2-(己氧基)乙胺 | 105939-60-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2-(己氧基)乙胺
• 英文名称: 2-(hexyloxy)ethanamine
• 英文别名: 2-Hexoxyethanamine
• CAS: 105939-60-4
• 化学式: C₈H₁₉NO
• 分子量: 145.245
• InChiKey: USVBZHXZZNJKFO-UHFFFAOYSA-N

物化性质

• 沸点：
  202.6±13.0 °C(Predicted)
• 密度：
  0.851±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  10
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,1-二甲氧基-N,N-二甲基乙胺 、 2-(己氧基)乙胺 在 二甲胺 作用下， 以 四氢呋喃 为溶剂， 反应 18.25h， 以91%的产率得到N'-(2-(hexyloxy)ethyl)-N,N-dimethylacetimidamide
  参考文献：
  名称：

  A Synthesis of Acetamidines

  摘要：

  The condensation of primary amine with N,N-dimethylacetamide dimethyl acetal yields a mixture of acetamidine and imidate ester. The product distribution in this reaction depends on the temperature, solvent, and structure of the primary amine. It is possible to suppress the formation of imidate ester by performing the reaction in the presence of excess dimethyl amine, yielding acetamidine as the exclusive product. For acetamidines that cannot be purified either by crystallization or distillation, this new method is necessary for the generation of pure acetamidines in good yields.

  DOI：

  10.1021/jo102358d
• 作为产物：
  描述：

  乙二醇己醚 在 4-二甲氨基吡啶 、 hydrazine hydrate 作用下， 以 乙醇 、 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 21.0h， 生成 2-(己氧基)乙胺
  参考文献：
  名称：

  A Synthesis of Acetamidines

  摘要：

  The condensation of primary amine with N,N-dimethylacetamide dimethyl acetal yields a mixture of acetamidine and imidate ester. The product distribution in this reaction depends on the temperature, solvent, and structure of the primary amine. It is possible to suppress the formation of imidate ester by performing the reaction in the presence of excess dimethyl amine, yielding acetamidine as the exclusive product. For acetamidines that cannot be purified either by crystallization or distillation, this new method is necessary for the generation of pure acetamidines in good yields.

  DOI：

  10.1021/jo102358d

文献信息

• An aqueous ink composition
  申请人：TAOKA CHEMICAL CO., LTD

  公开号：EP0168961A2

  公开（公告）日：1986-01-22

  57 An aqueous ink composition comprising a dyestuff, a wetting agent and water, characterized in that said dyestuff is a compound of the formula: wherein M1 and M2 are, the same or different, each a hydrogen atom, an alkali metal atom, an ammonium group or an organic ammonium group and X is an alkylamine or alkoxyalkylamine residue having 6 to 18 carbon atoms. Said ink composition is improved in storage stability, jet stability, image clarity, water resistance, etc.

  57 一种由染料、润湿剂和水组成的水性油墨组合物，其特征在于所述染料是式中的化合物： 其中 M1 和 M2 相同或不同，各自是氢原子、碱金属原子、铵基或有机铵基，X 是具有 6 至 18 个碳原子的烷基胺或烷氧基烷基胺残基。 所述油墨组合物在储存稳定性、喷射稳定性、图像清晰度、耐水性等方面均有改善。
• Azo compound and aqueous ink composition comprising the same
  申请人：TAOKA CHEMICAL CO., LTD

  公开号：EP0194885A1

  公开（公告）日：1986-09-17

  An azo compound of the formula wherein M1. M2 and M3 are, the same or different, each a hydrogen atom, an alkali metal atom, an ammonium group or an organic ammonium group; R1 and R2 are, the same or different, each a C-c3 alkyl group, a C1-C3 alkoxy group, a halogen atom or a hydrogen atom; m is 1 or 2; and X and Y are, the same or different, each a C6-C18 alkylamine, alkoxyalkylamine, arylamine, aralkylamine, alkanolamine or alkarylamine residue, which is useful as a magenta color dyestuff for an aqueous ink composition, particularly for ink jet recording.

