cinnamoyloxyethyl methacrylate | 41261-99-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: cinnamoyloxyethyl methacrylate
• 英文别名: Cinnamoyloxyethylmethacrylate；2-(3-phenylprop-2-enoyloxy)ethyl 2-methylprop-2-enoate
• CAS: 41261-99-8
• 化学式: C₁₅H₁₆O₄
• 分子量: 260.29
• InChiKey: IIYLRFRRKZNPIZ-UHFFFAOYSA-N

物化性质

• 沸点：
  380.5±17.0 °C(Predicted)
• 密度：
  1.125±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  19
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基丙烯酸羟乙酯 、 肉桂酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以93%的产率得到cinnamoyloxyethyl methacrylate
  参考文献：
  名称：

  Photochemical Crack Healing in Cinnamate-Based Polymers

  摘要：

  四种肉桂酸类单体被合成为自愈剂。通过[2+2]环加成反应，单体在光照下生成含有环丁烷结构的交联聚合物。通过傅里叶变换红外光谱研究了交联聚合物断裂时的环丁烷断裂和断裂聚合物的再环加成反应。通过测量交联、断裂和自愈聚合物的弯曲强度，证明了光化学裂纹自愈。观察到宽度为200纳米至2微米的微裂纹通过光照得到愈合。

  DOI：

  10.1166/jnn.2010.2953

文献信息

• Photochemical Crack Healing in Cinnamate-Based Polymers
  作者：Sung-Youl Cho、Joong-Gon Kim、Chan-Moon Chung

  DOI：10.1166/jnn.2010.2953

  日期：2010.10.1

  Four kinds of cinnamate-type monomers were synthesized as healing agents. Photoirradiation of the monomers gave cyclobutane-containing crosslinked polymers via [2+2] cycloaddition. Cyclobutane cleavage upon cracking of the crosslinked polymers and re-cycloaddition of the cracked polymers were investigated by FT-IR spectroscopy. Photochemical crack healing was demonstrated by measurement of flexural strength of crosslinked, cracked, and healed polymers. It was observed that microcracks with width of 200 nm to 2 μm were healed by photoirradiation.

  四种肉桂酸类单体被合成为自愈剂。通过[2+2]环加成反应，单体在光照下生成含有环丁烷结构的交联聚合物。通过傅里叶变换红外光谱研究了交联聚合物断裂时的环丁烷断裂和断裂聚合物的再环加成反应。通过测量交联、断裂和自愈聚合物的弯曲强度，证明了光化学裂纹自愈。观察到宽度为200纳米至2微米的微裂纹通过光照得到愈合。
• [EN] COPPER-CONTAINING POLYMERIC COMPOSITIONS<br/>[FR] COMPOSITIONS POLYMÈRES CONTENANT DU CUIVRE
  申请人：EASTMAN KODAK CO

  公开号：WO2016186864A1

  公开（公告）日：2016-11-24

  Copper-containing compositions can be provided in articles on a suitable substrate. Such compositions can include either reducible copper ions or copper nanoparticles complexed with a water-soluble reactive polymer or a water-insoluble crosslinked polymer derived from the water-soluble reactive polymer. The reactive polymer can be crosslinked using suitable irradiation to provide copper-containing water-insoluble complexes. The various articles and electrically -conductive materials can be assembled in electronic devices. The reactive polymer has greater than 1 mol % of recurring units comprising sulfonic acid or sulfonate groups, at least 5 mol % of recurring units comprising a pendant group capable of crosslinking via [2+2] photocycloaddition, and optionally at least 1 mol % of recurring units comprising a pendant amide, amine, hydroxy 1, lactam, phosphonic acid, or carboxylic acid group.

  含铜组分可以被提供在适合的基板上的物品中。这种组分可以包括可还原的铜离子或与水溶性活性聚合物或从水溶性活性聚合物衍生的水不溶性交联聚合物络合的铜纳米粒子。活性聚合物可以通过适当的辐照进行交联，以提供含铜的水不溶性络合物。各种物品和电导材料可以组装在电子器件中。活性聚合物具有大于1摩尔％的重复单元，包括磺酸或磺酸盐基团，至少5摩尔％的重复单元，包括通过[2+2]光环加成能够交联的侧链基团，以及可选地至少1摩尔％的重复单元，包括侧链酰胺、胺、羟基、内酰胺、膦酸或羧酸基团。
• Efficient Inverted Bulk Heterojunction Photovoltaic Devices Using a Transparent Polymeric Interfacial Buffer Layer with C&lt;SUB&gt;60&lt;/SUB&gt; Pendant and UV Curable Groups
  作者：Younghwan Shin、Seonju Jeong、Hyeok Yong Kwon、Yoon Soo Han、Younghwan Kwon

