9,10-dihydro-10-methyl-9-(2'-naphthylmethylene)acridine | 156247-71-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 9,10-dihydro-10-methyl-9-(2'-naphthylmethylene)acridine
• 英文别名: 10-Methyl-9-(naphthalen-2-ylmethylidene)acridine
• CAS: 156247-71-1
• 化学式: C₂₅H₁₉N
• 分子量: 333.433
• InChiKey: AFTZNOMUWWPAOV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  26
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9,10-dihydro-10-methyl-9-(2'-naphthylmethylene)acridine 生成 甲基-蒽酮
  参考文献：
  名称：

  Sakanishi Katsumasa, Kato Yoshiyuki, Mizukoshi Emi, Shimizu Kazufumi, Tetrahedron Lett, 35 (1994) N 27, S 4789-4792

  摘要：

  DOI：
• 作为产物：
  描述：

  2-萘甲醛 、 10-methoxyphosphinyl-9-methyl-9,10-dihydro-9-azoniaanthracene 生成 9,10-dihydro-10-methyl-9-(2'-naphthylmethylene)acridine
  参考文献：
  名称：

  A novel chemiluminescence from the reaction of 9-arylmethylene-10-methyl-9,10-dihydroacridines and peroxyacid

  摘要：

  Reaction of 9-arylmethylene-10-methyl-9,10-dihydroacridine (1) with more than two equivalents of m-choloroperoxybenzoic acid in CH2Cl2 affords intermediary beta-hydroxy-tertiary-alkyl peroxyester (5) decomposing to N-methylacridone and aromatic aldehyde with chemiluminescence by a CIEEL mechanism.

  DOI：

  10.1016/s0040-4039(00)73237-0

文献信息

• A novel chemiluminescence from the reaction of 9-arylmethylene-10-methyl-9,10-dihydroacridines and dimethyldioxirane
  作者：Katsumasa Sakanishi、Yoshiyuki Kato、Emi Mizukoshi、Kazufumi Shimizu

  DOI：10.1016/s0040-4039(00)76969-3

  日期：1994.7

  Reaction of 9-arylmethylene-10-methyl-9,10-dihydroacridine (1) with isolated dimethyldioxirane affords cleavage products with chemiluminescence via a 1,2,4-trioxan (5) which will be formed by the reaction of an intermediary epoxide (3) with dimethyldioxirane as nucleophile.
• Sakanishi Katsumasa, Kato Yoshiyuki, Mizukoshi Emi, Shimizu Kazufumi, Tetrahedron Lett, 35 (1994) N 27, S 4789-4792
  作者：Sakanishi Katsumasa, Kato Yoshiyuki, Mizukoshi Emi, Shimizu Kazufumi

  DOI：——

  日期：——
• A novel chemiluminescence from the reaction of 9-arylmethylene-10-methyl-9,10-dihydroacridines and peroxyacid
  作者：Katsumasa Sakanishi、Mohamad Bambang Nugroho、Yoshiyuki Kato、Natsuki Yamazaki

  DOI：10.1016/s0040-4039(00)73237-0

  日期：1994.5

  Reaction of 9-arylmethylene-10-methyl-9,10-dihydroacridine (1) with more than two equivalents of m-choloroperoxybenzoic acid in CH2Cl2 affords intermediary beta-hydroxy-tertiary-alkyl peroxyester (5) decomposing to N-methylacridone and aromatic aldehyde with chemiluminescence by a CIEEL mechanism.