6-Methylundec-5-ene | 859742-90-8

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 6-Methylundec-5-ene
• 英文别名: 5-methyl-dec-5-ene；5-Methyl-dec-5-en；5-Methyldec-5-ene；5-methyldec-5-ene
• CAS: 859742-90-8
• 化学式: C₁₁H₂₂
• 分子量: 154.296
• InChiKey: WGDLEBLRXYKKSS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  6-Methylundec-5-ene 在 间氯过氧苯甲酸 作用下， 生成 5-methyl-5-decene oxide 、 5-methyl-5-decene oxide
  参考文献：
  名称：

  金属酞菁配合物Cr（TBPC）OTf：一种高效，可回收的路易斯酸催化剂，可将环氧化物进行立体和立体选择性重排成醛。

  摘要：

  金属酞菁配合物Cr（TBPC）OTf是高效，可回收的路易斯酸催化剂，用于环氧化物和立体选择性重排成醛。

  DOI：

  10.1039/b820948k
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 碘 作用下， 生成 6-Methylundec-5-ene
  参考文献：
  名称：

  Church; Whitmore; McGrew, Journal of the American Chemical Society, 1934, vol. 56, p. 180,183

  摘要：

  DOI：

文献信息

• Methyl group migration in the reactions of alkynyltrialkylborates
  作者：Andrew Pelter、Robert A. Drake

  DOI：10.1016/s0040-4039(00)80450-5

  日期：1988.1

  It is shown that the methyl group cannot be used as a cheap, non-migrating group in the reactions of alkynyltrialkylborates with electrophiles. However, trimethylborane can be used as a methylboronating agent for alkynes, given the right choice of solvent, and this may be of use in terpene synthesis.

  结果表明，在炔基三烷基硼酸酯与亲电子试剂的反应中，甲基不能用作廉价的非迁移基团。但是，如果正确选择溶剂，三甲基硼烷可用作炔烃的甲基硼化剂，这可能在萜烯合成中使用。
• Lewis acid-promoted selective rearrangement of trisubstituted epoxides to aldehydes or ketones
  作者：Keiji Maruoka、Noriaki Murase、Ronan Bureau、Takashi Ooi、Hisashi Yamamoto

  DOI：10.1016/s0040-4020(01)90389-8

  日期：1994.3

  Rearrangement of trisubstituted epoxides has been effected under the influence of various Lewis acids. Among these, methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide) (MABR) can be selectively rearranged from trisubstituted epoxides to aldehydes, while antimony pentafluoride is employable for selective rearrangement to ketones under mild conditions.
• Atom transfer carbonylation using ionic liquids as reaction media
  作者：Takahide Fukuyama、Takaya Inouye、Ilhyong Ryu

  DOI：10.1016/j.jorganchem.2006.08.072

  日期：2007.1

  Photo-induced ATC reactions of RI, CO, and amines to produce amides, were examined using ionic liquids, such as [bmim]PF6 and [bmim]NTf2, as reaction media in the presence of a catalytic amount of a Pd-carbene complex. When the primary alkyl iodide was used, the yield of the amide was lowered due to competing S(N)2 reactions between RI and amines, whereas the reaction of the tertiary alkyl iodides was dependent on the structure of the substrates. ATC reactions of a wide variety of secondary RI proceeded smoothly when ionic liquids were used as reaction media. The Pd-catalyst and ionic liquid could also be recycled. (c) 2006 Elsevier B.V. All rights reserved.
• Church; Whitmore; McGrew, Journal of the American Chemical Society, 1934, vol. 56, p. 180,183
  作者：Church、Whitmore、McGrew

  DOI：——

  日期：——
• Metallophthalocyanine complex, Cr(TBPC)OTf: an efficient, recyclable Lewis acid catalyst in the regio- and stereoselective rearrangement of epoxides to aldehydes
  作者：Kohji Suda、Shin-ichiro Nakajima、Yasumi Satoh、Toshikatsu Takanami

  DOI：10.1039/b820948k

  日期：——

  The metallophthalocyanine complex Cr(TBPC)OTf works as a highly efficient, recyclable Lewis acid catalyst for the regio- and stereoselective rearrangements of epoxides to aldehydes.

  金属酞菁配合物Cr（TBPC）OTf是高效，可回收的路易斯酸催化剂，用于环氧化物和立体选择性重排成醛。