1-Methyl-4-[(4-methylphenyl)-bis[tris(4-propan-2-ylphenyl)silylamino]silyl]benzene | 1373216-35-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Methyl-4-[(4-methylphenyl)-bis[tris(4-propan-2-ylphenyl)silylamino]silyl]benzene
• 英文别名: 1-methyl-4-[(4-methylphenyl)-bis[tris(4-propan-2-ylphenyl)silylamino]silyl]benzene
• CAS: 1373216-35-3
• 化学式: C₆₈H₈₂N₂Si₃
• 分子量: 1011.67
• InChiKey: SMYKUMZKDWQZPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.11
• 重原子数：
  73
• 可旋转键数：
  18
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  germanium(II) chloride dioxane 、 1-Methyl-4-[(4-methylphenyl)-bis[tris(4-propan-2-ylphenyl)silylamino]silyl]benzene 在 n-butyllithium 作用下， 以 乙醚 、 正己烷 为溶剂， 以34%的产率得到
  参考文献：
  名称：

  Expanding the Steric Coverage Offered by Bis(amidosilyl) Chelates: Isolation of Low-Coordinate N-Heterocyclic Germylene Complexes

  摘要：

  The synthesis and coordination chemistry of a series of dianionic bis(amido)silyl and bis(amido)disilyl, [NSiN] and [NSi-SiN], chelates with N-bound aryl or sterically modified triarylsilyl (SiAr3) groups is reported. In order to provide a consistent comparison of the steric coverage afforded by each ligand construct, various two-coordinate N-heterocyclic germylene complexes featuring each ligand set were prepared and oxidative S-atom transfer chemistry was explored. In the cases where clean oxidation transpired, sulfido-bridged centrosymmetric germanium(IV) dimers of the general form [LGe(mu-S)](2) (L = bis(amidosilyl) ligands) were obtained in lieu of the target monomeric germanethiones with discrete Ge=S double bonds. These results indicate that the reported chelates possess sufficient conformational flexibility to allow for the dimerization of LGe=S units to occur. Notably, the new triarylsilyl groups (4-RC6H4)(3)Si- (R = Bu-t and Pr-i) still offer considerably expanded degrees of steric coverage relative to the parent congener, -SiPh3, and thus the use of substituted triarylsilyl groups within ligand design strategies should be a generally useful concept in advancing low-coordination main group and transition-metal chemistry.

  DOI：

  10.1021/ic300495k
• 作为产物：
  描述：

  4-溴异丙苯 在 正丁基锂 、 lithium amide 、 magnesium 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 为溶剂， 反应 51.0h， 生成 1-Methyl-4-[(4-methylphenyl)-bis[tris(4-propan-2-ylphenyl)silylamino]silyl]benzene
  参考文献：
  名称：

  Expanding the Steric Coverage Offered by Bis(amidosilyl) Chelates: Isolation of Low-Coordinate N-Heterocyclic Germylene Complexes

  摘要：

  The synthesis and coordination chemistry of a series of dianionic bis(amido)silyl and bis(amido)disilyl, [NSiN] and [NSi-SiN], chelates with N-bound aryl or sterically modified triarylsilyl (SiAr3) groups is reported. In order to provide a consistent comparison of the steric coverage afforded by each ligand construct, various two-coordinate N-heterocyclic germylene complexes featuring each ligand set were prepared and oxidative S-atom transfer chemistry was explored. In the cases where clean oxidation transpired, sulfido-bridged centrosymmetric germanium(IV) dimers of the general form [LGe(mu-S)](2) (L = bis(amidosilyl) ligands) were obtained in lieu of the target monomeric germanethiones with discrete Ge=S double bonds. These results indicate that the reported chelates possess sufficient conformational flexibility to allow for the dimerization of LGe=S units to occur. Notably, the new triarylsilyl groups (4-RC6H4)(3)Si- (R = Bu-t and Pr-i) still offer considerably expanded degrees of steric coverage relative to the parent congener, -SiPh3, and thus the use of substituted triarylsilyl groups within ligand design strategies should be a generally useful concept in advancing low-coordination main group and transition-metal chemistry.

  DOI：

  10.1021/ic300495k

文献信息

• Expanding the Steric Coverage Offered by Bis(amidosilyl) Chelates: Isolation of Low-Coordinate <i>N</i>-Heterocyclic Germylene Complexes
  作者：Sean K. Liew、S. M. Ibrahim Al-Rafia、James T. Goettel、Paul A. Lummis、Sean M. McDonald、Leah J. Miedema、Michael J. Ferguson、Robert McDonald、Eric Rivard

  DOI：10.1021/ic300495k

  日期：2012.5.7

  The synthesis and coordination chemistry of a series of dianionic bis(amido)silyl and bis(amido)disilyl, [NSiN] and [NSi-SiN], chelates with N-bound aryl or sterically modified triarylsilyl (SiAr3) groups is reported. In order to provide a consistent comparison of the steric coverage afforded by each ligand construct, various two-coordinate N-heterocyclic germylene complexes featuring each ligand set were prepared and oxidative S-atom transfer chemistry was explored. In the cases where clean oxidation transpired, sulfido-bridged centrosymmetric germanium(IV) dimers of the general form [LGe(mu-S)](2) (L = bis(amidosilyl) ligands) were obtained in lieu of the target monomeric germanethiones with discrete Ge=S double bonds. These results indicate that the reported chelates possess sufficient conformational flexibility to allow for the dimerization of LGe=S units to occur. Notably, the new triarylsilyl groups (4-RC6H4)(3)Si- (R = Bu-t and Pr-i) still offer considerably expanded degrees of steric coverage relative to the parent congener, -SiPh3, and thus the use of substituted triarylsilyl groups within ligand design strategies should be a generally useful concept in advancing low-coordination main group and transition-metal chemistry.