环丙甲醇,a-5-癸烯基-,(E)- | 134720-99-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 环丙甲醇,a-5-癸烯基-,(E)-
• 英文名称: 1-Cyclopropyl-6E-undecenol-1
• 英文别名: (E)-1-cyclopropylundec-6-en-1-ol
• CAS: 134720-99-3
• 化学式: C₁₄H₂₆O
• 分子量: 210.36
• InChiKey: RCXBNWMPMCTNEZ-AATRIKPKSA-N

物化性质

• 沸点：
  90 °C(Press: 0.5 Torr)
• 密度：
  0.920±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.06
• 重原子数：
  15.0
• 可旋转键数：
  9.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  环丙甲醇,a-5-癸烯基-,(E)- 在 三甲基溴硅烷 、 zinc dibromide 作用下， 以 二氯甲烷 为溶剂， 以94%的产率得到1-Bromo-3E,9E-tetradecadiene
  参考文献：
  名称：

  Synthesis of 3E-tetradecenol, 3E, 9E-tetradecadienol, and their acetates starting from acetylcyclopropane

  摘要：

  Stereospecific synthesis of the linear E-olefins mentioned in the title was realized by a general scheme that was worked out earlier by the authors and which includes as key steps homologization of the corresponding aliphatic pentakisnoraldehydes by means of trimethylsilyloxyvinylcyclopropane and ZnBr2-initiated rearrangement of the intermediate cyclopropylcarbinols under the influence of Me3SiBr.

  DOI：

  10.1007/bf00957995
• 作为产物：
  描述：

  Magnesium, bromo-1-octenyl-, (Z)- 在 sodium tetrahydroborate 、 sodium bis(2-methoxyethoxy)aluminum hydride 、 pyridinium chlorochromate 、 copper(I) bromide 、 zinc(II) chloride 作用下， 以 四氢呋喃 、 甲醇 、 乙醚 、 二氯甲烷 、 甲苯 为溶剂， 反应 5.33h， 生成 环丙甲醇,a-5-癸烯基-,(E)-
  参考文献：
  名称：

  Synthesis of 3E-tetradecenol, 3E, 9E-tetradecadienol, and their acetates starting from acetylcyclopropane

  摘要：

  Stereospecific synthesis of the linear E-olefins mentioned in the title was realized by a general scheme that was worked out earlier by the authors and which includes as key steps homologization of the corresponding aliphatic pentakisnoraldehydes by means of trimethylsilyloxyvinylcyclopropane and ZnBr2-initiated rearrangement of the intermediate cyclopropylcarbinols under the influence of Me3SiBr.

  DOI：

  10.1007/bf00957995

文献信息

• Formolysis and acetolysis of linear saturated and allylic secondary cyclopropyl carbinols
  作者：B. A. Cheskis、N. M. Ivanova、A. M. Moiseenkov

  DOI：10.1007/bf00958566

  日期：1991.4

  Simple esterification of a series of secondary aliphatic cyclopropyl carbinols under the influence of concentrated HCO2H or AcOH without modification of the carbon skeleton is disclosed. Under the same conditions related allyl alcohols undergo stereospecific isomerization to the corresponding esters of 3E,5E-dienols.
• IVANOVA, N. M.;CHESKIS, B. A.;RUBANOVA, E. V.;YATSYNIN, V. G.;MOISEENKOV,+, IZV. AN CCCP. CEP. XIM.,(1991) N, S. 640-644
  作者：IVANOVA, N. M.、CHESKIS, B. A.、RUBANOVA, E. V.、YATSYNIN, V. G.、MOISEENKOV,+

  DOI：——

  日期：——
• CHESKIS, B. A.;IVANOVA, N. M.;MOISEENKOV, A. M., IZV. AN CCCP. CEP. XIM.,(1991) N, S. 853-856
  作者：CHESKIS, B. A.、IVANOVA, N. M.、MOISEENKOV, A. M.

  DOI：——

  日期：——
• Synthesis of 3E-tetradecenol, 3E, 9E-tetradecadienol, and their acetates starting from acetylcyclopropane
  作者：N. M. Ivanova、B. A. Cheskis、E. V. Rubanova、V. G. Yatsynin、A. M. Moiseenkov、O. M. Nefedov

  DOI：10.1007/bf00957995

  日期：1991.3

  Stereospecific synthesis of the linear E-olefins mentioned in the title was realized by a general scheme that was worked out earlier by the authors and which includes as key steps homologization of the corresponding aliphatic pentakisnoraldehydes by means of trimethylsilyloxyvinylcyclopropane and ZnBr2-initiated rearrangement of the intermediate cyclopropylcarbinols under the influence of Me3SiBr.