4-(4-trifluoromethylbenzyloxy)-5-phenoxypyrimidine | 1383664-86-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-(4-trifluoromethylbenzyloxy)-5-phenoxypyrimidine
• 英文别名: 4-(4-Trifluoromethylbenzyloxy)-5-phenoxypyrimidine；5-phenoxy-4-[[4-(trifluoromethyl)phenyl]methoxy]pyrimidine
• CAS: 1383664-86-5
• 化学式: C₁₈H₁₃F₃N₂O₂
• 分子量: 346.309
• InChiKey: VWXOIFJARWPPPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  25
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  44.2
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  4-(三氟甲基)苄醇 、 4-chloro-5-phenoxypyrimidine 在 sodium hydride 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 3.0h， 以85%的产率得到4-(4-trifluoromethylbenzyloxy)-5-phenoxypyrimidine
  参考文献：
  名称：

  BENZYLOXYPYRIMIDINE DERIVATIVE, AGRICULTURAL/ HORTICULTURAL INSECTICIDE COMPRISING DERIVATIVE AND METHOD FOR USING SAME

  摘要：

  一种苄氧基嘧啶衍生物，由式（I）表示，其中R1是烷基、环烷基、烯基、炔基、卤代烷基、卤代烯基、卤代炔基、烷氧基烷基等；R2和R3分别是氢原子、烷基等；X是烷基、环烷基、烯基、炔基、卤代烷基、卤代烯基、卤代炔基、三烷基硅基等；A是氧原子等，m是0-5的整数，或其盐，以及含有该化合物作为活性成分的农业昆虫杀虫剂和使用方法。

  公开号：

  US20130267564A1

文献信息

• Benzyloxypyrimidine derivative, agricultural/ horticultural insecticide comprising derivative and method for using same
  申请人：Kasahara Ryota

  公开号：US08895574B2

  公开（公告）日：2014-11-25

  A benzyloxypyrimidine derivative represented by the formula (I) wherein R1 is an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, a haloalkyl group, a haloalkenyl group, a haloalkynyl group, an alkoxyalkyl group and the like; R2 and R3 are each a hydrogen atom, an alkyl group and the like; X is an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, a haloalkyl group, a haloalkenyl group, a haloalkynyl group, a trialkylsilyl group and the like; A is a oxygen atom and the like, and m is an integer of 0-5, or a salt thereof, and an agrohorticultural insecticide containing the compound as an active ingredient and a method of use thereof.

  一种由式(I)表示的苄氧基嘧啶衍生物，其中R1是烷基、环烷基、烯基、炔基、卤代烷基、卤代烯基、卤代炔基、烷氧基烷基等；R2和R3分别是氢原子、烷基等；X是烷基、环烷基、烯基、炔基、卤代烷基、卤代烯基、卤代炔基、三烷基硅基等；A是氧原子等，m是0-5的整数，或其盐，以及含有该化合物作为活性成分的农业昆虫杀虫剂和使用方法。
• BENZYLOXYPYRIMIDINE DERIVATIVE, AGRICULTURAL/HORTICULTURAL INSECTICIDE COMPRISING DERIVATIVE AND METHOD FOR USING SAME
  申请人：Nihon Nohyaku Co., Ltd.

  公开号：EP2657229A1

  公开（公告）日：2013-10-30

  A benzyloxypyrimidine derivative represented by the formula (I) wherein R1 is an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, a haloalkyl group, a haloalkenyl group, a haloalkynyl group, an alkoxyalkyl group and the like; R2 and R3 are each a hydrogen atom, an alkyl group and the like; X is an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, a haloalkyl group, a haloalkenyl group, a haloalkynyl group, a trialkylsilyl group and the like; A is a oxygen atom and the like, and m is an integer of 0 - 5, or a salt thereof, and an agrohorticultural insecticide containing the compound as an active ingredient and a method of use thereof.

  由式（I）代表的苄氧基嘧啶衍生物 其中 R1 是烷基、环烷基、烯基、炔基、卤代烷基、卤代烯基、卤代炔基、烷氧基烷基等；R2 和 R3 分别是氢原子、烷基等；X是烷基、环烷基、烯基、炔基、卤代烷基、卤代烯基、卤代炔基、三烷基硅烷基等；A是氧原子等，m是0-5的整数，或其盐，以及含有该化合物作为活性成分的农用园艺杀虫剂及其使用方法。
• BENZYLOXYPYRIMIDINE DERIVATIVE, AGRICULTURAL/HORTICULTURAL INSECTICIDE COMPRISING SAID DERIVATIVE AND METHOD FOR USING THE SAME
  申请人：Nihon Nohyaku Co., Ltd.

  公开号：EP2657229B1

  公开（公告）日：2016-03-30
• US8895574B2
  申请人：——

  公开号：US8895574B2

  公开（公告）日：2014-11-25
• BENZYLOXYPYRIMIDINE DERIVATIVE, AGRICULTURAL/ HORTICULTURAL INSECTICIDE COMPRISING DERIVATIVE AND METHOD FOR USING SAME
  申请人：Kasahara Ryota

  公开号：US20130267564A1

  公开（公告）日：2013-10-10

  A benzyloxypyrimidine derivative represented by the formula (I) wherein R 1 is an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, a haloalkyl group, a haloalkenyl group, a haloalkynyl group, an alkoxyalkyl group and the like; R 2 and R 3 are each a hydrogen atom, an alkyl group and the like; X is an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, a haloalkyl group, a haloalkenyl group, a haloalkynyl group, a trialkylsilyl group and the like; A is a oxygen atom and the like, and m is an integer of 0-5, or a salt thereof, and an agrohorticultural insecticide containing the compound as an active ingredient and a method of use thereof.

  一种苄氧基嘧啶衍生物，由式（I）表示，其中R1是烷基、环烷基、烯基、炔基、卤代烷基、卤代烯基、卤代炔基、烷氧基烷基等；R2和R3分别是氢原子、烷基等；X是烷基、环烷基、烯基、炔基、卤代烷基、卤代烯基、卤代炔基、三烷基硅基等；A是氧原子等，m是0-5的整数，或其盐，以及含有该化合物作为活性成分的农业昆虫杀虫剂和使用方法。