6-Methylnonan-3-one | 174323-01-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 6-Methylnonan-3-one
• CAS: 174323-01-4
• 化学式: C₁₀H₂₀O
• 分子量: 156.268
• InChiKey: PULXPCACRCTXMF-UHFFFAOYSA-N

物化性质

• 沸点：
  199.3±8.0 °C(Predicted)
• 密度：
  0.817±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  6-Methylnonan-3-one 在 sodium tetrahydroborate 、 lithium aluminium tetrahydride 、 二溴三苯基膦 作用下， 以 乙醚 、 二氯甲烷 、 二甲基亚砜 为溶剂， 反应 18.02h， 生成 4-甲基壬烷
  参考文献：
  名称：

  Sex pheromone of caddisflyHesperophylax occidentalis (Banks) (Trichoptera: Limnephilidae)

  摘要：

  The main component of the sex pheromone of the caddisfly Hesperophylax occidentalis (Banks) (Trichoptera: Limnephilidae) was identified as 6-methylnonan-3-one (enantiomeric composition has not yet been determined). Extracts of adult females elicited strong electroantennogram (EAG) responses from adult male antennae, but elicited significantly smaller EAG responses from adult female antennae. Extracts of adult males did not elicit appreciable EAG responses from antennae of either sex. Racemic 6-methylnonan-3-one was synthesized and elicited EAG responses from male antennae as strong as those obtained with female extracts. In field tests with baited sticky traps near lakes and streams, traps baited with synthetic racemic 6-methylnonan-3-one caught significantly more males than control traps. Female adults contained approximately 1 mu g of 6-methylnonan-3-one per individual. Related ketones and alcohols of other chain lengths were also tentatively identified, being present in tiny amounts in female extracts. Extraction of different body parts showed that 6-methylnonan-3-one occurs only in a region near the intersegmental membrane between the fourth and fifth abdominal sternites of the female (no discrete glands were observed). Extracts of males did not contain 6-methylnonan-3-one, nor did pupae of either sex.

  DOI：

  10.1007/bf02040203
• 作为产物：
  描述：

  戊烯 在 五氯化钽 作用下， 以 正己烷 为溶剂， 反应 7.0h， 生成 6-Methylnonan-3-one
  参考文献：
  名称：

  Catalytic Reductive β-Metalloethylation in the Synthesis of 6-Methylnonan-3-One and 3-Methylheptanoic Acid, Racemic Analogs of Hesperophylax occidentalis and Coleoptera scarabaeidae Pheromones

  摘要：

  DOI：

  10.1007/s10600-018-2282-6

文献信息

• BRANCHED TRIALKYLAMINE PRECURSORS, INTERMEDIATES, PRODUCTS MADE THEREFROM AND PROCESSES OF MANUFACTURE
  申请人：Eastman Chemical Company

  公开号：US20190218170A1

  公开（公告）日：2019-07-18

  The invention provides branched hydrophobes for the production of surfactants with improved properties over linear hydrophobes. The invention also provides branched C10-12 enals and aldehydes that are oxidized to branched fatty acids or hydrogenated to branched fatty alcohols and further derivatized to surfactants, through ethoxylation or esterification and other or subsequent reactions. The invention further provides surfactants made from the branched trialkylamine intermediates, including amphoteric, cationic and nonionic surfactants.

  这项发明提供了支链疏水基团，用于生产具有比线性疏水基团更好性能的表面活性剂。该发明还提供了支链C10-12 烯醛和醛，它们被氧化为支链脂肪酸或氢化为支链脂肪醇，并进一步通过乙氧基化或酯化等反应或随后的反应衍生为表面活性剂。该发明还提供了由支链三烷基胺中间体制备的表面活性剂，包括两性离子、阳离子和非离子表面活性剂。
• Process for producing alcohols and ketones
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0531715A1

  公开（公告）日：1993-03-17

  The present invention provides a process for the oxidation of straight-chain, branched-chain or cyclic alkanes of 1-20 carbon atoms and benzene derivatives represented by the following formulas (1) - (2). The alcohols and ketones obtained by the oxidation of the alkanes mentioned above and those by the oxidation of the benzene derivatives mentioned above represented by the following formulas (3) - (6) are important as basic starting materials in producing various chemical products including resins, such as nylon and polyester, pharmaceuticals, agricultural chemicals, perfumes, dyes, etc.

  本发明提供了一种氧化 1-20 个碳原子的直链、支链或环状烷烃以及由下列式子 (1) - (2) 表示的苯衍生物的工艺。由上述烷烃氧化得到的醇和酮以及由下列式子（3）-（6）表示的上述苯衍生物氧化得到的醇和酮是生产各种化学产品的重要基本起始原料，包括树脂（如尼龙和聚酯）、药品、农药、香水、染料等。
• Method of treating neurological disorders using acetone derivatives
  申请人：——

  公开号：US20040097598A1

  公开（公告）日：2004-05-20

  The present invention provides a method of treating neurological disorders, such as epilepsy, comprising administering an effect amount of an acetone derivative having the formula R 1 —C(X)—R 2 , to an animal in need thereof. Such acetone derivatives show higher anticonvulsant activity, higher potency and improved therapeutic indexes over acetone itself.
• METHOD FOR TREATING NEUROLOGICAL DISORDERS USING ACETONE DERIVATIVES
  申请人：Likhodi Serguei S.

  公开号：US20090042982A1

  公开（公告）日：2009-02-12

  The present invention provides a method of treating neurological disorders, such as epilepsy, comprising administering an effect amount of an acetone derivative having the formula R 1 —C(X)—R 2 , to an animal in need thereof. Such acetone derivatives show higher anticonvulsant activity, higher potency and improved therapeutic indexes over acetone itself.
• US5426237A
  申请人：——

  公开号：US5426237A

  公开（公告）日：1995-06-20