6,9-dihydroxy-2,6,9,11-tetramethyltricyclo[6.2.2.0^2,7]dodeca-3,11-diene-5,10-dione | 40381-80-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 6,9-dihydroxy-2,6,9,11-tetramethyltricyclo[6.2.2.0^2,7]dodeca-3,11-diene-5,10-dione
• 英文别名: 1,4-Aethyleno-2,8-dihydroxy-2,4a,8,9-tetramethyl-octahydronaphthal-5-en-3,7-dion；5,9-Dihydroxy-3,5,8a,9-tetramethyl-1,4a,5,8a-tetrahydro-1,4-ethanonaphthalene-6,10(4h)-dione；3,10-dihydroxy-3,7,10,11-tetramethyltricyclo[6.2.2.02,7]dodeca-5,11-diene-4,9-dione
• CAS: 40381-80-4
• 化学式: C₁₆H₂₀O₄
• 分子量: 276.332
• InChiKey: YZZXAJIWLRXAHA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,4-二甲基苯酚 在 sodium periodate 、 乙酸酐 作用下， 以34%的产率得到6,9-dihydroxy-2,6,9,11-tetramethyltricyclo[6.2.2.0^2,7]dodeca-3,11-diene-5,10-dione
  参考文献：
  名称：

  Novel One‐Pot Synthesis of Acetoxy‐2,4‐Cyclohexadienones

  摘要：

  A new, simple, one-pot method for the oxidative acetylation of some substituted phenols leading to acetoxycyclohexa-2,4-dienones is described. A novel diacetoxycyclohexadienone 12 has also been prepared using the present method from 2-hydroxymethyl phenol (salicyl alcohol).

  DOI：

  10.1081/scc-200061717

文献信息

• Novel One‐Pot Synthesis of Acetoxy‐2,4‐Cyclohexadienones
  作者：Pradeep T. Deota、Piyush R. Upadhyay、Hemant S. Parmar

  DOI：10.1081/scc-200061717

  日期：2005.6.1

  A new, simple, one-pot method for the oxidative acetylation of some substituted phenols leading to acetoxycyclohexa-2,4-dienones is described. A novel diacetoxycyclohexadienone 12 has also been prepared using the present method from 2-hydroxymethyl phenol (salicyl alcohol).