2-(1-氯乙基过氧)-2-甲基丙烷 | 20614-18-0

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 2-(1-氯乙基过氧)-2-甲基丙烷
• 英文名称: α-chloroethyl tert-butyl peroxide
• 英文别名: 2-[(1-Chloroethyl)peroxy]-2-methylpropane；2-(1-chloroethylperoxy)-2-methylpropane
• CAS: 20614-18-0
• 化学式: C₆H₁₃ClO₂
• 分子量: 152.621
• InChiKey: GVLVJJPXDKREPH-UHFFFAOYSA-N

物化性质

• 沸点：
  124.2±23.0 °C(Predicted)
• 密度：
  1.003±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  壬酸 、 2-(1-氯乙基过氧)-2-甲基丙烷 在 三乙胺 作用下， 以 氯仿 为溶剂， 以92%的产率得到α-pelargonyloxyethyl tert-butylperoxide
  参考文献：
  名称：

  Synthesis of α-hydroxyalkyl peroxide esters and ethers as initiators of radical processes

  摘要：

  alpha-Hydroxyalkyl peroxide esters and ethers containing, along with the peroxy bond, also acyloxy and alkoxy groups, are effective initiators of radical processes. The initiation efficiency is due to the capability of these molecules to generate simultaneously oxygen- and carbon-centered radicals capable of hydrogen abstraction from the substrate and of addition to > C=CaOE (c) bonds. The selectivity of the synthesis of alpha-hydroxyalkyl peroxide esters and ethers is mainly determined by the steps of the synthesis and isolation of the intermediate alpha-chloroalkyl peroxides, because of their high reactivity. Experimental conditions allowing control of the synthesis of alpha-hydroxyalkyl peroxide esters and ethers were found.

  DOI：

  10.1134/s1070427214120167
• 作为产物：
  描述：

  叔丁基过氧化氢 、 乙醛 在 盐酸 作用下， 生成 2-(1-氯乙基过氧)-2-甲基丙烷
  参考文献：
  名称：

  Razuvaev,G.A. et al., Journal of Organic Chemistry USSR (English Translation), 1968, vol. 4, p. 1256 - 1257

  摘要：

  DOI：

文献信息

• Shreibert,A.I. et al., Journal of Organic Chemistry USSR (English Translation), 1971, vol. 7, p. 984 - 988
  作者：Shreibert,A.I. et al.

  DOI：——

  日期：——
• Synthesis of α-tert-butylperoxyethyl perfluorocarboxylates
  作者：A. I. Rakhimov、O. N. Kutyga

  DOI：10.1134/s1070363208110339

  日期：2008.11
• ——
  作者：I. Yu. Kovalets、T. P. Aleinikova、V. E. Derbisher

  DOI：10.1023/a:1020954220698

  日期：——

  Conditions of synthesis of hydroxyl-containing mono- and diperoxy acetals by the reactions of alpha-chloroethyl tert-butyl peroxide with triethylene glycol and glycerol were determined. These compounds were used for preparing latexes.
• Khardin, A. P.; Lotov, V. V.; Navrotskii, V. A., Journal of Organic Chemistry USSR (English Translation), 1983, vol. 19, p. 788 - 789
  作者：Khardin, A. P.、Lotov, V. V.、Navrotskii, V. A.

  DOI：——

  日期：——
• Razuvaev,G.A. et al., Journal of Organic Chemistry USSR (English Translation), 1970, vol. 6, p. 659 - 660
  作者：Razuvaev,G.A. et al.

  DOI：——

  日期：——