

  摘要：

  DOI：

  10.1021/jo00224a038
• 作为产物：
  描述：

  1-甲氧基-5-甲基-1,4-环己二烯 在 氨 、 sodium amide 作用下， 生成 1-甲氧基-3-亚甲基环己烯
  参考文献：
  名称：

  327.通过溶解金属进行还原。第五部分

  摘要：

  DOI：

  10.1039/jr9470001642

文献信息

• HERBICIDAL BUS-NITROGEN-CONTAINING OXO AND SULFONO HETEROCYCLES
  申请人：Patel Kanu Maganbhai

  公开号：US20120149573A1

  公开（公告）日：2012-06-14

  Disclosed are compounds of Formula 1, including all stereoisomers, N-oxides, and salts thereof, X is CH or N; Y is C(O) or S(O) 2 ; provided that when Y is S(O) 2 , then X is CH; A is a radical selected from the group consisting of and B 1 , B 2 , B 3 , T, R 1 , R 2 R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling undesired vegetation comprising contacting the undesired vegetation or its environment with an effective amount of a compound or a composition of the invention.

  本发明涉及一种化合物，其化学式为1，包括所有立体异构体、N-氧化物和其盐。其中，X为CH或N；Y为C(O)或S(O)2；但当Y为S(O)2时，X为CH；A为从以下组中选择的基团：以及B1、B2、B3、T、R1、R2R3、R4、R5、R6、R7、R8、R9、R10、R11、R12和R13如本文所定义。本发明还涉及含有化合物1的组合物以及控制不良植物的方法，包括将不良植物或其环境与本发明化合物或组合物的有效量接触。
• HERBICIDAL PYRAZINONES
  申请人：Stevenson Thomas Martin

  公开号：US20140024527A1

  公开（公告）日：2014-01-23

  Disclosed are compounds of Formula 1, including all stereoisomers, N-oxides, and salts thereof, wherein A is a radical selected from the group consisting of and B 1 , B 2 , B 3 , T, R 1 , R 2 R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 and R 14 are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling undesired vegetation comprising contacting the undesired vegetation or its environment with an effective amount of a compound or a composition of the invention. Also disclosed are compounds useful as intermediates for preparing compounds of Formula 1.

  本发明涉及一种化合物，包括所有立体异构体、N-氧化物和其盐，其化学式为1，其中A是从以下组中选择的基团，包括B1、B2、B3、T、R1、R2、R3、R4、R5、R6、R7、R8、R9、R10、R11、R12、R13和R14，如本文所定义。本发明还涉及含有化合物1的组合物以及用于控制不良植被的方法，包括将不良植被或其环境与本发明的化合物或组合物的有效量接触。本发明还涉及用作制备化合物1的中间体的化合物。
• INTERMEDIATES TO PREPARE HERBICIDAL PYRIMIDONE DERIVATIVES
  申请人：E I DU PONT DE NEMOURS AND COMPANY

  公开号：US20150105549A1

  公开（公告）日：2015-04-16

  Disclosed are compounds of Formula 1, including all stereoisomers, N-oxides, and salts thereof, X is CH or N; Y is C(O) or S(O) 2 ; provided that when Y is S(O) 2 , then X is CH; A is a radical selected from the group consisting of and B 1 , B 2 , B 3 , T, R 1 , R 2 R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling undesired vegetation comprising contacting the undesired vegetation or its environment with an effective amount of a compound or a composition of the invention.

  本发明涉及公式1的化合物，包括所有立体异构体、N-氧化物和其盐，其中X为CH或N；Y为C(O)或S(O)2；但当Y为S(O)2时，X为CH；A为从以下组中选择的基团：以及B1、B2、B3、T、R1、R2R3、R4、R5、R6、R7、R8、R9、R10、R11、R12和R13在本公开中所定义。本发明还涉及含有公式1化合物的组合物以及控制不良植物的方法，包括将一种本发明化合物或组合物的有效量与不良植物或其环境接触。
• 327. Reduction by dissolving metals. Part V
  作者：Arthur J. Birch

  DOI：10.1039/jr9470001642

  日期：——
• Birch; Hextall, Australian Journal of Chemistry, 1955, vol. 8, p. 96,99
  作者：Birch、Hextall

  DOI：——

  日期：——