1-tributylgermyl-3-undecanol | 925703-34-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-tributylgermyl-3-undecanol
• 英文别名: 1-Tributylgermylundecan-3-ol；1-tributylgermylundecan-3-ol
• CAS: 925703-34-0
• 化学式: C₂₃H₅₀GeO
• 分子量: 415.239
• InChiKey: VHKVZASXCBEVTF-UHFFFAOYSA-N

物化性质

• 沸点：
  459.4±47.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.34
• 重原子数：
  25
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  正丁基锂 、 di-n-butylchlorogermane 、 1-十一烯-3-醇 在 三乙基硼 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以94%的产率得到1-tributylgermyl-3-undecanol
  参考文献：
  名称：

  Homolytic hydrogermylation of alkenes with dibutylchlorogermane

  摘要：

  In the presence of Et3B-dry air, dibutylchlorogermane (Bu2GeClH) reacted smoothly with alkenes at room temperature to give hydrogermylation products in high yields. This homolytic hydrogermylation was applicable to various alkenes including electron-deficient, electron-rich, and internal alkenes. Under the same conditions, tributylgermane (Bu3GeH) showed much lower reactivity than Bu2GeClH. The Et3B-initiated reaction of 1,6-dienes with Bu2GeClH gave germylmethylated cyclopentanes. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.04.043

文献信息

• Homolytic hydrogermylation of alkenes with dibutylchlorogermane
  作者：Katsukiyo Miura、Kazunori Ootsuka、Akira Hosomi

  DOI：10.1016/j.jorganchem.2006.04.043

  日期：2007.1

  In the presence of Et3B-dry air, dibutylchlorogermane (Bu2GeClH) reacted smoothly with alkenes at room temperature to give hydrogermylation products in high yields. This homolytic hydrogermylation was applicable to various alkenes including electron-deficient, electron-rich, and internal alkenes. Under the same conditions, tributylgermane (Bu3GeH) showed much lower reactivity than Bu2GeClH. The Et3B-initiated reaction of 1,6-dienes with Bu2GeClH gave germylmethylated cyclopentanes. (c) 2006 Elsevier B.V. All rights reserved.