烯丙基1H,1H-全氟辛基醚 | 812-72-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 烯丙基1H,1H-全氟辛基醚
• 英文名称: 8-(allyloxyl)-1,1,1,2,2,3,3,4,4,5,5,6,6,7,7-pentadecafluorooctane
• 英文别名: 1H,1H-pentadecafluorooctyl allyl ether；n-pentadecafluorooctyl allyl ether；3-(1H,1H-pentadecafluoro-octyloxy)-propene；<1H.1H-Perfluor-octyl>-allyl-aether；Allyl-<1H,1H-perfluor-octylaether>；Allyl 1H,1H-perfluorooctyl ether；1,1,1,2,2,3,3,4,4,5,5,6,6,7,7-pentadecafluoro-8-prop-2-enoxyoctane
• CAS: 812-72-6
• 化学式: C₁₁H₇F₁₅O
• mdl: MFCD00042149
• 分子量: 440.152
• InChiKey: DPOFHGRLDJWXKJ-UHFFFAOYSA-N

物化性质

• 沸点：
  178°C
• 密度：
  1,561 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  27
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.818
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  16

安全信息

• 危险类别码：
  R36/37/38
• 安全说明：
  S26,S36/37/39
• 储存条件：
  室温

上下游信息

• 上游原料

  中文名称	英文名称	CAS号	化学式	分子量
  2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五氟辛-1-醇	2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol	307-30-2	C8H3F15O	400.087
  全氟辛酸乙酯	ethyl perfluorooctanoate	3108-24-5	C10H5F15O2	442.125
  全氟辛酸	Perfluorooctanoic acid	335-67-1	C8HF15O2	414.071

• 下游产品

  中文名称	英文名称	CAS号	化学式	分子量
  ——	trichloro-3-(1H,1H-pentadecafluorooctyloxy)propylsilane	755-08-8	C11H8Cl3F15OSi	575.604

反应信息

• 作为反应物：
  描述：

  烯丙基1H,1H-全氟辛基醚 在 铂 dihydrogen hexachloroplatinate 、 lithium aluminium tetrahydride 、 三氯硅烷 作用下， 生成 Diaethoxy-[3-(1H,1H-pentadecafluoroctyloxy)-propyl]-silan
  参考文献：
  名称：

  Fluoroalkyl- and 3-(Fluoroalkoxy)propylpolysiloxanes

  摘要：

  DOI：

  10.1021/jo01066a076
• 作为产物：
  描述：

  全氟辛酸 在 lithium aluminium tetrahydride 、 硫酸 、 potassium carbonate 作用下， 以 丙酮 为溶剂， 生成 烯丙基1H,1H-全氟辛基醚
  参考文献：
  名称：

  Fluoroalkyl- and 3-(Fluoroalkoxy)propylpolysiloxanes

  摘要：

  DOI：

  10.1021/jo01066a076

文献信息

• Dynamic Contact Angle Studies of Self-Assembled Thin Films from Fluorinated Alkyltrichlorosilanes
  作者：Mark J. Pellerite、Erika J. Wood、Vivian W. Jones

  DOI：10.1021/jp013820m

  日期：2002.5.1

  Dynamic contact angle studies on self-assembled thin films from C7F15CH2OCH2CH2CH2SiCl3 reveal a range of interesting behavior. Solution-based processing conditions have been identified that allow preparation of essentially monolayer films on quartz exhibiting water adv/rec contact angles of 119/104 ± 2° and extremely low contact angle hysteresis (hexadecane adv/rec = 74/70°, heptane adv/rec = 56/55°)

