2,4,6-三丁基苯酚 | 5857-00-1

• 物质功能分类: 有机原料 - 醇、酚、酚醇类化合物及衍生物 - 酚及其卤化、磺化、硝化或亚硝化衍生物
• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 中文名称: 2,4,6-三丁基苯酚
• 英文名称: 2,4,6-Tributylphenol
• CAS: 5857-00-1
• 化学式: C₁₈H₃₀O
• 分子量: 262.4
• InChiKey: KHWQFISNNNRGLV-UHFFFAOYSA-N

物化性质

• 沸点：
  363.5±11.0 °C(Predicted)
• 密度：
  0.919±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  19
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-(4-Chloro-cis-2-butenyloxy)-benzaldehyde 、 2,4,6-三丁基苯酚 、 间氯过氧苯甲酸 生成 [2-[[(2R,3S)-3-(chloromethyl)oxiran-2-yl]methoxy]phenyl] formate
  参考文献：
  名称：

  GSCHWEND, H. W.;HUEBNER, C. F.

  摘要：

  DOI：

文献信息

• DIBENZORYLENETETRACARBOXIMIDES AS INFRARED ABSORBERS
  申请人：Koenemann Martin

  公开号：US20100048904A1

  公开（公告）日：2010-02-25

  Dibenzorylenetetracarboximides of the general formula I in which the variables are each defined as follows: R′ are identical or different radicals: hydrogen; optionally substituted aryloxy, arylthio, hetaryloxy or hetarylthio; R are identical or different radicals: hydrogen; optionally substituted C 1 -C 30 -alkyl, C 3 -C 8 -cycloalkyl, aryl or hetaryl; m, n are each independently 0 or 1.

  一般式I的二苯并咔唑四羧酰亚胺中，变量定义如下：R′为相同或不同的基团：氢；可选择取代的芳氧基、芳硫基、杂芳氧基或杂芳硫基；R为相同或不同的基团：氢；可选择取代的C1-C30烷基、C3-C8环烷基、芳基或杂芳基；m，n各自独立地为0或1。
• Etherified Tri-Butylphenol Alkoxylates, Process For Their Preparation And Their Use In Crop Protection Agents
  申请人：CLARIANT INTERNATIONAL LTD

  公开号：US20160244390A1

  公开（公告）日：2016-08-25

  Etherified tri-butylphenol alkoxylates of the formula (I), wherein R represents an unbranched or branched, saturated or unsaturated C 1 -C 4 alkyl, and A represents an ethylene group, a 1,2-propylene group, a 1,2-butylene group or mixtures of ethylene oxide groups and 1,2-propylene groups or mixtures of ethylene oxide groups and 1,2-butylene groups, and m is a number from 2 to 30, are suitable for improving the action of agrochemical active substances in and on plants.

  公式（I）的醚化三丁基苯酚烷氧基化合物，其中R代表直链或支链、饱和或不饱和的C1-C4烷基，A代表一个乙烯基、一个1,2-丙烯基、一个1,2-丁烯基或乙烯氧基和1,2-丙烯基的混合物或乙烯氧基和1,2-丁烯基的混合物，m为2至30之间的数字，适用于提高农药活性物质在植物内外的作用。
• Process for preparring linear alpha olefins
  申请人：De Boer Maria Eric Johannes

  公开号：US20060014989A1

  公开（公告）日：2006-01-19

  A process for the preparation of linear alpha olefins having 2n carbon atoms from linear alpha olefins having n carbon atoms comprising the steps of (a) dimerizing a linear alpha olefin having n carbon atoms in the presence of a dimerization catalyst to produce a linear internal olefin having 2n carbon atoms; (b)(i) reacting the linear internal olefin having 2n carbon atoms produced in step (a) with a trialkylaluminium compound in the presence of a catalytic amount of an isomerization/displacement catalyst in order to cause isomerization of the linear internal olefin and to displace alkyl group(s) from said trialkylaluminium compound to form an alkyl aluminium compound wherein at least one of the alkyl groups bound to aluminium is a linear alkyl which has been derived from the isomerization of said linear internal olefin; and (b)(ii) reacting said alkyl aluminium compound with an alpha olefin optionally in the presence of a displacement catalyst so as to displace said linear alkyl from said alkyl aluminium compound to form a linear alpha olefin having 2n carbon atoms.

