3-[3-(3-Hydroxy-2,2-bis-hydroxymethyl-propoxy)-2,2-bis-(3-hydroxy-2,2-bis-hydroxymethyl-propoxymethyl)-propoxy]-2,2-bis-hydroxymethyl-propan-1-ol | 6363-97-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-[3-(3-Hydroxy-2,2-bis-hydroxymethyl-propoxy)-2,2-bis-(3-hydroxy-2,2-bis-hydroxymethyl-propoxymethyl)-propoxy]-2,2-bis-hydroxymethyl-propan-1-ol
• 英文别名: 2-[[3-[3-Hydroxy-2,2-bis(hydroxymethyl)propoxy]-2,2-bis[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol
• CAS: 6363-97-9
• 化学式: C₂₅H₅₂O₁₆
• 分子量: 608.678
• InChiKey: SFMOZSHXJNJYOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -8
• 重原子数：
  41
• 可旋转键数：
  28
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  280
• 氢给体数：
  12
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  3-[3-(3-Hydroxy-2,2-bis-hydroxymethyl-propoxy)-2,2-bis-(3-hydroxy-2,2-bis-hydroxymethyl-propoxymethyl)-propoxy]-2,2-bis-hydroxymethyl-propan-1-ol 、 对甲苯磺酰氯 在 吡啶 作用下， 以93%的产率得到
  参考文献：
  名称：

  Starburst polyether dendrimers

  摘要：

  DOI：

  10.1021/jo00233a002
• 作为产物：
  描述：

  4-[[3-(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxy)-2,2-bis(2,6,7-trioxabicyclo[2.2.2]octan-4-ylmethoxymethyl)propoxy]methyl]-2,6,7-trioxabicyclo[2.2.2]octane 在 盐酸 作用下， 以 甲醇 为溶剂， 反应 3.0h， 以75%的产率得到3-[3-(3-Hydroxy-2,2-bis-hydroxymethyl-propoxy)-2,2-bis-(3-hydroxy-2,2-bis-hydroxymethyl-propoxymethyl)-propoxy]-2,2-bis-hydroxymethyl-propan-1-ol
  参考文献：
  名称：

  Starburst polyether dendrimers

  摘要：

  DOI：

  10.1021/jo00233a002

文献信息

• Size-Selective Yolk-Shell Nanoreactors with Nanometer-Thin Porous Polymer Shells
  作者：Ying Jia、Sergey N. Shmakov、Paul Register、Eugene Pinkhassik

  DOI：10.1002/chem.201501968

  日期：2015.9.1

  Yolk‐shell nanoreactors with metal nanoparticle core and ultrathin porous polymer shells are effective catalysts for heterogeneous reactions. Polymer shells provide size‐selectivity and improved reusability of catalyst. Nanocapsules with single‐nanometer porous shells are prepared by vesicle‐templated directed assembly. Metal nanoparticles are formed either by selective initiation in pre‐fabricated

  具有金属纳米颗粒核和超薄多孔聚合物壳的蛋黄壳纳米反应器是进行异相反应的有效催化剂。聚合物壳提供了尺寸选择性，并提高了催化剂的可重复使用性。通过囊泡模板定向组装制备具有单纳米多孔壳的纳米胶囊。金属纳米粒子可以通过在预制的纳米胶囊中选择性引发来形成，也可以通过交联聚合物壳的形成来形成。在这项研究中，我们研究了金纳米颗粒催化苯甲醇和苯甲醛的氧化以及铂纳米颗粒催化环己烯的氢化。
• PADIAS, ANNE BUYLE;HALL, H. K., JR.;TOMALIA, DONALD A.;MCCONNELL, J. R., J. ORG. CHEM., 52,(1987) N 24, 5305-5312
  作者：PADIAS, ANNE BUYLE、HALL, H. K., JR.、TOMALIA, DONALD A.、MCCONNELL, J. R.

  DOI：——

  日期：——
• Hollow Fiber Membrane and Preparing Method Thereof
  申请人：Bae Sung Su

  公开号：US20080261017A1

  公开（公告）日：2008-10-23

  The present invention relates to a polyvinylidene difluoride hollow fiber membrane and a method of preparing the same, and more particularly, to an improved polyvinylidene difluoride hollow fiber membrane and a preparation method thereof, in which a spinning solution consisting of polyvinylidene fluoride, alcohol dendrimer and organic solvent is prepared, and then is subjected to solidification by a wet-phase transition process, cleaning and drying, in which alcohol dendrimer that is an organic material as a pore former is introduced, allowing uniform disperse of alcohol dendrimer in polyvinylidene difluoride to form pores, with each having a high dispersion ability and a uniform size, and in which an excellent adhesion durability is imparted, owing to the use of a single material of polyvinylidene difluoride, unlike the conventional hollow fiber membrane preparation method in which pores are formed using existing inorganic particles.