  对 C7F15CH2OCH2CH2CH2SiCl3 自组装薄膜的动态接触角研究揭示了一系列有趣的行为。已经确定了基于溶液的加工条件，允许在石英上制备基本上单层的薄膜，其水接触角为 119/104 ± 2°，接触角滞后极低（十六烷 adv/rec = 74/70°，庚烷 adv /rec = 56/55°) 与烃类液体。这种化合物提供了一个氟化三氯硅烷的例子，它能够通过在室温下沉积来提供低滞后薄膜。还发现通过溶液中的水解和缩合反应形成的硅烷低聚物的吸附发生，比单层形成慢但与单层形成竞争。随着浸涂时间的增加，这一过程变得更加重要。硅晶片上的椭偏数据证实薄膜厚度随着浸渍时间的增加而增加，而 AFM 成像显示低聚物材料以颗粒的形式沉积。效果...
• Fluorinated polyhedral oligomeric silsesquioxanes
  作者：Xiaobai Wang、Qun Ye、Jing Song、Ching Mui Cho、Chaobin He、Jianwei Xu

  DOI：10.1039/c4ra15108a

  日期：——

  A series of fluorinated polyhedral oligomeric silsesquioxane (POSS) derivatives were prepared via hydrosilylation reaction and they were characterized by 1H, 13C, 29Si and 19F nuclear magnetic resonance (NMR) spectroscopy and elemental analysis. The thermal stability of POSS derivatives was studied using thermogravimetric analysis (TGA) and they exhibited high decomposition temperatures ranging from

  通过氢化硅烷化反应制备了一系列氟化多面体低聚倍半硅氧烷（POSS）衍生物，并通过1 H，13 C，29 Si和19 F核磁共振（NMR）光谱和元素分析对其进行了表征。使用热重分析（TGA）研究了POSS衍生物的热稳定性，它们在空气和惰性气氛中表现出327至380°C的高分解温度。在环境温度下，氟化POSS（FluoroPOSS）化合物3a–b和3d–e表现为动态粘度为140–430 mPas的流体油，值得注意的是3a，3d和3e即使在−80°C以下也不要固化。进行了这些FluoroPOSS油的热老化实验，结果表明，这些油表现出优异的长期热稳定性，并在空气中48小时内失重最少，使其成为从- 80至300°C。这些氟化的POSS衍生物还显示出了聚合物表面改性的潜力，这由水接触角从纯亲水性PMMA膜的〜68°到含有5 wt％氟化衍生物的共混膜的94-105°大大增加所证明。水接触角的增加很可能是
• Fluorochemical treatment for silicon articles
  申请人：3M Innovative Properties Company

  公开号：US20030226818A1

  公开（公告）日：2003-12-11

  Silicon substrates having Si—H bonds are chemically modified using a fluorinated olefin having the formula: 1 wherein m is an integer greater than or equal to 1; n is an integer greater than or equal to 0; Z is a divalent linking group; and R f is a highly fluorinated organic group.

  具有Si-H键的硅衬底通过使用具有以下公式的氟代烯烃进行化学修饰：1其中m是大于或等于1的整数；n是大于或等于0的整数；Z是二价连接基团；Rf是高度氟化的有机基团。
• CURABLE POLYSILOXANE COMPOSITIONS AND SLIPPERY MATERIALS AND COATINGS AND ARTICLES MADE THEREFROM
  申请人：ADAPTIVE SURFACE TECHNOLOGIES, INC.