  一种从具有n个碳原子的线性α-烯烃制备具有2n个碳原子的线性α-烯烃的方法，包括以下步骤：(a)在线性α-烯烃存在下通过二聚化催化剂使具有n个碳原子的线性α-烯烃二聚化，产生具有2n个碳原子的线性内部烯烃；(b)(i)在异构化/置换催化剂存在下，将步骤(a)产生的具有2n个碳原子的线性内部烯烃与三烷基铝化合物反应，以引起线性内部烯烃的异构化并将烷基从所述三烷基铝化合物中置换出来，形成一种烷基铝化合物，其中至少一个结合到铝的烷基是从所述线性内部烯烃的异构化中衍生出的线性烷基；(b)(ii)将所述烷基铝化合物与α-烯烃反应，可选地在置换催化剂存在下，以将所述线性烷基从所述烷基铝化合物中置换出来，形成具有2n个碳原子的线性α-烯烃。
• Multiple Chromophores Based on Rylene
  申请人：Konemann Martin

  公开号：US20080287678A1

  公开（公告）日：2008-11-20

  A rylene-based polychromophore of the general formula I in which the variables are each defined as follows: rylene is a radical of the formula which has been functionalized by at least one imide group, ester group or amide group and which may additionally be substituted by aryloxy, arylthio, hetaryloxy and/or hetarylthio; X is a rylenedicarboximide radical which absorbs at a different wavelength from the rylene radical, is bonded to the X radical in the peri-position via Y via a moiety —Y′-A-Y—, is bonded to the rylene radical and may likewise be substituted by aryloxy, arylthio, hetaryloxy and/or hetarylthio; A is a bridging member having at least one aromatic or heteroaromatic radical, the Y or Y and Y′ groups being bonded to the aromatic or heteroaromatic radical; Y is a moiety Y′ is a moiety where the moieties (i) and (ii) may be part of the ester groups of the rylene radical and the moieties (iii) are part of the imide groups of the rylene radical and the moieties (iv) are part of the amide groups of the rylene radical; R 1 is hydrogen or C 1 -C 18 -alkyl, where the R 1 radicals may be the same or different when they occur repeatedly; n is 1, 2 or 3; x is from 1 to 7.

  基于莱林的多色团的一般公式I，其中变量各自定义如下：莱林是一种具有下述结构的基团，已被至少一个酰亚胺基团、酯基团或酰胺基团官能化，并且还可以被芳氧基、芳硫基、杂芳氧基和/或杂芳硫基取代；X是一种莱林二酰亚胺基团，其在不同波长处吸收于莱林基团，通过Y通过一个团—Y′-A-Y—与X基团在邻位键合，与莱林基团键合，同样可以被芳氧基、芳硫基、杂芳氧基和/或杂芳硫基取代；A是至少具有一个芳香或杂芳基团的桥接成员，Y或Y和Y′基团与芳香或杂芳基团键合；Y是一个团，Y′是一个团，其中团（i）和（ii）可能是莱林基团的酯基团的一部分，团（iii）是莱林基团的酰亚胺基团的一部分，团（iv）是莱林基团的酰胺基团的一部分；R1是氢或C1-C18-烷基，当它们重复出现时，R1基团可能相同也可能不同；n为1、2或3；x为1到7。
• NOVEL COLOR CONVERTER
  申请人：BASF SE

  公开号：US20160284947A1

  公开（公告）日：2016-09-29

  Color converter comprising at least one polymer and at least one organic fluorescent dye comprising at least one structural unit of the formula (I) where the structural unit may be mono- or polysubstituted by identical or different substituents and where one or more CH groups of the six-membered ring of the benzimidazole structure shown may be replaced by nitrogen.

  颜色转换器包括至少一种聚合物和至少一种有机荧光染料，其中该染料包括至少一个结构单元，其化学式为(I)，其中该结构单元可以通过相同或不同的取代基进行单取代或多取代，并且苯并咪唑结构的六元环的一个或多个CH基团可以被氮取代。