4-(2,3-dihydro-1H-inden-5-yloxy)phthalonitrile | 864862-42-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-(2,3-dihydro-1H-inden-5-yloxy)phthalonitrile
• 英文别名: 4-(5-Indanyloxy)phthalonitrile；4-(2,3-dihydro-1H-inden-5-yloxy)benzene-1,2-dicarbonitrile
• CAS: 864862-42-0
• 化学式: C₁₇H₁₂N₂O
• 分子量: 260.295
• InChiKey: YTPOXCOORSNOJZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  56.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(2,3-dihydro-1H-inden-5-yloxy)phthalonitrile 、 titanium (IV) butoxide 在 尿素 作用下， 以 辛醇 为溶剂， 反应 6.0h， 以94.1%的产率得到2(3),9(10),16(17),23(24)-tetra(2,3-dihydro-1H-inden-5-yloxy)phthalocyaninatotitanium(IV) oxide
  参考文献：
  名称：

  Synthesis, characterization and dielectric properties of novel axial coumarin-substituted titanium(IV) phthalocyanines

  摘要：

  The oxotitanium(IV) phthalocyanine (2) and axial coumarin-substituted derivatives (5 and 6) have been synthesized, and characterized by IR, UV-Vis, fluorescence, H-1 NMR, MALDI-TOF mass spectrometry and elemental analysis. It was observed that the reaction of novel oxotitanium(IV) phthalocyanine with orthodihyroxycoumarin compounds gives its derivatives, substituted by coumarin at the axial position. The electronic and interface state density properties of the Ag/Pc/p-Si diodes have been investigated by current-voltage (I-V) and conductance-frequency-voltage (G-omega-V) methods. It was found that, the conduction mechanism of the diodes is controlled by the thermoionic emission mechanism. From the analysis of frequency, omega, dependence of electrical conductivity, sigma(ac), it was found that the sigma(ac) obeys the power law given by sigma(ac), = sigma(0)w(s). The interface state density of the diodes were determined from (G/omega)-omega plots. It was found that the kind of substitution affects both the interface and omega electrical properties of the phthalocyanine complexes considerably. The obtained results show that the Ag/6/p-Si heterojunction is a good candidate for the electronic device applications. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.09.055

文献信息

• Synthesis, characterization and dielectric properties of novel axial coumarin-substituted titanium(IV) phthalocyanines
  作者：Selçuk Altun、Ahmet Altındal、Mustafa Bulut

  DOI：10.1016/j.poly.2012.09.055

  日期：2013.1

  The oxotitanium(IV) phthalocyanine (2) and axial coumarin-substituted derivatives (5 and 6) have been synthesized, and characterized by IR, UV-Vis, fluorescence, H-1 NMR, MALDI-TOF mass spectrometry and elemental analysis. It was observed that the reaction of novel oxotitanium(IV) phthalocyanine with orthodihyroxycoumarin compounds gives its derivatives, substituted by coumarin at the axial position. The electronic and interface state density properties of the Ag/Pc/p-Si diodes have been investigated by current-voltage (I-V) and conductance-frequency-voltage (G-omega-V) methods. It was found that, the conduction mechanism of the diodes is controlled by the thermoionic emission mechanism. From the analysis of frequency, omega, dependence of electrical conductivity, sigma(ac), it was found that the sigma(ac) obeys the power law given by sigma(ac), = sigma(0)w(s). The interface state density of the diodes were determined from (G/omega)-omega plots. It was found that the kind of substitution affects both the interface and omega electrical properties of the phthalocyanine complexes considerably. The obtained results show that the Ag/6/p-Si heterojunction is a good candidate for the electronic device applications. (c) 2012 Elsevier Ltd. All rights reserved.