2,3-Dihydroindene-1,4,7-trione | 1105526-34-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,3-Dihydroindene-1,4,7-trione
• 英文别名: 2,3-dihydroindene-1,4,7-trione
• CAS: 1105526-34-8
• 化学式: C₉H₆O₃
• 分子量: 162.145
• InChiKey: MPWZUQYHQYUGBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  51.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  茚满 在 C₉₆H₉₆Fe₂N₁₆O 、 tetrabutylammonium oxone 作用下， 以 二氯甲烷 为溶剂， 反应 0.17h， 以74%的产率得到2,3-dihydro-1H-indene-4,7-dione
  参考文献：
  名称：

  Binuclear iron(III) phthalocyanine(μ-oxodimer)/tetrabutylammonium oxone: a powerful catalytic system for oxidation of hydrocarbons in organic solution

  摘要：

  Binuclear iron(III) phthalocyanine-(mu-oxodimer) complex was tested in catalytic oxygenation reactions of several hydrocarbons using tetrabutylammonium oxone as the oxidant in dichloromethane solution at room temperature. Results of the study demonstrate that this is an extremely powerful catalytic system for oxidative conversion of aromatic hydrocarbons (anthracene, 2-tert-butylanthracene, 2-methylnaphthalene, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene, indane, ethylbenzene, toluene, and benzene) to the respective p-quinones in high yields in 5-30 min. Under these conditions, adamantane is oxidized with 71% conversion after 10 min affording a mixture of 1-adamantanol, 2-adamantanone, 1-hydroxy-2-adamantanone, and 4-protoadamantanone. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.10.023

文献信息

• Binuclear iron(III) phthalocyanine(μ-oxodimer)/tetrabutylammonium oxone: a powerful catalytic system for oxidation of hydrocarbons in organic solution
  作者：Heather M. Neu、Viktor V. Zhdankin、Victor N. Nemykin

  DOI：10.1016/j.tetlet.2010.10.023

  日期：2010.12

  Binuclear iron(III) phthalocyanine-(mu-oxodimer) complex was tested in catalytic oxygenation reactions of several hydrocarbons using tetrabutylammonium oxone as the oxidant in dichloromethane solution at room temperature. Results of the study demonstrate that this is an extremely powerful catalytic system for oxidative conversion of aromatic hydrocarbons (anthracene, 2-tert-butylanthracene, 2-methylnaphthalene, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene, indane, ethylbenzene, toluene, and benzene) to the respective p-quinones in high yields in 5-30 min. Under these conditions, adamantane is oxidized with 71% conversion after 10 min affording a mixture of 1-adamantanol, 2-adamantanone, 1-hydroxy-2-adamantanone, and 4-protoadamantanone. (C) 2010 Elsevier Ltd. All rights reserved.