3,5,6-Trifluor-4-(1-naphthoxy)phthalonitril | 25579-66-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,5,6-Trifluor-4-(1-naphthoxy)phthalonitril
• 英文别名: 4-(1-Naphthoxy)trifluorophthalonitrile；3,4,6-trifluoro-5-naphthalen-1-yloxybenzene-1,2-dicarbonitrile
• CAS: 25579-66-2
• 化学式: C₁₈H₇F₃N₂O
• 分子量: 324.262
• InChiKey: PCAQDONRUMSBJM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  56.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  3,5,6-Trifluor-4-(1-naphthoxy)phthalonitril 在 potassium carbonate 作用下， 以 N,N-二甲基乙酰胺 、 二甲基亚砜 、 乙腈 为溶剂， 反应 4.5h， 生成
  参考文献：
  名称：

  프탈로시아닌 화합물, 근적외선 흡수 색소 및 근적외선 흡수 재료

  摘要：

  这个句子已经是中文了，没有需要翻译的部分。

  公开号：

  KR20150107729A
• 作为产物：
  描述：

  3,4,5,6-四氯苯-1,2-二甲腈 在 sodium naphtholate 作用下， 以 甲醇 、 二甲基亚砜 为溶剂， 生成 3,5,6-Trifluor-4-(1-naphthoxy)phthalonitril
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.9, 7, page 50 - 101

  摘要：

  DOI：

文献信息

• Polyfluoroarenes. Part XI. Reactions of tetrafluorophthalonitrile with nucleophilic reagents
  作者：J. M. Birchall、R. N. Haszeldine、J. O. Morley

  DOI：10.1039/j39700000456

  日期：——

  monosubstituted products. Diethylphosphine, sodium benzenethiolate, lithium chloride, and lithium bromide give mainly 4,5-di- and 3,4,5,6-tetra-substituted products under the conditions described. The reaction with lithium chloride has also been applied to tetrafluorohydroquinone, and gives tetrachlorohydroquinone in high yield. Tetrafluorophthalonitrile reacts with arylamines and with polynuclear aromatic

  二甲基甲酰胺，1-萘甲酸钠，苯胺，N-甲基苯胺和氨容易影响四氟邻苯二甲腈中4位氟离子的亲核取代，从而获得高收率的单取代产物。在所述条件下，二乙基膦，苯硫醇钠，氯化锂和溴化锂主要得到4,5-二-和3,4,5,6-四取代的产物。与氯化锂的反应也已经应用于四氟氢醌，并以高收率得到四氯氢醌。四氟邻苯二甲腈在低极性溶剂中与芳胺和多核芳香烃反应，生成稳定的结晶分子络合物。
• TRIPHENYLAMINE DERIVATIVE AND USE THEREFOR
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20160087220A1

  公开（公告）日：2016-03-24

  A triphenylamine derivative represented by formula (1) exhibits good solubility in an organic solvent and allows an organic EL element having excellent luminance characteristics to be achieved when formed into a thin film and applied to a positive hole injection layer. (In the formula, R 1 to R 17 mutually independently represent a hydrogen atom, a halogen atom, a nitro group, a cyano group, an amino group, an aldehyde group, a hydroxyl group, a thiol group, a carboxylic acid group, and the like; and l, m, and n mutually independently represent an integer 1 to 5.)

  式（1）所代表的三苯胺衍生物在有机溶剂中具有良好的溶解性，并且当形成薄膜并应用于正孔注入层时，可以实现具有优异发光特性的有机EL元件。（在该式中，R1至R17相互独立地表示氢原子、卤素原子、硝基、氰基、氨基、醛基、羟基、硫醇基、羧酸基等；l、m和n相互独立地表示整数1至5。）
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.9, 7, page 50 - 101
  作者：

  DOI：——

  日期：——
• ARYLSULFONIC ACID COMPOUND AND USE THEREOF AS ELECTRON-ACCEPTOR MATERIAL
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20130240795A1

  公开（公告）日：2013-09-19

  Disclosed is an arylsulfonic acid compound characterized by being represented by formula (1). By using this compound as an electron-acceptor material, highly uniform film formability can be achieved. By using a thin film containing the arylsulfonic acid compound in an OLED device or a PLED device, there can be obtained excellent EL device characteristics such as low driving voltage, high luminous efficiency and long life. (In the formula, X represents O, S or NH; Ar represents an aryl group; and n represents the number of sulfonic groups, which is an integer of 1-4.)
• ANILINE DERIVATIVE, CHARGE-TRANSPORTING VARNISH AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20160141507A1

  公开（公告）日：2016-05-19

  Provided is an aniline derivative represented by formula (1). (In formula (1), R 1 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group having 6-20 carbon atoms, a heteroaryl group, or a group represented by formula (2), and R 2 -R 55 independently represent a hydrogen atom, a halogen atom, a nitro group, a cyano group, an aldehyde group, a hydroxy group, a thiol group, a carboxylic acid group, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, etc.)