1-(s-butyl)cyclohexene | 71618-95-6

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 1-(s-butyl)cyclohexene
• 英文别名: (+/-)-1-sec-butyl-cyclohexene-(1)；(+/-)-1-sek.-Butyl-cyclohexen-(1)；1-sek.-Butyl-cyclohexen；1-s-Butylcyclohex-1-ene；1-butan-2-ylcyclohexene
• CAS: 71618-95-6
• 化学式: C₁₀H₁₈
• 分子量: 138.253
• InChiKey: IOERJMOJJLOARF-UHFFFAOYSA-N

物化性质

• 沸点：
  172-174 °C
• 密度：
  0.829 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  仲丁基苯 在 calcium tetraammine 、 乙醚 作用下， 生成 1-(s-butyl)cyclohexene
  参考文献：
  名称：

  Chromow; Rumjanzewa, Zhurnal Obshchei Khimii, 1945, vol. 15, p. 363,365

  摘要：

  DOI：

文献信息

• The Reaction of Organoboranes with Lithium Salts of Trisylhydrazones of Cycloalkanones Followed by Treatment with Iodine
  作者：Tsutomu Baba、Kamlakar Avasthi、Akira Suzuki

  DOI：10.1246/bcsj.56.1571

  日期：1983.5

  The titled reaction proceeds smoothly under mild conditions to give corresponding 1-alkylcycloalkenes in excellent yields. The overall reaction provides a convenient synthetic procedure of cycloalkenes for cycloalkanones, with various alkyl substituents readily available by means of hydrobortation.

  标题反应在温和条件下顺利进行，以优异的产率得到相应的 1-烷基环烯烃。整个反应为环烷酮提供了一种方便的环烯烃合成方法，其中各种烷基取代基很容易通过硼氢化反应获得。
• Beger, J.; Thomas, B.; Vogel, T., Journal fur praktische Chemie (Leipzig 1954), 1991, vol. 333, # 3, p. 481 - 488
  作者：Beger, J.、Thomas, B.、Vogel, T.、Kirmse, K.、Lang, R.

  DOI：——

  日期：——
• Ionic-liquid-like copolymer stabilized nanocatalysts in ionic liquids: II. Rhodium-catalyzed hydrogenation of arenes
  作者：C ZHAO、H WANG、N YAN、C XIAO、X MU、P DYSON、Y KOU

  DOI：10.1016/j.jcat.2007.05.014

  日期：2007.8.15

  Rhodium nanoparticles stabilized by the ionic-liquid-like copolymer poly [(N -vinyl-2-pyrrolidone)-co-(1-vinyl-3-butylimidazolium chloride)] were used to catalyze the hydrogenation of benzene and other arenes in ILs. The nanoparticle catalysts can endure forcing conditions (75 degrees C, 40 bar H-2), resulting in high reaction rates and high conversions compared with other nanoparticles that operate in ILs. The hydrogenation of benzene attained record total turnovers of 20,000, and the products were easily separated without being contaminated by the catalysts. Other substrates, including alkyl-substituted arenes, phenol, 4-n-propyl phenol, 4-methoxyl phenol, and phenyl-methanol, were studied and in most cases were found to afford partially hydrogenated products in addition to cyclohexanes. In-depth investigations on reaction optimization, including characterization of copolymers, transmission electron microscopy, and an infrared spectroscopic study of nanocatalysts, were also undertaken. (c) 2007 Elsevier Inc. All rights reserved.
• BABA, TSUTOMU;AVASTHI, KAMLAKAR;SUZUKI, AKIRA, BULL. CHEM. SOC. JAP., 1983, 56, N 5, 1571-1572
  作者：BABA, TSUTOMU、AVASTHI, KAMLAKAR、SUZUKI, AKIRA

  DOI：——

  日期：——