3-methylene-glutaric acid | 90423-57-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 3-methylene-glutaric acid
• 英文别名: 3-Methylen-glutarsaeure；2-Methylen-propan-dicarbonsaeure-(1.3)；3-Methylen-pentandisaeure；3-Methylenepentanedioic acid；3-methylidenepentanedioic acid
• CAS: 90423-57-7
• 化学式: C₆H₈O₄
• mdl: MFCD18432428
• 分子量: 144.127
• InChiKey: PTVUEWRDASTEGR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.333
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-methylene-glutaric acid 生成 3-甲基戊二酸
  参考文献：
  名称：

  Polymerization. II. Acid—Salt I`nterchange and Chain Branching in Sodium Polymerization of Dienes

  摘要：

  DOI：

  10.1021/ja01193a043
• 作为产物：
  描述：

  二氧化碳 、 sodium,pentane 、 异丁烯 在 正戊烷 作用下， 生成 3-methylene-glutaric acid
  参考文献：
  名称：

  Polymerization. II. Acid—Salt I`nterchange and Chain Branching in Sodium Polymerization of Dienes

  摘要：

  DOI：

  10.1021/ja01193a043

文献信息

• [EN] POLYMERS PREPARED FROM MEVALONOLACTONE AND DERIVATIVES<br/>[FR] POLYMÈRES PRÉPARÉS À PARTIR DE LA MÉVALONOLACTONE ET DE SES DÉRIVÉS
  申请人：VISOLIS INC

  公开号：WO2016077555A1

  公开（公告）日：2016-05-19

  Described herein polymer precursor compounds (aka polymer building blocks) of derived from biobased compounds, and specifically biobased mevalonolactone and its related derivatives. Through oxidation these biobased precursors can be reacted to yield building blocks for (unsaturated-) polyesters, polyester polyols and polyamides, as well as precursors for glycidyl esters and omega-alkenyl esters. Through reduction, these biobased precursors can be reacted to yield building blocks for (unsaturated-) polyesters, polyester polyols, polycarbonates, as well as precursors for glycidyl ethers and omega-alkenyl ethers. Through nucleophilic ring opening and/or amidation, these biobased precursors can be reacted to yield building blocks for polyester polyols, chain-extender for polyurethanes, or polyester-amides.

  本文描述了从生物基化合物中衍生的聚合物前体化合物（又称聚合物构建模块），特别是生物基美伐酮内酯及其相关衍生物。通过氧化，这些生物基前体可以被反应生成（不饱和的）聚酯、聚酯多元醇和聚酰胺的构建模块，以及环氧酯和ω-烯基酯的前体。通过还原，这些生物基前体可以被反应生成（不饱和的）聚酯、聚酯多元醇、聚碳酸酯的构建模块，以及环氧醚和ω-烯基醚的前体。通过亲核环开和/或酰胺化，这些生物基前体可以被反应生成聚酯多元醇的构建模块，聚氨酯的扩链剂，或聚酯酰胺。
• POLYMERS PREPARED FROM MEVALONOLACTONE AND DERIVATIVES
  申请人：Visolis, Inc.

  公开号：US20160130389A1

  公开（公告）日：2016-05-12

  Described herein polymer precursor compounds (aka polymer building blocks) of derived from biobased compounds, and specifically biobased mevalonolactone and its related derivatives. Through oxidation these biobased precursors can be reacted to yield building blocks for (unsaturated-) polyesters, polyester polyols and polyamides, as well as precursors for glycidyl esters and omega-alkenyl esters. Through reduction, these biobased precursors can be reacted to yield building blocks for (unsaturated-) polyesters, polyester polyols, polycarbonates, as well as precursors for glycidyl ethers and omega-alkenyl ethers. Through nucleophilic ring opening and/or amidation, these biobased precursors can be reacted to yield building blocks for polyester polyols, chain-extender for polyurethanes, or polyester-amides.

  本文描述了从生物基化合物中衍生出的聚合物前体化合物（又称聚合物构建块），特别是生物基美瓦酮内酯及其相关衍生物。通过氧化，这些生物基前体可以反应产生（不饱和）聚酯、聚酯多元醇和聚酰胺的构建块，以及环氧酯和ω-烯基酯的前体。通过还原，这些生物基前体可以反应产生（不饱和）聚酯、聚酯多元醇、聚碳酸酯的构建块，以及环氧醚和ω-烯基醚的前体。通过亲核环开和/或酰胺化，这些生物基前体可以反应产生聚酯多元醇、聚氨酯的链延长剂，或聚酯酰胺的构建块。
• Aqueous formaldehyde-free composition and fiberglass insulation including the same
  申请人：——

  公开号：US20040033747A1

  公开（公告）日：2004-02-19

  An aqueous composition that includes a) aqueous hydroxy functional, carboxy functional polymer including the reaction product of at least 5% by weight &agr;,&bgr;-ethylenically unsaturated hydroxy monomer, at least 30% by weight ethylenically unsaturated carboxylic acid monomer, from 0% by weight to less than 50% by weight &agr;,&bgr;-ethylenically unsaturated nonhydroxy functional, noncarboxy functional monomer, and chain transfer agent, and b) condensation accelerator, and articles that include a nonwoven web including glass fibers, and cured aqueous binder composition.

  一种水性组合物，包括a)水性羟基功能、羧基功能聚合物，包括至少5%重量的α，β-乙烯基不饱和羟基单体的反应产物，至少30%重量的乙烯基不饱和羧酸单体，从0%重量到小于50%重量的α，β-乙烯基不含羟基功能、不含羧基功能单体，以及链转移剂；和b)缩聚加速剂，以及包括玻璃纤维的非织造网和固化的水性粘合剂组合物的制品。
• Binders and materials made therewith
  申请人：Swift Lee Brian

  公开号：US20070123679A1

  公开（公告）日：2007-05-31

  Binders to produce or promote cohesion in non or loosely assembled matter.

  Binders是指用于非或松散组装物质中产生或促进凝聚力的物质。
• BINDERS AND MATERIALS MADE THEREWITH
  申请人：Swift Brian Lee

  公开号：US20090324915A1

  公开（公告）日：2009-12-31

  Binders to produce or promote cohesion in non-assembled or loosely assembled matter.

  Binders用于生产或促进非组装或松散组装的物质中的凝聚作用。