  式中的偶氮化合物 其中 M1.M2和M3相同或不同，各自为氢原子、碱金属原子、铵基团或有机铵基团；R1和R2相同或不同，各自为C-c3烷基、C1-C3烷氧基、卤素原子或氢原子；m为1或2；X和Y相同或不同，各自为C6-C18烷基胺、烷氧基烷基胺、芳基胺、芳基胺、烷醇胺或烷芳基胺残基，可用作水性油墨组合物的洋红色染料，特别是用于喷墨记录。
• Quinoline derivative and use of same
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0818512A1

  公开（公告）日：1998-01-14

  Quinoline compound, zinc halogenide complex and zinc complex suited for use in an electro-luminescence element, a fluorescent material and an ultraviolet absorption material, and a preparation process for these compounds are described. These compounds and a tautomer of the same has a strong luminescent intensity and is used for an EL material, the compound of zinc halogenide complex and zinc complex and a tautomer of the same has absorption at a wave length of 400nm or less and is used for an ultraviolet absorption material, and further the quinoline compound and a tautomer has a strong luminescent intensity and is used for a fluorescent material. The zinc halogenide complex and zinc complex can be prepared by each other related preparation processes directly from a quinoline derivative and a phthalimide derivative, or by way of the quinoline compound which is obtained from these derivatives.

  描述了适用于电致发光元件、荧光材料和紫外线吸收材料的喹啉化合物、卤化锌络合物和锌络合物，以及这些化合物的制备工艺。 这些化合物及其同系物具有很强的发光强度，可用于电致发光材料；卤化锌络合物和锌络合物的化合物及其同系物在波长为 400nm 或以下时有吸收，可用于紫外线吸收材料；此外，喹啉化合物及其同系物具有很强的发光强度，可用于荧光材料。 卤化锌络合物和锌络合物可以直接从喹啉衍生物和邻苯二甲酰亚胺衍生物，或通过从这些衍生物中得到的喹啉化合物，通过彼此相关的制备工艺制备。
• Process for preparing 1,3-disubstituted urea
  申请人：SUMIKA FINE CHEMICALS Co., Ltd.

  公开号：EP0846679A2

  公开（公告）日：1998-06-10

  Process for preparing 1,3-disubstituted urea of the formula: wherein R5 is the same as or different from R6, and each of R5 and R6 is independently linear or branched, alkyl of 1-20 carbon atoms, alkenyl group having 2 to 20 carbon atoms or alkynyl group having 2 to 20 carbon atoms, which may have phenoxy, alkoxy of 1-13 carbon atoms, monocycloalkyl of 3-8 carbon atoms, bicycloalkyl of 6-12 carbon atoms, aryl of 6-13 carbon atoms, furyl, pyridyl, or aralkyl of 7-20 carbon atoms, comprising reacting cyclic carbonic acid ester with an amine using alkali metal alkoxide or trialkylamine as base, in safety and high yield.

  制备式 1，3-二取代脲的工艺： 其中 R5 与 R6 相同或不同，R5 和 R6 各自独立地为 1-20 个碳原子的直链或支链烷基、具有 2-20 个碳原子的烯基或具有 2-20 个碳原子的炔基，它们可以具有苯氧基、1-13 个碳原子的烷氧基、3-8 个碳原子的单环烷基、6-12 个碳原子的双环烷基、6-13 个碳原子的芳基、3-8 个碳原子的单环烷基、6-12 个碳原子的双环烷基、6-13 个碳原子的芳基、7-20 个碳原子的呋喃基、吡啶基或芳烷基，包括以碱金属氧化物或三烷基胺为碱，使环状碳酸酯与胺反应，安全且收率高。
• PERYLENE TETRACARBOXYDIIMIDE DERIVATIVE
  申请人：Dainichiseika Color & Chemicals Mfg. Co., Ltd.

  公开号：EP2471778A1

  公开（公告）日：2012-07-04

  Provided is a perylene tetracarboxylic diimide derivative represented by the following formula (1): In the formula (1), R1 means a linear or branched alkyl group having from 1 to 20 carbon atoms, R2 and R3 each independently mean a linear or branched alkyl group having from 2 to 6 carbon atoms, X1 and X2 each mean a hetero atom selected from an oxygen atom, sulfur atom or selenium atom, Y means a halogen atom or cyano group, m stands for a number of from 0 to 4, and n stands for a number of from 0 to 2.

  本发明提供了一种由下式（1）表示的过烯四羧酸二亚胺衍生物： 在式 (1) 中，R1 表示具有 1 至 20 个碳原子的直链或支链烷基，R2 和 R3 各自独立地表示具有 2 至 6 个碳原子的直链或支链烷基，X1 和 X2 各自表示选自氧原子、硫原子或硒原子的杂原子，Y 表示卤素原子或氰基，m 代表 0 至 4 的数字，n 代表 0 至 2 的数字。