4-dimethylsulfylimino-3-phenylfuroxan | 130319-35-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 4-dimethylsulfylimino-3-phenylfuroxan
• 英文别名: 4-dimethylsulfinyl-3-phenylfuroxane；Dimethyl-[(5-oxido-4-phenyl-1,2,5-oxadiazol-5-ium-3-yl)imino]-lambda4-sulfane；dimethyl-[(5-oxido-4-phenyl-1,2,5-oxadiazol-5-ium-3-yl)imino]-λ4-sulfane
• CAS: 130319-35-6
• 化学式: C₁₀H₁₁N₃O₂S
• 分子量: 237.282
• InChiKey: FVBRKHXYORLSPD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  83.1
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4-dimethylsulfylimino-3-phenylfuroxan 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 以93%的产率得到4-nitroso-3-phenylfuroxan
  参考文献：
  名称：

  Sulfyliminofuroxans: Synthesis, structure, and oxidation to nitro and nitroso derivatives

  摘要：

  We have synthesized sulfylimines of the furoxan series. It was shown that by oxidation of 4-dimethylsulfyliminofuroxans both nitro and nitroso derivatives, the first examples of nitrosofuroxans, can be prepared. With x-ray stuctural analysis the main structural characteristics of the sulfyliminofuroxans were established.

  DOI：

  10.1007/bf00957864
• 作为产物：
  描述：

  4-amino-3-phenylfuroxane 、 dimethyl sulfide bis-trifluoroacetate 以 二氯甲烷 、 二甲基亚砜 为溶剂， 反应 2.5h， 生成 4-dimethylsulfylimino-3-phenylfuroxan
  参考文献：
  名称：

  Sulfyliminofuroxans: Synthesis, structure, and oxidation to nitro and nitroso derivatives

  摘要：

  We have synthesized sulfylimines of the furoxan series. It was shown that by oxidation of 4-dimethylsulfyliminofuroxans both nitro and nitroso derivatives, the first examples of nitrosofuroxans, can be prepared. With x-ray stuctural analysis the main structural characteristics of the sulfyliminofuroxans were established.

  DOI：

  10.1007/bf00957864

文献信息

• RAKITIN, O. A.;VLASOVA, O. G.;CHERTANOVA, L. F.;XMELNITSKIJ, L. I., IZV. AN CCCP. CEP. XIM.,(1990) N, S. 1625-1629
  作者：RAKITIN, O. A.、VLASOVA, O. G.、CHERTANOVA, L. F.、XMELNITSKIJ, L. I.

  DOI：——

  日期：——
• Sulfyliminofuroxans: Synthesis, structure, and oxidation to nitro and nitroso derivatives
  作者：O. A. Rakitin、O. G. Vlasova、L. F. Chertanova、L. I. Khmel'nitskii

  DOI：10.1007/bf00957864

  日期：1990.7

  We have synthesized sulfylimines of the furoxan series. It was shown that by oxidation of 4-dimethylsulfyliminofuroxans both nitro and nitroso derivatives, the first examples of nitrosofuroxans, can be prepared. With x-ray stuctural analysis the main structural characteristics of the sulfyliminofuroxans were established.