1,3,3-Trimethylcyclopenten | 57497-14-0

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 1,3,3-Trimethylcyclopenten
• 英文别名: cis-3-Trimethyl cyclopentene；1,3,3-trimethylcyclopentene
• CAS: 57497-14-0
• 化学式: C₈H₁₄
• 分子量: 110.199
• InChiKey: WIOCDNGMFWXOCM-UHFFFAOYSA-N

物化性质

• 沸点：
  111.3±7.0 °C(Predicted)
• 密度：
  0.796±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2,5-二甲基-1-己烯 在 potassium tert-butylate 作用下， 生成 1,3,3-Trimethylcyclopenten
  参考文献：
  名称：

  Alkylidenecarbenes from acyclic vinyl bromides and potassium tert-butoxide

  摘要：

  DOI：

  10.1021/jo00867a001

文献信息

• Palladium-catalyzed formylation of organic halides with carbon monoxide and tin hydride
  作者：Victor P. Baillargeon、J. K. Stille

  DOI：10.1021/ja00263a015

  日期：1986.2

  La formylation catalysee par le palladium d'une variete de substrats organiques (iodoarenes, halogenures benzyliques, iodures vinyliques, triflates de vinyles et halogenures allyliques) avec le tributylstannane et le monoxyde de carbone donne les aldehydes avec de bons rendements dans des conditions douces et tolere un certain nombre de groupes fonctionnels

  La formylation catalysee par le palladium d'une variete de substrats Organics特定的团体名称
• A Mechanistic Study of the Reactions of Geminal Dihalides with LDA. Evidence for a Single Electron Transfer Pathway in the Reaction of Geminal Diiodides
  作者：E. C. Ashby、Abhay K. Deshpande、Girish S. Patil

  DOI：10.1021/jo00108a032

  日期：1995.2

  While the reaction of the geminal dichloride, 6,6-dichloro-5,5-dimethyl-1-hexene (8a) with LDA afforded only one product, wh:ich was derived from a chlorocarbene intermediate, the reaction of the corresponding geminal diiodide 8b resulted in the formation of a number of products that were accounted for by a single electron transfer (SET) initiated reaction. This difference in the reactivity patterns of the two substrates shows that the reduction potential of 8b is more favorable than that of 8a and that LDA can function as a one-electron donor. Additionally, 8a was more reactive toward LDA than the already studied monochloro substrate (1a) with the same carbon skeleton. This enhanced reactivity is attributed to the increased acidity of the hydrogen atom attached to the carbon bearing the two chlorine atoms in 8a. The observation that 8b reacted with LDA at a faster rate, not only relative to 8a but also to the corresponding monoiodo compound 1c, indicates that the reduction potential of 8b is more favorable than that of 1c for SET reduction by LDA. Based on the nature of the products formed in the reactions of 8a and 8b with LDA, evidence is presented that supports the notion that, in addition to funtioning as a strong base, LDA can also function as a one-electron donor toward the geminal diiodide 8b.
• Ondruschka, Bernd; Remmler, Matthias; Zimmermann, Gerhard, Journal fur praktische Chemie (Leipzig 1954), 1987, vol. 329, # 1, p. 49 - 54
  作者：Ondruschka, Bernd、Remmler, Matthias、Zimmermann, Gerhard、Krueger, Christian

  DOI：——

  日期：——
• J. PRAKT. CHEM., 329,(1987) N 1, 49-54
  作者：

  DOI：——

  日期：——
• ONDRUSCHKA B.; REMMLER M.; ZIMMERMANN G.; KRUGER CHR., J. PRAKT. CHEM., 329,(1987) N 1, 49-54
  作者：ONDRUSCHKA B.、 REMMLER M.、 ZIMMERMANN G.、 KRUGER CHR.

  DOI：——

  日期：——