(3Z)-4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-hexadecafluoroundec-3-en-2-one | 136909-85-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (3Z)-4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-hexadecafluoroundec-3-en-2-one
• 英文别名: (Z)-4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-hexadecafluoroundec-3-en-2-one
• CAS: 136909-85-8
• 化学式: C₁₁H₄F₁₆O
• 分子量: 456.127
• InChiKey: FGWAKQKTCXBUER-RQOWECAXSA-N

物化性质

• 沸点：
  196.1±40.0 °C(Predicted)
• 密度：
  1.582±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  28
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为产物：
  描述：

  乙酸异丙烯酯 、 全氟壬酸 在 氢氧化钾 作用下， 以 丙酮 为溶剂， 以9.4%的产率得到(3Z)-4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-hexadecafluoroundec-3-en-2-one
  参考文献：
  名称：

  Electrochemical synthesis of perfluoroalkylacetones

  摘要：

  The interaction of electrochemically generated radicals in the electrolysis of the perfluorocarboxylic acids R(F)CF2COOH (I), where R(F) = F (a), CF3 (b), C2F5 (c), C3F7 (d), C5F11 (e), and C7H15 (f), with isopropenyl acetate (II) was studied. The dependence of the results of the electrolysis on the adsorption capacity of the anode permits the proposition that the interaction of (II) with the ECG-radicals occurs close to the surface of the electrode. The yield of the perfluoroalkylacetones comprised 30-37%.

  DOI：

  10.1007/bf00961239

文献信息

• Electrochemical synthesis of perfluoroalkylacetones
  作者：I. M. Vol'pin、M. A. Kurykin、V. A. Grinberg、Yu. B. Vasil'ev、L. S. German

  DOI：10.1007/bf00961239

  日期：1991.7

  The interaction of electrochemically generated radicals in the electrolysis of the perfluorocarboxylic acids R(F)CF2COOH (I), where R(F) = F (a), CF3 (b), C2F5 (c), C3F7 (d), C5F11 (e), and C7H15 (f), with isopropenyl acetate (II) was studied. The dependence of the results of the electrolysis on the adsorption capacity of the anode permits the proposition that the interaction of (II) with the ECG-radicals occurs close to the surface of the electrode. The yield of the perfluoroalkylacetones comprised 30-37%.