  DOI：10.1166/jnn.2012.5900

  日期：2012.5.1

  We demonstrate the synthesis of a transparent, polymeric n-type material (M1) consisting of C60 pendant and UV curable groups in side chains. This material (M1) is employed as a polymeric n-type interfacial buffer layer for an efficient inverted bulk heterojunction (BHJ) photovoltaic device based on regioregular poly(3-hexylthiophene):[6,6]-phenyl C61 butyric acid methyl ester (P3HT:PC61BM) active layer. Under simulated solar illumination of AM 1.5G (100 mW/cm2), the highest efficient devices fabricated with a configuration of ITO/interfacial buffer layer (M1, 10 nm)/P3HT:PC61BM (1:0.9 w:w) (120 nm)/PEDOT:PSS (30 nm)/Ag (100 nm) achieve an average power conversion efficiency PCE of 2.16%, with short-circuit current J sc = 6.70 mA/cm2, fill factor FF = 54.2%, and open-circuit voltage V Oc = 0.60 V. This result is comparable to the inverted BHJ photovoltaic devices fabricated with Cs2CO3, one of widely used as a buffer layer. The synthesized M1 have thus proven to be promising polymeric interfacial buffer layer for high efficient BHJ photovoltaic devices.

  我们展示了一种透明的高分子 n 型材料（M1）的合成过程，这种材料由 C60 垂体和侧链中的紫外线固化基团组成。这种材料（M1）被用作高分子 n 型界面缓冲层，用于基于多规聚（3-己基噻吩）：[6,6]-苯基 C61 丁酸甲酯（P3HT:PC61BM）活性层的高效反向体异质结（BHJ）光伏器件。在 AM 1.5G（100 mW/cm2）的模拟太阳光照射下，采用 ITO/界面缓冲层（M1，10 nm）/P3HT:PC61BM（1:0.9 w:w) (120 nm)/PEDOT:PSS (30 nm)/Ag (100 nm)配置制成的最高效率器件的平均功率转换效率 PCE 为 2.16%，短路电流 J sc = 6.70 mA/cm2，填充因子 FF = 54.2%，开路电压 V Oc = 0.60 V。这一结果与使用 Cs2CO3（广泛用作缓冲层之一）制造的反相 BHJ 光伏器件相当。因此，合成的 M1 被证明是用于高效 BHJ 光伏器件的理想聚合物界面缓冲层。
• Synthesis and Photoluminescent Properties of Red Phosphorescent Random Copolymers with Photopatternable Moiety
  作者：Minhyeon Song、Kyung-Hoe Kim、Younghwan Kwon、Yoon Soo Han

  DOI：10.1080/15421400701497597

  日期：2007.8.10
• Poly [2-(cinnamoyloxy)ethyl methacrylate-co-octamethacryl-POSS] nanocomposites: Synthesis and properties
  作者：A.B.V. Kiran Kumar、T. Daniel Thangadurai、Yong-Ill Lee

  DOI：10.1016/j.reactfunctpolym.2013.05.010

  日期：2013.9

  Poly [2-(cinnamoyloxy)ethyl methacrylate-co-octamethacryl-POSS] nanocomposites were synthesized from octamethacryl-POSS and 2-(cinnamoyloxy)ethyl methacrylate (CEM) by free radical polymerization. The chemical structures and morphologies of these nanocomposites were determined by FTIR, Si-29 NMR, energy-dispersive spectroscopy (EDS), X-ray powder diffraction (XRD), and scanning electron microscopy (SEM) techniques. The XRD data showed that the materials were amorphous in nature, indicating that PUSS formed an aggregate instead of a crystalline form in the polymer matrix. The POSS-CEM nanocomposites exhibited high thermal stability. Excitation and emission of the CEM-incorporated POSS nanocomposites, studied in the solid state, exhibited blue emission with CIE (x, 0.178; y, 0.137) coordinates, in addition to an emission intensity that increased with increasing CEM (monomer) concentration. (C) 2013 Elsevier Ltd. All rights reserved.