Low dusting crystal transformations of 2,2'-methylenbis[4-(1,1,3,3-tetramethylbutyl)-6-benzotriazolylphenol] and mixture thereof, method for preparing them, and ultraviolet absorbent using the same
申请人:——
公开号:US20040242733A1
公开(公告)日:2004-12-02
The present invention relates to a low dusting crystalline 2,2′-methylenebis[4-(1,1,3,3-tetramethylbutyl)-6-benzotriazolylphenol] type I crystal transformation which exhibits diffraction peaks at diffraction angles (2&thgr;±0.1°) of 7.1°, 8.6°, 14.3°, 16.1°, 18.1° and 23.0° in powder X-ray diffraction analysis with Cu-K&agr; radiation; a low dusting 2,2′-methylenebis[4-(1,1,3,3-tetramethylbutyl)-6-benzotriazolylphenol] type II crystal transformation which does not exhibit a distinct diffraction peak but an amorphous halo in powder X-ray diffraction analysis with Cu-K&agr; radiation; a mixture thereof; a method for preparing them; and a UV light absorber, an emulsion composition and a polymer material using them.
本发明涉及一种低粉尘结晶2,2'-亚甲基双[4-(1,1,3,3-四甲基丁基)-6-苯并三唑基苯酚]I型晶体转化,该晶体在Cu-K&agr;辐射下的粉末X射线衍射分析中表现出在衍射角度(2&thgr;±0.1°)为7.1°、8.6°、14.3°、16.1°、18.1°和23.0°的衍射峰;一种低粉尘2,2'-亚甲基双[4-(1,1,3,3-四甲基丁基)-6-苯并三唑基苯酚]II型晶体转化,其在Cu-K&agr;辐射下的粉末X射线衍射分析中不表现出明显的衍射峰,而是呈现出无定形的晕影;以及它们的混合物、制备它们的方法以及使用它们的UV光吸收剂、乳液组合物和聚合物材料。