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2-异丁氧基环己烷-1-醇 | 94279-04-6

中文名称
2-异丁氧基环己烷-1-醇
中文别名
——
英文名称
2-Isobutoxycyclohexan-1-ol
英文别名
2-(2-methylpropoxy)cyclohexan-1-ol
2-异丁氧基环己烷-1-醇化学式
CAS
94279-04-6
化学式
C10H20O2
mdl
——
分子量
172.268
InChiKey
QYNMQOJKJIUWRX-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 沸点:
    233.8±8.0 °C(Predicted)
  • 密度:
    0.95±0.1 g/cm3(Predicted)

计算性质

  • 辛醇/水分配系数(LogP):
    2.1
  • 重原子数:
    12
  • 可旋转键数:
    3
  • 环数:
    1.0
  • sp3杂化的碳原子比例:
    1.0
  • 拓扑面积:
    29.5
  • 氢给体数:
    1
  • 氢受体数:
    2

反应信息

  • 作为产物:
    描述:
    异丁醇氧化环己烯 在 molybdenum incorporated SBA-15 mesoporous silica 作用下, 反应 0.5h, 生成 2-异丁氧基环己烷-1-醇
    参考文献:
    名称:
    Enhanced metal loading in SBA-15-type catalysts facilitated by salt addition: Synthesis, characterization and catalytic epoxide alcoholysis activity of molybdenum incorporated porous silica
    摘要:
    We report a novel method to increase the metal loading in SBA-15 silica matrix via direct synthesis. It was demonstrated through the synthesis and characterization of a series of molybdenum containing SBA-15 mesoporous silica catalysts prepared with and without diammonium hydrogen phosphate (DHP) as an additive. Catalysts prepared with DHP show a 2-3 times increase in incorporation of molybdenum in the silica matrix and pore size enlargement. The synthesized catalysts were characterized using nitrogen sorption, X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma-optical emission spectroscopy (ICP-OES). The catalytic activity of catalysts prepared with DHP for alcoholysis of epoxides was superior than the catalyst prepared without DHP. Alcoholysis of epoxides was demonstrated for a range of alcohols and epoxides under ambient conditions in as little as 30 min with high selectivity. (C) 2014 Elsevier B.V. All rights reserved.
    DOI:
    10.1016/j.apcata.2014.01.055
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文献信息

  • Optically active compounds, liquid crystal compositions comprising said compounds, and liquid crystal optical modulators using said compositions
    申请人:HITACHI, LTD.
    公开号:EP0376294B1
    公开(公告)日:1996-03-13
  • US5269965A
    申请人:——
    公开号:US5269965A
    公开(公告)日:1993-12-14
  • US5370821A
    申请人:——
    公开号:US5370821A
    公开(公告)日:1994-12-06
  • Enhanced metal loading in SBA-15-type catalysts facilitated by salt addition: Synthesis, characterization and catalytic epoxide alcoholysis activity of molybdenum incorporated porous silica
    作者:Sridhar Budhi、Chorthip Peeraphatdit、Svitlana Pylypenko、Vy H.T. Nguyen、Emily A. Smith、Brian G. Trewyn
    DOI:10.1016/j.apcata.2014.01.055
    日期:2014.4
    We report a novel method to increase the metal loading in SBA-15 silica matrix via direct synthesis. It was demonstrated through the synthesis and characterization of a series of molybdenum containing SBA-15 mesoporous silica catalysts prepared with and without diammonium hydrogen phosphate (DHP) as an additive. Catalysts prepared with DHP show a 2-3 times increase in incorporation of molybdenum in the silica matrix and pore size enlargement. The synthesized catalysts were characterized using nitrogen sorption, X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma-optical emission spectroscopy (ICP-OES). The catalytic activity of catalysts prepared with DHP for alcoholysis of epoxides was superior than the catalyst prepared without DHP. Alcoholysis of epoxides was demonstrated for a range of alcohols and epoxides under ambient conditions in as little as 30 min with high selectivity. (C) 2014 Elsevier B.V. All rights reserved.
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