1-Methyl-3-prop-2-enoxycyclopentene | 1103209-98-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-Methyl-3-prop-2-enoxycyclopentene
• 英文别名: 1-methyl-3-prop-2-enoxycyclopentene
• CAS: 1103209-98-8
• 化学式: C₉H₁₄O
• 分子量: 138.21
• InChiKey: UHOBHZROCVKTGP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  苯磺酰基叠氮化物 、 1-Methyl-3-prop-2-enoxycyclopentene 在 偶氮叔丁烷 作用下， 以 苯 为溶剂， 以89%的产率得到4-azido-4-methyl-3-(phenylsulfonylmethyl)hexahydro-2H-cyclopenta[b]furan
  参考文献：
  名称：

  Azidosulfonylation of alkenes, dienes, and enynes

  摘要：

  The radical mediated aziclosulfonylation of various alkenes and alkynes that are able to undergo a rapid radical rearrangement is reported. For instance, treatment of 1,6-dienes or 1-en-6-ynes with benzenesulfonyl azide affords cyclic azidosulfones. High yields are observed when tertiary alkyl radicals are azidated in the last step of the cascade process. The aziclosulfonylation of P-pinene involving ring opening of the bicyclic skeleton is also reported. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.09.096
• 作为产物：
  描述：

  3-甲基环戊-2-烯-1-醇 、 3-溴丙烯 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 生成 1-Methyl-3-prop-2-enoxycyclopentene
  参考文献：
  名称：

  Azidosulfonylation of alkenes, dienes, and enynes

  摘要：

  The radical mediated aziclosulfonylation of various alkenes and alkynes that are able to undergo a rapid radical rearrangement is reported. For instance, treatment of 1,6-dienes or 1-en-6-ynes with benzenesulfonyl azide affords cyclic azidosulfones. High yields are observed when tertiary alkyl radicals are azidated in the last step of the cascade process. The aziclosulfonylation of P-pinene involving ring opening of the bicyclic skeleton is also reported. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.09.096

文献信息

• Azidosulfonylation of alkenes, dienes, and enynes
  作者：Nathalie Mantrand、Philippe Renaud

  DOI：10.1016/j.tet.2008.09.096

  日期：2008.12

  The radical mediated aziclosulfonylation of various alkenes and alkynes that are able to undergo a rapid radical rearrangement is reported. For instance, treatment of 1,6-dienes or 1-en-6-ynes with benzenesulfonyl azide affords cyclic azidosulfones. High yields are observed when tertiary alkyl radicals are azidated in the last step of the cascade process. The aziclosulfonylation of P-pinene involving ring opening of the bicyclic skeleton is also reported. (C) 2008 Elsevier Ltd. All rights reserved.