1-(2-hydroxyethoxy)-2,7-octadiene | 75320-42-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(2-hydroxyethoxy)-2,7-octadiene
• 英文别名: trans 1-hydroxy-2-(2,7-octadienyl-1-oxy)ethane；2-octa-2,7-dienyloxyethanol；2-[(2E)-octa-2,7-dienoxy]ethanol
• CAS: 75320-42-2
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: BLHPBLHXZZXLRT-VOTSOKGWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,3-丁二烯 、 乙二醇 、 三苯基膦 以74%的产率得到
  参考文献：
  名称：

  DZHEMILEV U. M.; KUNAKOVA R. V.; BAJBULATOVA N. Z.; TOLSTIKOV G. A.; PANA+, ZH. ORGAN. XIMII, 1980, 16, HO 6, 1157-1161

  摘要：

  DOI：

文献信息

• Process of telomerizing conjugated dienes
  申请人：Celanese Chemicals Europe GmbH

  公开号：EP1201634A1

  公开（公告）日：2002-05-02

  The present invention is related to a process for telomerizing a conjugated diene which comprises reacting said conjugated diene with a compound containing active hydrogen in the presence of a catalyst system comprising at least one transition metal compound, at least one phosphorus-containing compound, and at least one salt which forms a liquid under the conditions of the telomerization process.

  本发明涉及一种用于对共轭二烯进行缩聚的方法，包括在存在至少一种过渡金属化合物、至少一种含磷化合物和至少一种在缩聚过程条件下形成液体的盐的催化剂体系的情况下，将所述共轭二烯与含活性氢的化合物反应的过程。
• (METH)ACRYLATE MONOMER, POLYMER AND COATING AGENT
  申请人：Schuetz Thorben

  公开号：US20110130509A1

  公开（公告）日：2011-06-02

  The present invention relates to a (meth)acrylate monomer of the general formula (I) in which R 1 is hydrogen or a methyl group, X is oxygen or a group of the formula NR′ in which R′ is hydrogen or a radical having 1 to 6 carbon atoms, R 2 is an alkylene group having 1 to 22 carbon atoms, Y is oxygen, sulphur or a group of the formula NR″, in which R″ represents hydrogen or a radical having 1 to 6 carbon atoms, and R 3 is an unsaturated radical having 8 carbon atoms and at least two double bonds. The present invention further relates to a process for preparing the monomers set out above, to polymers obtainable from this monomer mixture, and to coating materials which comprise the stated polymers.

  本发明涉及一种通式（I）的（甲基）丙烯酸酯单体，其中R1为氢或甲基基团，X为氧或式NR′的基团，其中R′为氢或具有1至6个碳原子的基团，R2为具有1至22个碳原子的烷基基团，Y为氧、硫或式NR″的基团，其中R″表示氢或具有1至6个碳原子的基团，而R3为具有8个碳原子和至少两个双键的不饱和基团。本发明还涉及一种制备上述单体的方法，以及从该单体混合物得到的聚合物和包含所述聚合物的涂料材料。
• Reactive diluents in coating formulation
  申请人：Gracey Patrick Benjamin

  公开号：US20070060713A1

  公开（公告）日：2007-03-15

  A composition for use as an reactive diluent is prepared by reacting an allylic alcohol with an epoxide in the presence of a suitable catalyst to form a hydroxy ether, which is further reacted with an aldehyde or a carboxylic acid or derivative using a catalyst that does not induce undue polymerization or rearrangement to form- an ether ester or -acetal- composition useful as an reactive diluent.

  制备用作反应性稀释剂的组合物，通过在适当催化剂的存在下将烯丙醇与环氧化合物反应，形成羟基醚，然后再使用不会引起过度聚合或重排的催化剂将其与醛或羧酸或衍生物进一步反应，形成醚酯或缩醛组成的组合物，该组合物可用作反应性稀释剂。
• Imidazolium salts and their use of these ionic liquids as a solvent
  申请人：——

  公开号：US20040026666A1

  公开（公告）日：2004-02-12

  New 1,2,3- or 1,2,3,4- or 1,2,3,4,5- substituted imidazolium salts and their uses as solvent in catalyzed organic reactions, as well as compositions containing them and a transition metal compound. They can be used in the following reactions: the telomerisation of conjugated dienes, dimerisation of olefins, the oligomerisation of olefins, polymerization of olefins, alkylation of olefins, hydrogenation of olefins, olefin metathesis, hydroformylation of olefins, ring-closing metathesis of olefins, ring-opening metathesis polymerisation of olefins, symetric or asymetric epoxidation of olefins (including heteroatom substituted olefins) and the cyclopropanation of olefins, condensation reaction, hydrogenation reaction, isomerization reaction, Suzuki cross-coupling reactions, amination reaction, partial oxidation of alkancs, kinetic resolution of racemic mixtures, hydrogenation of imines, hydrogenation of ketones, transfer hydrogenation and hydroxylation of aromatic organic compounds.

  新型 1,2,3- 或 1,2,3,4- 或 1,2,3,4,5- 取代的咪唑鎓盐及其在催化有机反应中作为溶剂的用途，以及含有它们和过渡金属化合物的组合物。它们可用于以下反应：共轭二烯的端聚反应、烯烃的二聚反应、烯烃的低聚反应、烯烃的聚合反应、烯烃的烷基化反应、烯烃的氢化反应、烯烃的元合成反应、烯烃的氢甲酰化反应、烯烃的闭环元合成反应、烯烃的开环元合成聚合反应、烯烃（包括杂原子取代的烯烃）的对称或不对称环氧化反应以及烯烃的环丙烷化反应、缩合反应、氢化反应、异构化反应、铃木交叉偶联反应、胺化反应、烷烃的部分氧化、外消旋混合物的动力学解析、亚胺的氢化、酮的氢化、芳香族有机化合物的转移氢化和羟基化。
• Imidazolium salts and the use of these ionic liquids as a solvent and as a catalyst
  申请人：CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)

  公开号：EP1201657B1

  公开（公告）日：2004-05-06