quinolinium bromide | 32353-67-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: quinolinium bromide
• 英文别名: quinoline*HBr；quinoline hydrobromide；Chinoliniumhydrobromid；quinoline;hydrobromide
• CAS: 32353-67-6
• 化学式: Br*C₉H₈N
• 分子量: 210.073
• InChiKey: YHQSXWOXIHDVHQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.34
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  14.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  quinolinium bromide 在 FeBr₃ 、 HBr 作用下， 以 not given 为溶剂， 生成 quinolinium iron(III) bromide
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Fe: MVol.B5, 1.4.7.18, page 1030 - 1034

  摘要：

  DOI：
• 作为产物：
  描述：

  喹啉 、 (α-bromovinyl)dimethylchlorosilane 生成 quinolinium bromide
  参考文献：
  名称：

  MATSUMOTO HIDEYUKI; KATO TAKAYUKI; MATSUBARA IKUYA; HOSHINO YOSHIKAZU; NA+, CHEM. LETT., 1979, NO 10, 1287-1290

  摘要：

  DOI：
• 作为试剂：
  描述：

  3-甲基-1,2-丁二烯 在 喹啉 、 lead(II) hydroxide on calcium carbonate 、 水 、 氢溴酸 、 quinolinium bromide 作用下， 生成 3-甲基-2-丁酮
  参考文献：
  名称：

  Pd Deposition onto the Thermally Roughened Cu(110) Surface

  摘要：

  We study the deposition of Pd onto two morphologically distinct Cu(110) surfaces: the first being the surface prepared by conventional ion bombardment and anneal cycles and the second being the thermally roughened surface consisting of a well-defined surface morphology of large terraces terminated by exclusively monoatomic height steps. We use the optical technique of reflection anisotropy spectroscopy in combination with scanning tunnelling microscopy to characterise the deposition. We find that the morphological nature of the Cu(110) surface results in a different surface reconstruction for the same conditions of Pd deposition.

  DOI：

  10.1002/1521-396x(200112)188:4<1505::aid-pssa1505>3.0.co;2-8

文献信息

• [EN] TRPV4 ANTAGONISTS<br/>[FR] ANTAGONISTES DE TRPV4
  申请人：GLAXOSMITHKLINE LLC

  公开号：WO2011119701A1

  公开（公告）日：2011-09-29

  The present invention relates to quinoline analogs, pharmaceutical compositions containing them and their use as TRPV4 antagonists.

  本发明涉及喹啉类似物、含有它们的药物组合物以及它们作为TRPV4拮抗剂的用途。
• PHOTO LEWIS ACID GENERATOR
  申请人：Nippon Shokubai Co., Ltd.

  公开号：US20200062783A1

  公开（公告）日：2020-02-27

  Provided is a compound capable of generating a Lewis acid in response to light unlike conventional photo acid generators. The compound comprises an anionic moiety having a central boron atom and a particular cationic moiety (for example, a cation having a HOMO-LUMO gap of 5.3 eV or less). The cationic moiety may, for example, have a skeleton selected from an N-substituted pyridinium skeleton, an N-substituted bipyridinium skeleton, an N-substituted quinolinium skeleton, and a pyrylium skeleton.

  提供一种化合物，能够产生与传统光酸发生器不同的路易斯酸。该化合物包括具有中心硼原子的阴离子基团和特定阳离子基团（例如，具有5.3电子伏特或更低的HOMO-LUMO能隙的阳离子基团）。阳离子基团可以选择具有N-取代吡啶骨架、N-取代联吡啶骨架、N-取代喹啉骨架和吡啉骨架的骨架之一。
• Corrosion Inhibition
  申请人：Schlumberger Technology Corporation

  公开号：US20180135187A1

  公开（公告）日：2018-05-17

  Corrosion of steel in acidic solution is inhibited using a mixture of a compound in which a plurality of heterocyclic aromatic groups with a quaternary nitrogen atom are connected together, such as by a linking group which may be covalently attached to the quaternary nitrogen atoms of the aromatic heterocyclic rings, and a polarizable adsorption-intensifying anion.

  在酸性溶液中，使用一种混合物来抑制钢铁的腐蚀，这种混合物包括多个杂环芳香基团与季铵氮原子连接在一起的化合物，例如通过可能共价连接到芳香杂环环的季铵氮原子的连接基团，以及一种极化吸附增强阴离子。
• Quinoline derivatives as anti-inflammatory agents
  申请人：——

  公开号：US20020082276A1

  公开（公告）日：2002-06-27

  This invention relates to compounds, which are generally anti-inflammatory and analgesic compounds, and which are represented by Formula I: 1 wherein A is a CH 2 , CH(OH), C(O), C═NOR 4 , NR 5 , O, S, S(O), or S(O) 2 , and the other substituents are as defined in the specification; or prodrugs, individual isomers, mixtures of isomers, and pharmaceutically acceptable salts thereof. The invention further relates to pharmaceutical compositions containing such compounds and methods for their use as therapeutic agents

  这项发明涉及化合物，通常是抗炎和镇痛化合物，其表示为公式I：其中A是CH2、CH(OH)、C(O)、C═NOR4、NR5、O、S、S(O)或S(O)2，其他取代基如规范中定义；或其前药、单体异构体、异构体混合物和药用盐。该发明还涉及含有这些化合物的药物组合物以及它们作为治疗剂的使用方法。
• CHEMOSENSOR AND A METHOD OF DETECTING PALLADIUM IONS
  申请人：King Fahd University of Petroleum and Minerals

  公开号：US20200392148A1

  公开（公告）日：2020-12-17

  A palladium selective chemosensor based on a fluorescein-allyloxy benzene scaffold and a method of detecting palladium ions in a fluid sample with the chemosensor, whereby the fluid sample is contacted with a solution that includes water and the chemosensor to form a mixture. An ultraviolet visible absorption profile and/or a fluorescence emission profile of the mixture is measured to determine a presence or absence of palladium ions in the fluid sample, wherein the chemosensor has an ultraviolet visible absorption peak at 315 to 325 nm and a fluorescence emissions peak at 380 to 400 nm in the solution, and wherein a bathochromic shift in the ultraviolet visible absorption peak to 338 to 342 nm in the mixture and/or a bathochromic shift in the fluorescence emissions peak to 530 to 550 nm in the mixture indicates the presence of palladium ions in the fluid sample.

  一种基于荧光素-烯丙氧基苯基骨架的钯选择性化学传感器，以及使用该化学传感器检测液体样品中钯离子的方法，其中将液体样品与包括水和化学传感器的溶液接触以形成混合物。测量混合物的紫外可见吸收谱和/或荧光发射谱以确定液体样品中钯离子的存在或不存在，其中化学传感器在溶液中具有315至325 nm的紫外可见吸收峰和380至400 nm的荧光发射峰，在混合物中紫外可见吸收峰向338至342 nm的巴氏红移和/或荧光发射峰向530至550 nm的巴氏红移表明液体样品中存在钯离子。