3,6,9-trioxa-11,12-epoxy-1-dodecanol | 17557-20-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,6,9-trioxa-11,12-epoxy-1-dodecanol
• 英文别名: 2-<2-(((2-oxiranylmethoxy)ethoxy)ethoxy)>ethanol；2-(2-{2-[(Oxiran-2-yl)methoxy]ethoxy}ethoxy)ethan-1-ol；2-[2-[2-(oxiran-2-ylmethoxy)ethoxy]ethoxy]ethanol
• CAS: 17557-20-9
• 化学式: C₉H₁₈O₅
• 分子量: 206.239
• InChiKey: ACKPSZGIQNQZLW-UHFFFAOYSA-N

物化性质

• 沸点：
  165-166 °C(Press: 5 Torr)
• 密度：
  1.1060 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  -1.2
• 重原子数：
  14
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  60.4
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3,6,9-trioxa-11,12-epoxy-1-dodecanol 在 lithium tetrafluoroborate 、 三氟化硼乙醚 作用下， 以 1,4-二氧六环 为溶剂， 以48%的产率得到1,4,7,10-四氧杂环十三烷-12-醇
  参考文献：
  名称：

  Shabanov, A. L.; Ismiev, I. I.; Magerramova, L. M., Journal of Organic Chemistry USSR (English Translation), 1987, vol. 23, # 2, p. 251 - 254

  摘要：

  DOI：
• 作为产物：
  描述：

  2-(2-(2-(allyloxy)ethoxy)ethoxy)ethanol 在 间氯过氧苯甲酸 作用下， 以 氯仿 为溶剂， 反应 2.0h， 以77%的产率得到3,6,9-trioxa-11,12-epoxy-1-dodecanol
  参考文献：
  名称：

  Di-, tri-, tetra-, and pentacationic alkylammonium salts. Ligands designed to prevent the nonspecific electrostatic precipitation of polyanionic, functionalized cyclopentadienyltitanium-substituted heteropolytungstate electron microscopy labels with cationic biomolecules

  摘要：

  DOI：

  10.1021/jo00388a041

文献信息

• Ion-conductive polymer electrolyte
  申请人：DAI-ICHI KOGYO SEIYAKU CO., LTD.

  公开号：EP0392839A2

  公开（公告）日：1990-10-17

  An ion-conductive polymer electrolyte comprises an organic polymer and a soluble electrolyte salt. The organic polymer is obtained by crosslinking a compound having an average molecular weight of 1,000 to 20,000 and having a structure of the following formula ①; in which Z is a residue of a compound having at least one active hydrogen, Y is a hydrogen atom or polymerizable functional group, m is an integer of 1 to 250, n is 0 or an integer of 1 to 25, k is an integer of 1 to 12, R is an alkyl, alkenyl, aryl or alkylaryl group having 1 to 20 carbon atoms. While the compound represented by the formula ① in which Y is a hydrogen atom may be crosslinked with a crosslinking agent such as an isocyanate compound, the compound having a structure of the formula ① in which Y is a polymerizable functional group may be crosslinked by itself.

  一种离子导电聚合物电解质包括一种有机聚合物和一种可溶性电解质盐。有机聚合物是通过交联平均分子量为 1,000 至 20,000 并具有下式①结构的化合物而获得的； 其中 Z 是至少有一个活性氢的化合物残基，Y 是氢原子或可聚合官能团，m 是 1 至 250 的整数，n 是 0 或 1 至 25 的整数，k 是 1 至 12 的整数，R 是具有 1 至 20 个碳原子的烷基、烯基、芳基或烷基芳基。虽然 Y 为氢原子的式 ① 所表示的化合物可与异氰酸酯化合物等交联剂交联，但具有 Y 为可聚合官能团的式 ① 结构的化合物本身也可交联。
• Electrophotographic photosensitive member and apparatus using same
  申请人：CANON KABUSHIKI KAISHA

  公开号：EP0498626A1

  公开（公告）日：1992-08-12

  A photosensitive member suitable for use in an electrophotographic apparatus is constituted by an electroconductive support, and an intermediate layer and a photosensitive layer disposed in this order on the support. The intermediate layer comprises a reaction product of a polyol compound comprising at least one of a polyol compound [I] represented by Formula (1) shown below and a phosphated polyol compound with a polyisocyanate compound: wherein A denotes B denotes -R⁴-O-, A and B may be connected at random or in blocks with each other, Z denotes an active hydrogen compound residue; R¹ is an alkylene group having 1 - 9 carbon atoms; R² is an alkylene group having 1 - 10 carbon atoms; R³ is an alkyl group, alkenyl group, aryl group or aralkyl group having 1 - 20 carbon atoms; R⁴ is an alkylene group having 2 - 10 carbon atoms; k is a number of 1 - 12; m is a number of 1 - 250; n is a number of 0 - 100; and p is a number of 0 - 5.

