3-chloromethyl-1-pentadecyn-3-ol | 1417444-65-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-chloromethyl-1-pentadecyn-3-ol
• 英文别名: 3-(Chloromethyl)pentadec-1-yn-3-ol；3-(chloromethyl)pentadec-1-yn-3-ol
• CAS: 1417444-65-5
• 化学式: C₁₆H₂₉ClO
• 分子量: 272.859
• InChiKey: TZHWRHMSVNJLNT-UHFFFAOYSA-N

物化性质

• 沸点：
  357.6±27.0 °C(Predicted)
• 密度：
  0.956±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-chloromethyl-1-pentadecyn-3-ol 在 碲化氢 、 sodium tetrahydroborate 、 对甲苯磺酸 作用下， 以 乙醇 、 正己烷 为溶剂， 反应 4.0h， 生成 3-dodecyltellurophene
  参考文献：
  名称：

  Poly(3-alkyltellurophene)s Are Solution-Processable Polyheterocycles

  摘要：

  The synthesis and characterization of a series of poly(3-allcyltellurophene)s are described. Polymers are prepared by both electrochemical and Kumada catalyst transfer polymerization methods. These polymers have reasonably high molecular weights (M-n = 5.4-11.3 kDa) and can be processed in a manner analogous to that of their lighter atom analogues. All examples exhibit red-shifted optical absorption, as well as solid-state organization, as evidenced by absorption spectroscopy and atomic force microscopy. Overall, the synthesis and characterization of these materials open up a wide range of future studies involving tellurium-based polyheterocycles.

  DOI：

  10.1021/ja309404j
• 作为产物：
  描述：

  magnesium,dodecane,bromide 以 四氢呋喃 为溶剂， 反应 25.0h， 生成 3-chloromethyl-1-pentadecyn-3-ol
  参考文献：
  名称：

  Poly(3-alkyltellurophene)s Are Solution-Processable Polyheterocycles

  摘要：

  The synthesis and characterization of a series of poly(3-allcyltellurophene)s are described. Polymers are prepared by both electrochemical and Kumada catalyst transfer polymerization methods. These polymers have reasonably high molecular weights (M-n = 5.4-11.3 kDa) and can be processed in a manner analogous to that of their lighter atom analogues. All examples exhibit red-shifted optical absorption, as well as solid-state organization, as evidenced by absorption spectroscopy and atomic force microscopy. Overall, the synthesis and characterization of these materials open up a wide range of future studies involving tellurium-based polyheterocycles.

  DOI：

  10.1021/ja309404j

文献信息

• [EN] 3-SUBSTITUTED TELLUROPHENES AND RELATED COMPOUNDS<br/>[FR] TELLUROPHÈNES SUBSTITUÉS EN 3ÈME POSITION ET COMPOSÉS ASSOCIÉS
  申请人：UNIV TORONTO

  公开号：WO2014067016A1

  公开（公告）日：2014-05-08

  Monomeric 3-substututed tellurophene compounds, as well as their use in the synthesis of oligomeric and/or polymeric compounds consisting of two or more tellurophene-2,5-diyl groups which are covalently linked to each other are disclosed, as is the use of said oligomers and polymers in devices such as diodes and solar cells, electrodes and semiconductors.

  单体3-取代碲吩化合物以及它们在合成由两个或更多碲吩-2,5-二基基团共价连接在一起的寡聚物和/或聚合物中的用途被揭示，还公开了这些寡聚物和聚合物在二极管和太阳能电池、电极和半导体等器件中的用途。
• Influence of the heteroatom on the optoelectronic properties and transistor performance of soluble thiophene-, selenophene- and tellurophene–vinylene copolymers
  作者：Mohammed Al-Hashimi、Yang Han、Jeremy Smith、Hassan S. Bazzi、Siham Yousuf A. Alqaradawi、Scott E. Watkins、Thomas D. Anthopoulos、Martin Heeney

  DOI：10.1039/c5sc03501e

  日期：——

  We report the first soluble poly(3-dodecyl tellurophenylenevinylene) and compare its properties to the analogous thiophene and selenophene containing polymers.

  我们报道了第一种可溶性的聚(3-十二烷基碲苯乙烯)并将其性质与类似的含有噻吩和硒吩的聚合物进行了比较。
• Patchy Nanofibers from the Thin Film Self-Assembly of a Conjugated Diblock Copolymer
  作者：Emily L. Kynaston、Yuan Fang、Joseph G. Manion、Nimrat K. Obhi、Jane Y. Howe、Dmitrii F. Perepichka、Dwight S. Seferos

  DOI：10.1002/anie.201700134

  日期：2017.5.22

  unexpected morphology comprising patchy nanofibers can be accessed from the self-assembly of an all-conjugated, polyselenophene-block-polythiophene copolymer. This morphology consists of very small (<10 nm), polythiophene- and polyselenophene-rich domains and is unprecedented for both conjugated polymers and diblock copolymers in general. We propose that the patchy morphology occurs from the enhanced

  可以从全共轭聚硒吩嵌段聚噻吩共聚物的自组装中获得包含斑驳的纳米纤维的出乎意料的形态。这种形态由很小的（<10 nm），富含聚噻吩和聚硒吩的结构域组成，对于共轭聚合物和二嵌段共聚物而言，这是前所未有的。我们提出，与具有较短烷基链的类似嵌段共聚物相比，由较长烷基链产生的嵌段的可混溶性增强，出现了片状形态，后者完全相分离，并且在聚噻吩和聚硒吩嵌段之间存在刚性差异。这项工作演示了一种通过修饰侧链取代基来调节共轭嵌段共聚物自组装行为的简便方法。
• 3-SUBSTITUTED TELLUROPHENES AND RELATED COMPOUNDS
  申请人：THE GOVERNING COUNCIL OF THE UNIVERSITY OF TORONTO

  公开号：US20150295178A1

  公开（公告）日：2015-10-15

  Monomeric 3-substituted tellurophene compounds, as well as their use in the synthesis of oligomeric and/or polymeric compounds consisting of two or more tellurophene-2,5-diyl groups which are covalently linked to each other are disclosed, as is the use of said oligomers and polymers in devices such as diodes and solar cells, electrodes and semiconductors.

  本发明公开了单体3-取代碲吩化合物，以及它们在合成由两个或更多碲吩-2,5-二基团构成的寡聚物和/或聚合物中的应用，这些基团之间共价键连接。同时，本发明还公开了使用所述寡聚体和聚合物制造器件，如二极管和太阳能电池、电极和半导体。
• Poly(3-alkyltellurophene)s Are Solution-Processable Polyheterocycles
  作者：Ashlee A. Jahnke、Brandon Djukic、Theresa M. McCormick、Ester Buchaca Domingo、Christoph Hellmann、Yunjeong Lee、Dwight S. Seferos

  DOI：10.1021/ja309404j

  日期：2013.1.23

  The synthesis and characterization of a series of poly(3-allcyltellurophene)s are described. Polymers are prepared by both electrochemical and Kumada catalyst transfer polymerization methods. These polymers have reasonably high molecular weights (M-n = 5.4-11.3 kDa) and can be processed in a manner analogous to that of their lighter atom analogues. All examples exhibit red-shifted optical absorption, as well as solid-state organization, as evidenced by absorption spectroscopy and atomic force microscopy. Overall, the synthesis and characterization of these materials open up a wide range of future studies involving tellurium-based polyheterocycles.