2,4-dichloro-6-(2,4-dimethyl-phenoxy)-[1,3,5]triazine | 32998-09-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,4-dichloro-6-(2,4-dimethyl-phenoxy)-[1,3,5]triazine
• 英文别名: 2,4-Dichloro-6-(2,4-dimethylphenoxy)-1,3,5-triazine
• CAS: 32998-09-7
• 化学式: C₁₁H₉Cl₂N₃O
• mdl: MFCD17294502
• 分子量: 270.118
• InChiKey: CXAJUICOYYJNPB-UHFFFAOYSA-N

物化性质

• 沸点：
  444.7±55.0 °C(Predicted)
• 密度：
  1.377±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.181
• 拓扑面积：
  47.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,4-dichloro-6-(2,4-dimethyl-phenoxy)-[1,3,5]triazine 在 三乙胺 、 三氟乙酸 、 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 17.17h， 生成 4,4-difluoro-8-(4-(4-chloro-6-(2,4-dimethylphenyloxy)-1,3,5-triazin-2-yloxy)phenyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indancene
  参考文献：
  名称：

  Synthesis and photophysical properties of tripod BODIPY dyes bearing mono-phenolic derivatives

  摘要：

  A series of new tripod boron dipyrromethene (BODIPY) dyes bearing mono-phenolic derivatives were synthesized and characterized. An optimized reaction condition for the synthesis of the bis-substituted intermediates was obtained. An unanticipated phenol-dependent effect on the yields was found and a hypothetic mechanism was proposed to elucidate the reactivity of the tripod dipyrromethene species during the complexation step. The new dyes showed typical photophysical properties of the BODIPY fluorophore. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2014.12.072
• 作为产物：
  描述：

  三聚氯氰 、 2,4-二甲基苯酚 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 生成 2,4-dichloro-6-(2,4-dimethyl-phenoxy)-[1,3,5]triazine
  参考文献：
  名称：

  Synthesis and photophysical properties of tripod BODIPY dyes bearing mono-phenolic derivatives

  摘要：

  A series of new tripod boron dipyrromethene (BODIPY) dyes bearing mono-phenolic derivatives were synthesized and characterized. An optimized reaction condition for the synthesis of the bis-substituted intermediates was obtained. An unanticipated phenol-dependent effect on the yields was found and a hypothetic mechanism was proposed to elucidate the reactivity of the tripod dipyrromethene species during the complexation step. The new dyes showed typical photophysical properties of the BODIPY fluorophore. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2014.12.072

文献信息

• Synthesis and photophysical properties of tripod BODIPY dyes bearing mono-phenolic derivatives
  作者：Jiahui Lu、Xin Qi、Tao Yue、Weiran Tang、Liping Ding

  DOI：10.1016/j.tet.2014.12.072

  日期：2015.2

  A series of new tripod boron dipyrromethene (BODIPY) dyes bearing mono-phenolic derivatives were synthesized and characterized. An optimized reaction condition for the synthesis of the bis-substituted intermediates was obtained. An unanticipated phenol-dependent effect on the yields was found and a hypothetic mechanism was proposed to elucidate the reactivity of the tripod dipyrromethene species during the complexation step. The new dyes showed typical photophysical properties of the BODIPY fluorophore. (C) 2014 Elsevier Ltd. All rights reserved.