  一种适用于电子照相设备的感光构件由导电支架、依次设置在支架上的中间层和感光层构成。中间层由多元醇化合物与多异氰酸酯化合物的反应产物组成，多元醇化合物包括下图中式（1）表示的多元醇化合物[I]和磷化多元醇化合物中的至少一种： 其中 A 表示 B 表示 -R⁴-O-，A 和 B 可以任意连接或相互成块连接，Z 表示活性氢化合物残基；R¹ 是具有 1 - 9 个碳原子的亚烷基；R² 是具有 1 - 10 个碳原子的亚烷基；R³ 是具有 1 - 20 个碳原子的烷基、烯基、芳基或芳烷基；R⁴ 是具有 2 - 10 个碳原子的亚烷基；k 是 1 - 12 的数字；m 是 1 - 250 的数字；n 是 0 - 100 的数字；p 是 0 - 5 的数字。
• Use of modified galactomannans for protecting dyed hair color from fading
  申请人：Rhodia Opérations

  公开号：EP2520276A1

  公开（公告）日：2012-11-07

  This invention relates to the use of modified galactomannans in a hair composition for protecting dyed hair color from fading and to a method for protecting dyed hair color from fading by treating said hair with a hair composition containing a modified galactomannan.

  本发明涉及在头发组合物中使用改性半乳甘露聚糖，以保护染发颜色不褪色，还涉及用含有改性半乳甘露聚糖的头发组合物处理头发，以保护染发颜色不褪色的方法。
• PHOTOSENSITIVE RESIN COMPOSITION, CURED FILM, ELEMENT PROVIDED WITH CURED FILM, AND METHOD FOR MANUFACTURING SEMICONDUCTOR DEVICE
  申请人：Toray Industries, Inc.

  公开号：EP3203320A1

  公开（公告）日：2017-08-09

  To provide a photosensitive resin composition which is capable of forming a pattern with high resolution and obtaining a cured film having excellent heat resistance and cracking resistance, and is also alkali developable; and a method capable of shortening the step required to remove a cured film of the composition after formation of an impurity region on a semiconductor substrate; and a method for manufacturing a semiconductor device using the same. Disclosed is a photosensitive resin composition including a polysiloxane (A), wherein the polysiloxane (A) is a polysiloxane represented by the general formula (1), and wherein (X) and (Y) are represented by the general formulas (4) to (6). 7.5≤X≤75 2.5≤Y≤40 1.5×Y≤X≤3×Y

  提供一种光敏树脂组合物，该组合物能够形成具有高分辨率的图案并获得具有优异的耐热性和抗裂性的固化膜，而且还可进行碱显影；提供一种方法，该方法能够缩短在半导体衬底上形成杂质区后去除该组合物固化膜所需的步骤；以及提供一种使用该组合物制造半导体器件的方法。公开了一种包括聚硅氧烷(A)的光敏树脂组合物，其中聚硅氧烷(A)是由通式(1)表示的聚硅氧烷，且(X)和(Y)由通式(4)至(6)表示。7.5≤x≤75 2.5≤y≤40 1.5×y≤x≤3×y
• Photosensitive resin composition, cured film, element provided with cured film, and method for manufacturing semiconductor device
  申请人：TORAY INDUSTRIES, INC.

  公开号：US10409163B2

  公开（公告）日：2019-09-10

  To provide a photosensitive resin composition which is capable of forming a pattern with high resolution and obtaining a cured film having excellent heat resistance and cracking resistance, and is also alkali developable; and a method capable of shortening the step required to remove a cured film of the composition after formation of an impurity region on a semiconductor substrate; and a method for manufacturing a semiconductor device using the same. Disclosed is a photosensitive resin composition including a polysiloxane (A).

  提供一种光敏树脂组合物，该组合物能够形成高分辨率的图案并获得具有优异耐热性和抗裂性的固化膜，而且还可进行碱显影；提供一种方法，该方法能够缩短在半导体衬底上形成杂质区后去除该组合物固化膜所需的步骤；以及提供一种使用该组合物制造半导体器件的方法。本发明公开了一种包括聚硅氧烷（A）的光敏树脂组合物。