  公开号：EP3489010A1

  公开（公告）日：2019-05-29

  The present teachings generally provide curable polysiloxane compositions including a base resin and a lubricating liquid. The curable polysiloxane compositions can create a slippery material or coating, where an overlayer of the lubricating liquid is spontaneously presented at an exposed surface of the cured base resin. Articles of manufacture including the curable polysiloxane compositions and slippery coatings and materials also are provided. Per some aspects of the invention addition and condensation based curable silicone coating composition is provided which may be used to to provide slippery, lubricious, or repellent materials and coatings against a fluid matter including water, oil, viscous fluids, slurries, complex fluid mixtures with or without solids in them, biological fluids and organisms, bodily fluids, ice, frost, and mixtures thereof; to reduce drag or friction; to enhance product performance by providing slippery feeling, by providing anti-fouling function, by providing application mechanism of payloads such as lubricants, personal care products, drug molecules, and biocides; to provide non-stick or easy-to-clean function; to provide anti-fouling or foul-release function on open surfaces, internal surfaces, membranes; to provide pinning free or low contact angle hysteresis surfaces; to provide homogeneous interface to suppress nucleation; to provide a barrier layer such as anti-corrosion; to provide anti-stain, anti-smudge, anti-fingerprint, anti-soil function. The curable silicone coating composition of the present invention comprises a stable thin liquid overlayer (LOL) leading to a slippery surface with very low roll-off angle for water typically seen as equal or greater than 15 degrees when a 15 uL water droplet is applied on said slippery surfaces. In addition, the curable polysiloxane compositons can further incorporate at least one or more surface active amphiphilic polymers leading to a self-lubricating amphiphilic slippery coating, and can incorporate optional biocides and/or biocidal effect boosters that can further impart anti-biofouling functions in both static and dynamic conditions.

  本教导一般提供可固化的聚硅氧烷组合物，包括基底树脂和润滑液体。可固化的聚硅氧烷组合物可以制成滑爽的材料或涂层，其中润滑液体的覆盖层会自发地呈现在固化的基础树脂的暴露表面。本发明还提供了包括可固化聚硅氧烷组合物和滑爽涂层及材料的制造物品。根据本发明的某些方面，本发明提供了基于添加和缩合的可固化有机硅涂料组合物，可用于提供防滑、润滑或排斥流体物质的材料和涂料，这些流体物质包括水、油、粘性流体、泥浆、含有或不含固体的复杂流体混合物、生物流体和有机体、体液、冰、霜及其混合物；以减少阻力或摩擦；通过提供滑爽感、防污功能、提供有效载荷（如润滑剂、个人护理产品、药物分子和杀菌剂）的应用机制来提高产品性能；提供不粘性或易清洁功能；在开放表面、内表面、膜上提供防污或除污功能；提供无针刺或低接触角滞后表面；提供均匀界面以抑制成核；提供阻挡层，如防腐蚀；提供防污、防污迹、防指纹、防污功能。本发明的可固化有机硅涂料组合物包括一个稳定的薄液体覆盖层（LOL），可形成滑爽的表面，当 15 uL 的水滴在所述滑爽表面上时，水的滚落角非常低，通常等于或大于 15 度。此外，可固化的聚硅氧烷复合物还可进一步加入至少一种或多种表面活性两性聚合物，形成自润滑的两性滑爽涂层，并可加入任选的杀菌剂和/或杀菌效果增强剂，进一步增强静态和动态条件下的防生物污染功能。
• Curable polysiloxane compositions and slippery materials and coatings and articles made therefrom
  申请人：Adaptive Surface Technologies, Inc.

  公开号：US10240067B2

  公开（公告）日：2019-03-26

  The present teachings generally provide curable polysiloxane compositions including a base resin including a MQ vinyl siloxane. Articles of manufacture including the curable polysiloxane compositions and slippery coatings and materials also are provided. The compositions may be used to provide slippery, lubricious, or repellent materials and coatings and may provide anti-fouling function. The compositions can provide anti-fouling or foul-release function on open surfaces, internal surfaces, membranes; to provide pinning free or low contact angle hysteresis surfaces; to provide homogeneous interface to suppress nucleation; to provide a barrier layer such as anti-corrosion; to provide anti-stain, anti-smudge, anti-fingerprint, anti-soil function.

  本教导一般提供可固化的聚硅氧烷组合物，包括一种包括 MQ 乙烯基硅氧烷的基础树脂。还提供了包括可固化聚硅氧烷组合物和防滑涂层及材料的制造物品。这些组合物可用于提供防滑、润滑或驱避材料和涂层，并可提供防污功能。这些组合物可在开放表面、内表面、膜上提供防污或除污功能；提供无针刺或低接触角滞后表面；提供均匀界面以抑制成核；提供屏障层，如防腐蚀；提供防污、防污迹、防指纹、防污功能。